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Methyl 4-ketocyclohexanecarboxylate

Product Name
Methyl 4-ketocyclohexanecarboxylate
CAS No.
6297-22-9
Chemical Name
Methyl 4-ketocyclohexanecarboxylate
Synonyms
4-OXO-CYCLOHEXANECARBOXYLIC ACID METHYL ESTER;NSC 17321;4-carbomethoxycyclohexanone;4-(Methoxycarbonyl)cyclohexanone;Methyl 4-cyclohexanonecarboxylate;methyl 4-oxocyclohexancarboxylate;Methyl cyclohexanone-4-carboxylate;METHYL 4-KETOCYCLOHEXANECARBOXYLATE;4-CYCLOHEXANE CARBOXYLIC ACID METHYL ESTER;4-Oxocyclohexane-1-carboxylic acid methyl ester
CBNumber
CB2282868
Molecular Formula
C8H12O3
Formula Weight
156.18
MOL File
6297-22-9.mol
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Methyl 4-ketocyclohexanecarboxylate Property

Boiling point:
96-97 °C(Press: 8.0 Torr)
Density 
1.11g/ml
storage temp. 
Inert atmosphere,Room Temperature
solubility 
soluble in Chloroform, Methanol
form 
Oil
color 
Clear Colourless
InChI
InChI=1S/C8H12O3/c1-11-8(10)6-2-4-7(9)5-3-6/h6H,2-5H2,1H3
InChIKey
BLYKGTCYDJZLFB-UHFFFAOYSA-N
SMILES
C1(C(OC)=O)CCC(=O)CC1
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Safety

HS Code 
2918300090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M315045
Product name
Methyl4-Oxocyclohexanecarboxylate
Packaging
2g
Price
$165
Updated
2021/12/16
Matrix Scientific
Product number
114724
Product name
Methyl 4-oxocyclohexanecarboxylate
Purity
97%
Packaging
5g
Price
$188
Updated
2021/12/16
AK Scientific
Product number
W7499
Product name
Methyl4-oxocyclohexanecarboxylate
Packaging
5g
Price
$49
Updated
2021/12/16
Matrix Scientific
Product number
114724
Product name
Methyl 4-oxocyclohexanecarboxylate
Purity
97%
Packaging
1g
Price
$57
Updated
2021/12/16
AK Scientific
Product number
W7499
Product name
Methyl4-oxocyclohexanecarboxylate
Packaging
10g
Price
$81
Updated
2021/12/16
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Methyl 4-ketocyclohexanecarboxylate Chemical Properties,Usage,Production

Uses

Methyl 4-Oxocyclohexanecarboxylate is an intermediate for preparation of imidazobenzazepine derivatives as dual H1/5-HT2A antagonists for treatment of sleep disorders.

Synthesis

The 4-hydroxy methyl ester (4.147 g; 26.21 mmol) was dissolved in 150 mL DCM, and pyridinium chlorochromate (PCC) (8.476 g; 39.32 mmol) was added. The reaction mixture was allowed to stir at room temperature overnight. The reaction mixture was diluted with ether and decanted. Solvents were removed, and the residue was purified by flash column chromatography using 25 percent EtOAc in a hexane mixture as eluent. The product Methyl 4-ketocyclohexanecarboxylate was obtained as a colorless oil.

Methyl 4-ketocyclohexanecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 4-ketocyclohexanecarboxylate Suppliers

Leancare Ltd.
Tel
--
Fax
--
Email
enquiry@leancare.co.uk
Country
United Kingdom
ProdList
6446
Advantage
42
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View Lastest Price from Methyl 4-ketocyclohexanecarboxylate manufacturers

Career Henan Chemical Co
Product
Methyl 4-ketocyclohexanecarboxylate 6297-22-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2020-01-02

6297-22-9, Methyl 4-ketocyclohexanecarboxylateRelated Search:


  • METHYL 4-KETOCYCLOHEXANECARBOXYLATE
  • Cyclohexanecarboxylic acid, 4-oxo-, methyl ester
  • methyl 4-oxocyclohexancarboxylate
  • 4-Oxocyclohexane-1-carboxylic acid methyl ester
  • 4-OXO-CYCLOHEXANECARBOXYLIC ACID METHYL ESTER
  • 4-CYCLOHEXANE CARBOXYLIC ACID METHYL ESTER
  • Methyl cyclohexanone-4-carboxylate
  • 4-(Methoxycarbonyl)cyclohexanone
  • NSC 17321
  • 4-carbomethoxycyclohexanone
  • Methyl 4-cyclohexanonecarboxylate
  • Cyclohexanecarboxylic acid, 4-oxo-, methyl este
  • 6297-22-9
  • Drug Intermediates
  • Intermediates
  • Miscellaneous Reagents