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TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE

Product Name
TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE
CAS No.
150008-24-5
Chemical Name
TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE
Synonyms
tert-Butyl 4-(hydroxyimino);1-Boc-4-(hydroxyimino)piperidine;N-BOC-4-(hydroxyimino)piperidine;tert-butyl 4-(hydroxyimino)piperidin-1-carboxylate;TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE;4-Hydroxyimino-piperidine-1-carboxylic acid tert-butyl ester;1-Piperidinecarboxylic acid, 4-(hydroxyiMino)-, 1,1-diMethylethyl ester
CBNumber
CB22464657
Molecular Formula
C10H18N2O3
Formula Weight
214.26
MOL File
150008-24-5.mol
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TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE Property

storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
Appearance
Off-white to yellow Solid
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
B809913
Product name
tert-Butyl4-(hydroxyimino)piperidine-1-carboxylate
Packaging
50mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
W3277
Product name
tert-Butyl4-(hydroxyimino)piperidine-1-carboxylate
Packaging
1g
Price
$70
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0385380
Product name
TERT-BUTYL-4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE
Purity
95.00%
Packaging
5MG
Price
$497.62
Updated
2021/12/16
Alichem
Product number
150008245
Product name
tert-Butyl4-(hydroxyimino)piperidine-1-carboxylate
Packaging
100g
Price
$587.07
Updated
2021/12/16
Atlantic Research Chemicals
Product number
XS037165
Product name
tert-Butyl4-(Hydroxyimino)piperidine-1-carboxylate
Purity
95%
Packaging
10gm:
Price
$636.22
Updated
2021/12/16
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TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE Chemical Properties,Usage,Production

Uses

tert-Butyl 4-(hydroxyimino)piperidine-1-carboxylate is a useful intermediate for organic synthesis.

Synthesis

79099-07-3

150008-24-5

The general procedure for the synthesis of 4-oxime-1-Boc-piperidine using N-Boc-4-piperidone as starting material is as follows: 1 equiv. of N-Boc-4-piperidone, 1.6 equiv. of hydroxylamine hydrochloride, and 2.0 equiv. of sodium acetate were dissolved in an aqueous methanol solution, mixed homogeneously, and then heated to reflux the reaction. Upon completion of the reaction, the target product 4-oxime-1-Boc-piperidine was obtained in quantitative yield. The synthetic method was applicable for the preparation of all oxime substrates in this study.

References

[1] Bioorganic and Medicinal Chemistry Letters, 2010, vol. 20, # 9, p. 2942 - 2945
[2] Tetrahedron Letters, 2010, vol. 51, # 24, p. 3216 - 3217
[3] Tetrahedron Letters, 2011, vol. 52, # 10, p. 1074 - 1077
[4] Patent: EP1477490, 2004, A1. Location in patent: Page 109
[5] Patent: WO2008/150447, 2008, A1. Location in patent: Page/Page column 206

TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE Suppliers

China 44 India 1 Switzerland 1 United States 7 Global 53
Achemica
Tel
--
Fax
--
Email
contact@achemica.com
Country
Switzerland
ProdList
6155
Advantage
50
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View Lastest Price from TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE manufacturers

Career Henan Chemical Co
Product
TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE 150008-24-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-01-08

150008-24-5, TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATERelated Search:

tert-Butyl 4-bromobutanoate TERT-BUTYL 4-CYANO-4-(PYRIDIN-2-YL)PIPERIDINE-1-CARBOXYLATE 5-BROMO-3-IODOINDOLE-1-CARBOXYLIC ACID TERT-BUTYL ESTER tert-butyl 3,8-diazabicyclo[3.2.1]octane-3-carboxylate tert-Butyl 2,6-dichloroisonicotinate tert-Butyl methacrylate tert-Butyl N-((2S,1S)-2-hydroxycyclohexyl)carbamate TERT-BUTYL 4-OXO-3,4-DIHYDROQUINOLINE-1(2H)-CARBOXYLATE tert-Butyl 4-(4-bromophenoxy)piperidine-1-carboxylate ethyl 4-(hydroxyimino)piperidine-1-carboxylate TERT-BUTYL 5-(HYDROXYIMINO)-2-AZABICYCLO[2.2.1]HEPTANE-2-CARBOXYLATE TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE

  • TERT-BUTYL 4-(HYDROXYIMINO)PIPERIDINE-1-CARBOXYLATE
  • 1-Piperidinecarboxylic acid, 4-(hydroxyiMino)-, 1,1-diMethylethyl ester
  • 1-Boc-4-(hydroxyimino)piperidine
  • tert-Butyl 4-(hydroxyimino)
  • N-BOC-4-(hydroxyimino)piperidine
  • 4-Hydroxyimino-piperidine-1-carboxylic acid tert-butyl ester
  • tert-butyl 4-(hydroxyimino)piperidin-1-carboxylate
  • 150008-24-5