ChemicalBook > CAS DataBase List > Chlorobis(cyclooctene)rhodium(I) dimer

Chlorobis(cyclooctene)rhodium(I) dimer

Product Name
Chlorobis(cyclooctene)rhodium(I) dimer
CAS No.
12279-09-3
Chemical Name
Chlorobis(cyclooctene)rhodium(I) dimer
Synonyms
[Rh(coe)2Cl]2;[RhCl(cis-cyclooctene)2]2;Chlorobis(cyclooctene)rhodium(I);CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER;Bicyclooctene rhodium chloride dimer;Chlorobis(cyclooctene)rhodium(I)dimere;CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER;Di-μ-chlorodirhodium-cyclooctene (1:4);Chlorobis(cyclooctene)rhodiuM(I),diMer 98%;Chlorobis(cyclooctene)rhodium(I) dimer,98%
CBNumber
CB2429483
Molecular Formula
C32H56Cl2Rh2
Formula Weight
717.5
MOL File
12279-09-3.mol
More
Less

Chlorobis(cyclooctene)rhodium(I) dimer Property

Melting point:
190 °C (dec.) (lit.)
storage temp. 
Freezer
form 
crystal
color 
orange to red
optical activity
-0.60°(C=0.01g/ml CHCL3)
Sensitive 
air sensitive, store cold
CAS DataBase Reference
12279-09-3
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
No
HS Code 
28439000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
302473
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
98%
Packaging
250mg
Price
$131
Updated
2025/07/31
Sigma-Aldrich
Product number
302473
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
98%
Packaging
1g
Price
$360
Updated
2025/07/31
TCI Chemical
Product number
C2253
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
>96.0%(T)
Packaging
100mg
Price
$112
Updated
2025/07/31
TCI Chemical
Product number
C2253
Product name
Chlorobis(cyclooctene)rhodium(I) Dimer
Purity
>96.0%(T)
Packaging
500mg
Price
$338
Updated
2025/07/31
Strem Chemicals
Product number
45-0265
Product name
Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
Packaging
250mg
Price
$117
Updated
2024/03/01
More
Less

Chlorobis(cyclooctene)rhodium(I) dimer Chemical Properties,Usage,Production

Chemical Properties

orange-brown powder

Uses

Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:

  • To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
  • In direct C-arylation of N-unprotected indoles and pyrroles.
  • In the carboxylation of arenes via C-H bond activation.

Uses

Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.

reaction suitability

core: rhodium
reagent type: catalyst

Chlorobis(cyclooctene)rhodium(I) dimer Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Chlorobis(cyclooctene)rhodium(I) dimer Suppliers

Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
United States Biological
Tel
--
Fax
--
Email
chemicals@usbio.net
Country
United States
ProdList
6214
Advantage
80
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Reagent World
Tel
--
Fax
--
Email
Sales@ReagentWorld.com
Country
United States
ProdList
1637
Advantage
50
Acros Organics USA
Tel
--
Fax
--
Email
eveleth@fisherchem.com
Country
United States
ProdList
3846
Advantage
81
AK Scientific, Inc.
Tel
--
Fax
--
Email
sales@aksci.com
Country
United States
ProdList
6347
Advantage
65
American Custom Chemicals Corporation
Tel
--
Fax
--
Email
sales@acccorporation.com
Country
United States
ProdList
6820
Advantage
51
OChem Incorporation
Tel
--
Fax
--
Email
sales@ocheminc.com
Country
United States
ProdList
6501
Advantage
60
Colonial Metals
Tel
--
Fax
--
Email
info@colonialmetals.com
Country
United States
ProdList
317
Advantage
61
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
More
Less

View Lastest Price from Chlorobis(cyclooctene)rhodium(I) dimer manufacturers

Longyan Tianhua Biological Technology Co., Ltd
Product
Chlorobis(cyclooctene)rhodium(I) dimer 12279-09-3
Price
US $20.00/Kg
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-11-11
Career Henan Chemical Co
Product
Chlorobis(cyclooctene)rhodium(I) dimer 12279-09-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-07-03

12279-09-3, Chlorobis(cyclooctene)rhodium(I) dimerRelated Search:


  • [RhCl(cis-cyclooctene)2]2
  • CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER
  • Chlorobis(cyclooctene)rhodium(I)
  • Chlorobis(cyclooctene)rhodium(I)dimere
  • Chlorobis(cyclooctene)rhodium(I)dimer,min.98%
  • Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
  • Chlorobis(cyclooctene)rhodium(I) dimer,98%
  • CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER
  • Chlorobis(cyclooctene)rhodiuM(I) diMer, 98% 100MG
  • Chlorobis(cyclooctene)rhodiuM(I),diMer 98%
  • [Rh(coe)2Cl]2
  • Chlorobis(cyclooctene)rhodium(I) Dimer &gt
  • Chlorobis(cyclooctene)rhodium(I) dimer ISO 9001:2015 REACH
  • Di-μ-chlorodirhodium-cyclooctene (1:4)
  • Bicyclooctene rhodium chloride dimer
  • 12279-09-3
  • RhClC8H1422
  • C32H56Cl2Rh2
  • Catalysis and Inorganic Chemistry
  • Rh
  • organometallic complex
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Rh (Rhodium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Rhodium