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(S)-Oxiranemethanol

Product Name
(S)-Oxiranemethanol
CAS No.
60456-23-7
Chemical Name
(S)-Oxiranemethanol
Synonyms
LUBE-012;S-Glycidoe;(S)-GLYCIDOL;(-)-Glycidol;(S)-(-)-GLYCIDOL;(s)-oxiranemethano;RARECHEM AK HZ 0047;(S)-Oxiranemethanol;(S)-(-)-Glycidol>(S)-Glycidol,99%e.e.
CBNumber
CB2247179
Molecular Formula
C3H6O2
Formula Weight
74.08
MOL File
60456-23-7.mol
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(S)-Oxiranemethanol Property

Melting point:
72-73 °C
alpha 
-15 º (neat)
Boiling point:
66-67 °C19 mm Hg(lit.)
Density 
1.116 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.433(lit.)
Flash point:
178 °F
storage temp. 
-20°C
solubility 
Soluble in chloroform, DMSO and methanol.
pka
14.62±0.10(Predicted)
form 
Liquid
color 
Pale yellow
optical activity
[α]20/D 15°, neat
BRN 
79783
InChIKey
CTKINSOISVBQLD-VKHMYHEASA-N
CAS DataBase Reference
60456-23-7(CAS DataBase Reference)
NIST Chemistry Reference
Oxiranemethanol, (S)-(60456-23-7)
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Safety

Hazard Codes 
T
Risk Statements 
45-60-21/22-23-36/37/38-68-41-37/38
Safety Statements 
53-45-36/37/39-26
RIDADR 
UN 2810 6.1/PG 2
WGK Germany 
3
RTECS 
RR0508100
F 
10-21
HazardClass 
6.1
PackingGroup 
III
HS Code 
29109000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H330Fatal if inhaled

H335May cause respiratory irritation

H341Suspected of causing genetic defects

H350May cause cancer

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
474789
Product name
(S)-(?)-Glycidol
Purity
97%, optical purity ee: 98% (GLC)
Packaging
1g
Price
$23.4
Updated
2024/03/01
Sigma-Aldrich
Product number
474789
Product name
(S)-(?)-Glycidol
Purity
97%, optical purity ee: 98% (GLC)
Packaging
5g
Price
$111
Updated
2024/03/01
TCI Chemical
Product number
G0364
Product name
(S)-(-)-Glycidol
Purity
>96.0%(GC)
Packaging
5g
Price
$64
Updated
2024/03/01
TCI Chemical
Product number
G0364
Product name
(S)-(-)-Glycidol
Purity
>96.0%(GC)
Packaging
25g
Price
$249
Updated
2024/03/01
Alfa Aesar
Product number
H63502
Product name
(S)-(-)-Glycidol, 99+%, ee 99+%
Packaging
1g
Price
$26.65
Updated
2024/03/01
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(S)-Oxiranemethanol Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Employed in the synthesis of chiral (E)-allylic alcohol side-chains for introduction into prostacyclin and prostaglandin frameworks by cross-metathesis.

Definition

ChEBI: (S)-glycidol is a glycidol. It is functionally related to a (S)-1,2-epoxypropane. It is an enantiomer of a (R)-glycidol.

General Description

Glycidol or 2,3-epoxy-1-propanol is a highly reactive epoxy derivative, which is generally used as a monomer in the preparation of many polymers like polyesters,?polycarbonates,?polyurethanes,?and polyamides. It is also used in the preparation of detergents, rubbers, perfumes, fabric dyes, varnishes, cosmetics, and paints.

Purification Methods

[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.

(S)-Oxiranemethanol Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-Glycidyl butyrate (R)-(-)-Methyl glycidyl ether 2-(AMINOMETHYL)CYCLOPROPANECARBOXYLIC ACID (R)-(-)-Benzyl glycidyl ether (2R)-(-)-Glycidyl tosylate
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(S)-Oxiranemethanol Suppliers

Americas 1 Belgium 1 China 216 Europe 5 Germany 4 India 15 Japan 1 South Korea 2 Switzerland 1 United Kingdom 13 United States 43 Global 302
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
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View Lastest Price from (S)-Oxiranemethanol manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
(S)-Oxiranemethanol 60456-23-7
Price
US $0.10/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
1000Tons
Release date
2024-07-12
Hebei Weibang Biotechnology Co., Ltd
Product
(S)-Oxiranemethanol 60456-23-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2023-02-14
Career Henan Chemical Co
Product
(S)-Oxiranemethanol 60456-23-7
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000KG
Release date
2019-08-31

60456-23-7, (S)-OxiranemethanolRelated Search:

Ethylene glycol diglycidyl ether DIGLYCIDYL ETHER 1-Propanol Phenolic epoxy resin ETHYLENE OXIDE 1,2,3-PROPANETRIOL GLYCIDYL ETHER Methanol GLYCIDALDEHYDE Glycidyl phenyl ether Resin epoxy Propylene oxide Isopropyl alcohol GLYCIDAMIDE CHLOROPHOSPHONAZO III Allyl glycidyl ether BISPHENOL A DIGLYCIDYL ETHER RESIN (2R)-(-)-Glycidyl tosylate (2R)-(-)-2-METHYLGLYCIDYL 4-NITROBENZOATE

  • (S)-(-)-GLYCIDOL ((S)-(-)-2,3-EPOXY-1-PROPANOL)
  • [(2r)-oxiran-2-yl]methanol
  • (S)-(-)-GLYCIDOL, 97% (98% EE/GLC)
  • S-Glycidoe
  • (R)-3-Hydroxy-1,2-epoxypropane
  • (S)-(-)-2,3-Epoxy-1-propanol, (S)-(-)-Oxirane-2-methanol
  • (S)-(-)-Glycidol, (98% ee), 97%
  • (2S)-(-)-3-Hydroxy-1,2-propenoxide 97%
  • (2S)-Oxiran-2-ylmethanol, (2S)-(-)-2,3-Epoxypropan-1-ol
  • (S)-oxiran-2-ylMethanol
  • (S)-(-)-1-Hydroxy-2,3-epoxypropane (S)-(-)-2-(Hydroxymethyl)oxirane
  • (S)-(-)-Glycidol, 97%, (98% ee)
  • (S)-()-Glycidol,(S)-()-2,3-Epoxy-1-propanol, (S)-()-Oxirane-2-methanol
  • (S)-(-)-Glycidol 97%, optical purity ee: 98% (GLC)
  • 2-OxiraneMethanol,(2S)-
  • (S)-Glycidol,99%e.e.
  • (S)-(-)-Glycidol, ee ≥99%
  • RARECHEM AK HZ 0047
  • (S)-(-)-2,3-EPOXY-1-PROPANOL
  • (S)-(-)-GLYCIDOL
  • (S)-GLYCIDOL
  • (S)-Oxiranemethanol
  • S(-)-OXIRANE-2-METHANOL
  • OXIRANEMETHANOL, (2S)-
  • (s)-oxiranemethano
  • Oxiranemethanol,(S)-
  • LUBE-012
  • (S)-(-)-Glycidol&gt
  • (S)-(-)-1-Hydroxy-2,3-epoxypropane
  • S(-)Glycidol, puriss, 98%
  • [(2S)-oxiran-2-yl]methanol
  • (-)-Glycidol
  • Levodropropizine Impurity 4
  • 60456-23-7
  • Organic Building Blocks
  • Epoxides
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Chiral Compound
  • CHIRAL COMPOUNDS
  • chiral
  • API intermediates