2-Bromopropionic acid

Product Name: 2-Bromopropionic acid
CAS No.: 598-72-1
Chemical Name: 2-Bromopropionic acid
Synonyms: 2-BROMOPROPANAMIDE;(S)-2-BROMOPROPANOIC ACID;A-BROMOPROPIONIC ACID;ALPHA-BROMOPROPIONIC ACID;2-broMide;3-(3-(4'2-Bromopropion;-Bromo-[1,1'DL-2-Bromopropionic;RARECHEM AL BO 1266
CBNumber: CB2260767
Molecular Formula: C3H5BrO2
Formula Weight: 152.97
MOL File: 598-72-1.mol

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2-Bromopropionic acid Property

Melting point:: 25.7°C
Boiling point:: 203 °C (lit.)
Density: 1.7 g/mL at 25 °C (lit.)
refractive index: n20/D 1.475(lit.)
Flash point:: 212 °F
storage temp.: room temp
form: Liquid After Melting
pka: pK1: 2.971 (25°C)
Specific Gravity: 1.7
color: Clear colorless to yellow
Water Solubility: soluble
BRN: 605451
Dielectric constant: 11.0
NIST Chemistry Reference: 2-Bromopropanoic acid(598-72-1)
EPA Substance Registry System: Propanoic acid, 2-bromo- (598-72-1)

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Safety

Hazard Codes: C,Xi,F
Risk Statements: 22-34-40-36/37/38-38-11
Safety Statements: 26-36/37/39-45-36-16-24-9
RIDADR: UN 3265 8/PG 2
WGK Germany: 3
RTECS: UA2451715
TSCA: Yes
HazardClass: 8
PackingGroup: II
HS Code: 29159080

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: B78300
Product name: 2-Bromopropionic acid
Purity: 99%
Packaging: 1kg
Price: $217
Updated: 2024/03/01

Sigma-Aldrich

Product number: 47645
Product name: 2-Bromopropionic acid solution
Purity: certified reference material, 1000?μg/mL in methyl tert-butyl ether
Packaging: 1mL
Price: $37.2
Updated: 2022/05/15

TCI Chemical

Product number: B0644
Product name: 2-Bromopropionic Acid
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $20
Updated: 2024/03/01

TCI Chemical

Product number: B0644
Product name: 2-Bromopropionic Acid
Purity: >98.0%(GC)(T)
Packaging: 500g
Price: $73
Updated: 2024/03/01

Alfa Aesar

Product number: A17569
Product name: 2-Bromopropionic acid, 98%
Packaging: 250g
Price: $66
Updated: 2024/03/01

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2-Bromopropionic acid Chemical Properties,Usage,Production

Chemical Properties

clear colorless to yellowish liquid after melting. soluble in water, miscible with alcohol, ether, chloroform and benzene.

Uses

It is employed as pharmaceutical and agrochemical intermediate. It is used as an alkylation agent for mercaptans and other sulfur containing compounds.

Uses

2-Bromopropionic Acid is a versatile reactant used in emulsion polymerization in the preparation of reversible addition-fragmentation chain transfer (RAFT) agent.

Application

2-bromopropionic acid is an organic synthesis intermediate, used in the production of herbicides quizalofop-ethyl, napropamide, fenthiaprop and fungicides metalaxyl, benalaxyl, procymidone, etc., used in the synthesis of pharmaceutical intermediates body alanine.

Preparation

2-Bromopropionic acid is obtained by bromination of propionic acid. Add propionic acid and phosphorus trichloride to the reaction kettle, keep the temperature at 80°C, slowly add bromine to the reaction solution dropwise, and heat up to 85°C after the addition of bromine, and raise the temperature to 100°C when the color of bromine disappears completely, it takes about 2~3h, and then the bromine and hydrobromic acid are recovered under reduced pressure, and then the finished product is obtained by distillation under reduced pressure.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 4067, 1972 DOI: 10.1016/S0040-4039(01)94239-X

2-Bromopropionic acid Preparation Products And Raw materials

Raw materials

Propionic acid Phosphorus trichloride

Preparation Products

L-Alanine 2-Phenoxypropionic acid NAPROANILIDE

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View Lastest Price from 2-Bromopropionic acid manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: 2-Bromopropionic acid 598-72-1
Price: US $0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-10-12

Hebei Yanxi Chemical Co., Ltd.

Product: 2-Bromopropionic acid 598-72-1
Price: US $0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20tons
Release date: 2023-10-12

Hebei Weibang Biotechnology Co., Ltd

Product: 2-Bromopropionic acid 598-72-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-24

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