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Bis[4-(2-phenyl-2-propyl)phenyl]amine

Product Name
Bis[4-(2-phenyl-2-propyl)phenyl]amine
CAS No.
10081-67-1
Chemical Name
Bis[4-(2-phenyl-2-propyl)phenyl]amine
Synonyms
KY-405;AO-405;Connguard 445;JADEWIN AN 405;Antioxidant 445;Antioxidant 405;4,4'-Bis(αAntioxidang 405;antioxidantky-405;4-(269-Butyl)phenol
CBNumber
CB2335797
Molecular Formula
C30H31N
Formula Weight
405.57
MOL File
10081-67-1.mol
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Bis[4-(2-phenyl-2-propyl)phenyl]amine Property

Melting point:
100°C
Boiling point:
535.2±39.0 °C(Predicted)
Density 
1.061±0.06 g/cm3(Predicted)
vapor pressure 
6.67hPa at 20℃
storage temp. 
Sealed in dry,Room Temperature
solubility 
Practically insoluble in water
form 
powder to crystal
pka
1.59±0.50(Predicted)
color 
White to Almost white
Water Solubility 
6.7μg/L at 20℃
InChI
InChI=1S/C30H31N/c1-29(2,23-11-7-5-8-12-23)25-15-19-27(20-16-25)31-28-21-17-26(18-22-28)30(3,4)24-13-9-6-10-14-24/h5-22,31H,1-4H3
InChIKey
UJAWGGOCYUPCPS-UHFFFAOYSA-N
SMILES
C1(NC2=CC=C(C(C)(C3=CC=CC=C3)C)C=C2)=CC=C(C(C)(C2=CC=CC=C2)C)C=C1
LogP
7.9 at 25℃
CAS DataBase Reference
10081-67-1(CAS DataBase Reference)
EPA Substance Registry System
Benzenamine, 4-(1-methyl-1-phenylethyl)-N-[4-(1-methyl-1-phenylethyl)phenyl]- (10081-67-1)
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Safety

Risk Statements 
36/37/38-53
Safety Statements 
26-36/37/39
HS Code 
29214990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B1970
Product name
4,4'-Bis(alpha,alpha-dimethylbenzyl)diphenylamine
Purity
>98.0%(GC)
Packaging
25g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
B1970
Product name
4,4'-Bis(alpha,alpha-dimethylbenzyl)diphenylamine
Purity
>98.0%(GC)
Packaging
500g
Price
$142
Updated
2024/03/01
AK Scientific
Product number
R277
Product name
4,4'-Bis(phenylisopropyl)diphenylamine
Packaging
25g
Price
$28
Updated
2021/12/16
Arctom
Product number
AS018116
Product name
4,4-Bis(α,α-dimethylbenzyl)diphenylamine
Purity
98%
Packaging
5g
Price
$9
Updated
2021/12/16
Arctom
Product number
AS018116
Product name
4,4-Bis(α,α-dimethylbenzyl)diphenylamine
Purity
98%
Packaging
25g
Price
$17
Updated
2021/12/16
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Bis[4-(2-phenyl-2-propyl)phenyl]amine Chemical Properties,Usage,Production

Description

4,4'-Diphenylisopropyl diphenylamine (Antioxidant HS-911) is a kind of high-efficient nontoxic Antioxidant to replace D, A, RD and so on which are carcinogenic. HS-911 can be used in NR, IIR, SBR, NBR, BR, CR and their blend, and is especially efficient in protecting CR from thermal aging. It can also be used in plastic industry. HS-911 not only can protect vulcanized rubber from thermal aging, light aging, ozone aging and damage caused by repeating deformation, but also has a passivating effect on heavy metal and transition metal.

Uses

Because of its light contamination, HS-911 can be used in insulative and protective rubber sheeting for color wires and cables as well as common color rubber products in place of Antioxidant 264, SP, 2264, MB, DNP, etc, to greatly reduce the production cost. In carbon black rubber, it has oxidation resistance of amine type, and will not pollute products. HS-911 can be exclusively used or used together with other Antioxidant . Normal dosage in rubber is 2-3 phr.

Application

Diphenylamine antioxidant CAPOX 445, 4, 4'-Bis (alpha, alpha-dimethylbenzyl) diphenylamine, is a highly effective non-discoloring aromatic amine type antioxidant finding utility as a thermal stabilizer in a wide variety of applications, including polyolefins, styrenics, polyols, hot melt adhesives, lubricants and polyamides. Excellent performance at processing temperatures, and strong synergy with other types of antioxidants such as phenolics and phosphites, makes CAPOX 445 an excellent choice as a component of your thermal stabilizer package.

Flammability and Explosibility

Non flammable

Industrial uses

This product is one of the few kinds of antioxidant, which is non-toxic, tasteless, light colored. The anti- oxygen effect is similar America in Uniroyal. It is widely used in various kinds of elastomers. It can be used in polyethylene, polypropylene, polyvinyl chloride and other color master batch. It can also be used as antioxidant in polyurethane foam, rubber wire, cable, food package and adhesive, especially in neoprene colorful cable's jacket for its excellent resistance to heat, light, and aging. In polyether this product can be used as light-resistant and anti-aging antioxidant, also as antioxidant for lubricating oil.It is especially effective to be used in neoprene acrylate rubber, polyether polyalcohol for its resistance to aging caused by high temperature and light. When used together with sulfur-contained antioxidant, it has operational effect.

Synthesis


a, first raw material diphenylamine 50.0g into a reaction vessel equipped with a stirrer, reflux condenser, heated to diphenylamine added to melt;After completely melted, a mixed catalyst prepared from 1.5 g of magnesium chloride and 1.5 g of anhydrous stannous chloride was added, and heating and stirring were continued for mixing; b. After step a is mixed uniformly, 80.5 g of |á-methylstyrene is added dropwise, and the dropwise addition time is 0.5 h. After the dropwise addition is completed, the reaction temperature is controlled to be 130-140?? C., and the reaction is completed at this temperature for 1 h. The reaction is completed. ; c, after the end of the reaction, the resulting reaction solution was cooled, then add 60 of petroleum ether 140g and methanol 5g mixed solvent, dropped to 25 ?à 2 ??C cooling crystallization; d, after the end of crystallization, followed by filtration, petroleum ether and water washing, and then dried at 45 ??C for 14 hours, dried to obtain the antioxidant 4,4 '- bis (|á, |á- dimethyl benzyl) diphenylamine . The product obtained in this example was white crystal with a yield of 85% and a purity of 98.24%

Bis[4-(2-phenyl-2-propyl)phenyl]amine Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis[4-(2-phenyl-2-propyl)phenyl]amine Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
TCI Japan
Tel
--
Fax
--
Email
@TCIchemicals.com
Country
Japan
ProdList
2741
Advantage
58
Hattori Corporation
Tel
--
Fax
--
Email
info@hattoricorp.com
Country
Japan
ProdList
1254
Advantage
58
Seiko Chemical Co., Ltd.
Tel
--
Fax
--
Email
sales-dev@seiko-chem.co.jp
Country
Japan
ProdList
33
Advantage
58
OuchiShinko Chemical Industrial Co., Ltd
Tel
--
Fax
--
Email
support@jp-noc.co.jp
Country
Japan
ProdList
185
Advantage
71
Wako Pure Chemical Industries, Ltd.
Tel
--
Fax
--
Email
labchem-tec@wako-chem.co.jp
Country
Japan
ProdList
6819
Advantage
80
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View Lastest Price from Bis[4-(2-phenyl-2-propyl)phenyl]amine manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Bis[4-(2-phenyl-2-propyl)phenyl]amine 10081-67-1
Price
US $99.00-45.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-11-14
Shanghai Tiandui New Material Co., Ltd
Product
Antioxidant 445 10081-67-1
Price
US $0.00/kg
Min. Order
25kg
Purity
99%
Supply Ability
8000 Tons
Release date
2024-12-10
Hebei Weibang Biotechnology Co., Ltd
Product
Bis[4-(2-phenyl-2-propyl)phenyl]amine 10081-67-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-12-06

10081-67-1, Bis[4-(2-phenyl-2-propyl)phenyl]amineRelated Search:


  • 4-(1-methyl-1-phenylethyl)-n-[4-(1-methyl-1-phenylethyl)phenyl]-benzenamin
  • 4-(1-methyl-1-phenylethyl)-N-[4-(1-methyl-1-phenylethyl)phenyl]-Benzenamine
  • 4,4’Bis(pehnylisopropyl)diphenylamine
  • 4,4’-Dicumyl-diphenylamine
  • antioxidantky-405
  • Benzenamine,4-(1-methyl-1-phenylethyl)-N-[4-(1-methyl-1-phenylethyl)phenyl]-
  • 4,4'-BIS(ALPHA,ALPHA-DIMETHYLBENZYL)DIPHENYLAMINE
  • 4-(1-methyl-1-phenylethyl)-N-[4-(1-methyl-1-phenylethyl)phenyl]aniline
  • 4,4`-bis(phenylisopropyl)diphenylamine
  • 4,4-bis)a,a,dimethylbenzyl)diphenylamine
  • 4,4'-Bis(α,α-dimethylbenzyl) diphenylamine
  • 4,4''-BIS(ALPHA ALPHA-DIMETHYLBENZYL)DIPHENYLAMINE 98+%
  • Antioxidant 445
  • 1,1'-Iminobis[4-(2-phenylpropane-2-yl)benzene]
  • 4,4'-Bis(4-α,α-dimethylbenzyl)diphenylamine
  • Bis[4-(1-phenyl-1-methylethyl)phenyl]amine
  • Bis[4-(α,α-dimethylbenzyl)phenyl]amine
  • BIS[4-(2-PHENYL-2-PROPYL)PHENYL]AMINE
  • Bis[4-(α-cumyl)phenyl]amine
  • N-[4-(α,α-Dimethylbenzyl)phenyl]-4-(α,α-dimethylbenzyl)benzenamine
  • 4, 4'-bis (4-.alpha.,.alpha.-dimethylbenzyl) di-phenylamine
  • 4-(2-phenylpropan-2-yl)-N-[4-(2-phenylpropan-2-yl)phenyl]aniline
  • bis[4-(1-methyl-1-phenyl-ethyl)phenyl]amine
  • Antioxidant 405
  • Bis(4-(2-phenylpropan-2-yl)phenyl)aMine
  • Connguard 445
  • 4,4'-Bis(&alpha
  • -dimethylbenzyl)diphenylamine
  • 4,4'-Bis-(1,1-dimethylbenzyl)-diphenylamine
  • 4,4'-Bis(α,α-dimethylbenzyl)diphenyiamine
  • 6-(1-cyclohex-2-enyl)-1,3,5-triazine-2,4-diamine
  • KY-405
  • 4'-Bis(α,α-dimethylbenzyl)diphenylamine
  • Antioxidang 405
  • 4,4-bis(dimethylbenthylbenzyldiphenylamine (Naugard 445)
  • 4,4'-Bis(alpha,alpha-dimethylbenzyl)diphenylamine &gt
  • AO-405
  • Bis[4-(2-phenyl-2-propyl)phenyl]amine ISO 9001:2015 REACH
  • ANTIOXIDANT TRUELICHT AN445
  • JADEWIN AN 405
  • 4,4'-Bis(α,α-dimethylbenzyl)diphenylamine
  • 4-(269-Butyl)phenol
  • 4,4'-Bis(α,α-dimethylbenzyl)diphenylamine
  • 4,4-Bis(α,α-dimethylbenzyl)diphenylamine in methanol
  • 10081-67-1
  • C30H31N
  • It is especially effective in polyisoprene, Neoprene, nitrile, EPDM, HNBR and acrylic rubbers
  • Industrial/Fine Chemicals
  • Organics