Methyl 4-chloropicolinate

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Methyl 4-chloropicolinate

Product Name: Methyl 4-chloropicolinate
CAS No.: 24484-93-3
Chemical Name: Methyl 4-chloropicolinate
Synonyms: 4-CHLORO-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER;METHYL 4-CHLOROPYRIDINE-2-CARBOXYLATE;4-chloropicolinate;EOS-62380;IFLAB-BB F2108-0101;oro-2-pyridinecarboxyL;Methyl 4-chloropicolite;METHYL 4-CHLOROPICOLINATE;4-chloropyridine-2-formate;Methyl 4-Chloro-2-picolinate
CBNumber: CB2224066
Molecular Formula: C7H6ClNO2
Formula Weight: 171.58
MOL File: 24484-93-3.mol

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Methyl 4-chloropicolinate Property

Melting point:: 50-52
Boiling point:: 105-111 °C(Press: 2-3 Torr)
Density: 1.294±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Solid
pka: -0.25±0.10(Predicted)
color: Off-White to Beige
InChI: InChI=1S/C7H6ClNO2/c1-11-7(10)6-4-5(8)2-3-9-6/h2-4H,1H3
InChIKey: VTENWIPSWAMPKI-UHFFFAOYSA-N
SMILES: C1(C(OC)=O)=NC=CC(Cl)=C1
CAS DataBase Reference: 24484-93-3(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36
Safety Statements: 26
HazardClass: IRRITANT
HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H319Causes serious eye irritation
Precautionary statements: P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: ADE000348
Product name: 4-Chloro-pyridine-2-carboxylic acid methyl ester
Purity: Aldrich
Packaging: 1g
Price: $209
Updated: 2024/03/01

TCI Chemical

Product number: M1832
Product name: Methyl 4-Chloro-2-pyridinecarboxylate
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $20
Updated: 2024/03/01

TCI Chemical

Product number: M1832
Product name: Methyl 4-Chloro-2-pyridinecarboxylate
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $38
Updated: 2024/03/01

TRC

Product number: M294455
Product name: Methyl4-Chloropicolinate
Packaging: 1g
Price: $60
Updated: 2021/12/16

Usbiological

Product number: M3396-85
Product name: Methyl 4-Chloropicolinate
Packaging: 1g
Price: $333
Updated: 2021/12/16

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Methyl 4-chloropicolinate Chemical Properties,Usage,Production

Chemical Properties

Brown Solid

Uses

Methyl 4-Chloropicolinate (cas# 24484-93-3) is a compound useful in organic synthesis.

Production Methods

The starting material 2-picolinic acid was treated with SOCl2 to generate 4-chloropicolinoyl chloride, and then esterification with MeOH resulted in the formation of methyl 4-chloropicolinate.

Synthesis Reference(s)

Synthetic Communications, 26, p. 2017, 1996 DOI: 10.1080/00397919608003557

Synthesis

To a suspension of 4-chloropyridine-2-carboxylic acid (4.5 g, 29.0 mmol) in methylene chloride (120 mL) was added oxalyl chloride (3.0 mL, 1.2 eq) under Ar2. The reaction was cooled to 0° C., and 500 uL of DMF was added. A large amount of gas was generated in situ. The reaction was stirred at room temperature for 1.5 h and then concentrated. Dry MeOH (50 mL) was added to the crude acyl chloride residue. The reaction was stirred at room temperature for 0.5 h, then quenched with NaHCO3 (5%) to neutral, extracted with EtOAc, and washed with brine. The combined organics were dried over MgSO4, filtered, and concentrated in vacuo to give 5.0 g of a crude solid, which was triturated with 5% EtOAc/hexane to give Methyl 4-chloropicolinate as a light yellow solid (4.5 g, 90%).

Methyl 4-chloropicolinate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 4-chloropicolinate manufacturers

Hebei Dangtong Import and export Co LTD

Product: Methyl 4-chloropicolinate 24484-93-3
Price: US $170.00-150.00/kg
Min. Order: 100kg
Purity: 99.99%
Supply Ability: 100Tons
Release date: 2023-03-06

Henan Fengda Chemical Co., Ltd

Product: Methyl 4-chloropicolinate 24484-93-3
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-30

Hebei Fengqiang Trading Co., LTD

Product: Methyl 4-chloropicolinate 24484-93-3
Price: US $100.00/bag
Min. Order: 1bag
Purity: 99
Supply Ability: 5000
Release date: 2023-09-14

24484-93-3, Methyl 4-chloropicolinateRelated Search:

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IFLAB-BB F2108-0101

METHYL 4-CHLOROPICOLINATE

4-Chloropyridine-2- forMic acidMethyl ester

4-chloropicolinate

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Methyl 4-chloropyridine-2-car

EOS-62380

Methyl 4-chloropyridine-2-carboxylate 97%

METHYL 4-CHLOROPYRIDINE-2-CARBOXYLATE

METHYL 4-CHLORO-2-PYRIDINECARBOXYLATE

4-CHLORO-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER

6-Methyl-2-(trifluoromethanesulfonyl)Oxypyridine

Methyl 4-Chloro-2-picolinate

4-Chloropicolinic Acid Methyl Ester Methyl 4-Chloropicolinate 4-Chloro-2-pyridinecarboxylic Acid Methyl Ester

2-Pyridinecarboxylic acid, 4-chloro-, methyl ester

4-Chloropicolinic Acid Methyl Ester

4-Chloro-pyridine-2-carboxylic acid methyl

Methyl 4-chloro-2-pyridin...

Methyl 4-chloropicolinate, 4-Chloro-2-(methoxycarbonyl)pyridine

oro-2-pyridinecarboxyL

Methyl4-Chloro-2-pyridinecarboxylate&gt

4-chloropyridine-2-formate

Methyl 4-chloropicolinate ISO 9001：2015 REACH

24484-93-3

24482-93-3

pharmacetical

Pyridine

Aromatics Compounds

Aromatics

Bases & Related Reagents

Nucleotides

Pharmaceutical intermediate

blocks

Carboxes

Pyridines

Acids and Derivatives

Heterocycles

Picolinic acid series

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