ChemicalBook > CAS DataBase List > Bromoacetyl chloride
Bromoacetyl chloride
- Product Name
- Bromoacetyl chloride
- CAS No.
- 22118-09-8
- Chemical Name
- Bromoacetyl chloride
- Synonyms
- JACS-22118-09-8;BROMOACETYL CHLORIDE;Acetyl chloride, bromo-;Bromoacetyl Chloride >2-bromoethanoyl chloride;Acetyl chloride, 2-bromo-;Bromoacetic acid chloride;monobromo acetyl chloride;monobromoacetic acid chloride;BroMoacetyl chloride >=95% (GC)
- CBNumber
- CB2431011
- Molecular Formula
- C2H2BrClO
- Formula Weight
- 157.39
- MOL File
- 22118-09-8.mol
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Bromoacetyl chloride Property
- Boiling point:
- 127-128 °C (lit.)
- Density
- 1.89 g/mL at 20 °C
- refractive index
- n20/D 1.495
- storage temp.
- 2-8°C
- form
- Liquid
- color
- Clear yellow to brown
- BRN
- 1209323
- CAS DataBase Reference
- 22118-09-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Bromoacetyl chloride(22118-09-8)
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Safety
- Hazard Codes
- C
- Risk Statements
- 14-34-37
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3265 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29159000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 16120
- Product name
- Bromoacetyl chloride
- Purity
- ≥95% (GC)
- Packaging
- 25ml
- Price
- $105
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 16120
- Product name
- Bromoacetyl chloride
- Purity
- ≥95% (GC)
- Packaging
- 100ml
- Price
- $330
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B0900
- Product name
- Bromoacetyl Chloride
- Purity
- >85.0%(GC)
- Packaging
- 25g
- Price
- $61
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B0900
- Product name
- Bromoacetyl Chloride
- Purity
- >85.0%(GC)
- Packaging
- 500g
- Price
- $493
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 16120
- Product name
- Bromoacetyl chloride
- Purity
- ≥95% (GC)
- Packaging
- 500ml
- Price
- $1190
- Updated
- 2023/06/20
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Bromoacetyl chloride Chemical Properties,Usage,Production
Chemical Properties
Clear yellow liquid
Mechanism of action
Bromoacetyl chloride photodissociation has been interpreted as a typical process in which nonadiabatic effects play a dominant role. Stationary points (minima and saddle points) and minimum energy paths are characterized on the S0 and S1 potential energy surfaces. The five adiabatic excited electronic states are converted to a nonadiabatic representation using a quadruple-path nonadiabatic approach. The nonadiabatic potential energy matrix of the first five excited singlet states is constructed along several cuts of the potential energy hypersurface. The thermochemical properties of the photodissociation reaction and the comparison with experimental translational energy profiles strongly suggest that nonadiabatic effects dominate the C-Br cleavage, but the reaction proceeds along an energetically allowed nonadiabatic path to excited state products rather than being nonadiabatically inhibited. This conclusion is also supported by the low values of nonadiabatic coupling along the C-Br cleavage reaction path[1].
Uses
Bromoacetyl chloride was used in the synthesis of α,α-disubstituted thioisomünchnones. It was also used in the preparation of 1,3-dibromoacetone.
General Description
The competitive photodissociation of bromoacetyl chloride has been studied by ab initio methods.
Precautions
readily hydrolyzed with formation of HCl; corrosive; lachrymator. This reagent should only be handled in a fume hood.
References
[1] ROSENDO VALERO; Donald G T. Nonadiabatic effects in C-Br bond scission in the photodissociation of bromoacetyl chloride.[J]. Journal of Chemical Physics, 2006, 125 19: 194305. DOI:10.1063/1.2363991.
Bromoacetyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Bromoacetyl chloride manufacturers
Hebei Yanxi Chemical Co., Ltd.
- Product
- Bromoacetyl chloride 22118-09-8
- Price
- US $20.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 30 tons
- Release date
- 2023-10-16
Henan Aochuang Chemical Co.,Ltd.
- Product
- Bromoacetyl chloride 22118-09-8
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-12
Career Henan Chemical Co
- Product
- Bromoacetyl chloride 22118-09-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98% HPLC
- Supply Ability
- 10 tons/month
- Release date
- 2020-01-08
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