6-Bromo-2-naphthoic acid

Product Name: 6-Bromo-2-naphthoic acid
CAS No.: 5773-80-8
Chemical Name: 6-Bromo-2-naphthoic acid
Synonyms: RAVI-001;6-Bromo-2-naphthoic;6-BROMO-2-NAPHTHALENE;6-Bromo-2-phthoic acid;6-BROMO-2-NAPHTHOIC ACID;6-BROMO-2-NAPHTHIOC ACID;6-BROMO-2-NAPHTHOLIC AICD;6-BROMO-2-NAPHTHOLIC ACID;6-Bromo-2-naphthoicacid,96%;6-BROMO-2-NAPHTHOIC ACID 99%
CBNumber: CB2467951
Molecular Formula: C11H7BrO2
Formula Weight: 251.08
MOL File: 5773-80-8.mol

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6-Bromo-2-naphthoic acid Property

Melting point:: 294-295°C
Boiling point:: 387.3±17.0 °C(Predicted)
Density: 1.648±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: DMSO (Slightly), Methanol (Slightly)
form: powder to crystal
pka: 4.06±0.30(Predicted)
color: White to Light yellow
Water Solubility: Insoluble in water.
BRN: 2328940
InChI: InChI=1S/C11H7BrO2/c12-10-4-3-7-5-9(11(13)14)2-1-8(7)6-10/h1-6H,(H,13,14)
InChIKey: NPMCAVBMOTZUPD-UHFFFAOYSA-N
SMILES: C1=C2C(C=C(Br)C=C2)=CC=C1C(O)=O
CAS DataBase Reference: 5773-80-8(CAS DataBase Reference)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-20/21/22
Safety Statements: 26-36/37/39-36
HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: CDS004635
Product name: 6-Bromo-2-naphthoic acid
Purity: Aldrich<SUP>CPR</SUP>
Packaging: 100 mg
Price: $73.1
Updated: 2025/07/31

TCI Chemical

Product number: B3823
Product name: 6-Bromo-2-naphthoic Acid
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $51
Updated: 2025/07/31

TCI Chemical

Product number: B3823
Product name: 6-Bromo-2-naphthoic Acid
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $201
Updated: 2025/07/31

TRC

Product number: B685930
Product name: 6-Bromo-2-napthoicAcid
Packaging: 25g
Price: $695
Updated: 2021/12/16

Matrix Scientific

Product number: 068817
Product name: 6-Bromo-2-naphthoic acid
Purity: >95%
Packaging: 1g
Price: $10
Updated: 2021/12/16

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6-Bromo-2-naphthoic acid Chemical Properties,Usage,Production

Chemical Properties

Pale brown solid

Uses

Benzimidazole derivatives has been prepared by using ortho-phenyl diamine and 6-bromo-2-naphthoic acid.

Synthesis

33626-98-1

5773-80-8

Methyl 6-bromo-2-naphthalenecarboxylate (3b) (2.7 g, 10.0 mmol) was used as a raw material to form a suspension with potassium hydroxide (1.1 g, 20.0 mmol) in methanol (50 mL) at 50 °C with vigorous stirring. At the beginning of the reaction, the suspension gradually changed to a homogeneous solution, indicating that the raw material was completely consumed. After the reaction lasted for 8 hours, about 2/3 of the volume of solvent was removed by evaporation under reduced pressure. Subsequently, water (1500 mL) was added to the residue and the unreacted esters were extracted with ethyl acetate. The aqueous phase was acidified to pH 3 with 10% H2SO4 and subsequently extracted with ethyl acetate (3 x 200 mL). The organic phases were combined, dried over anhydrous sodium sulfate and concentrated under reduced pressure to give pure 6-bromo-2-naphthalenecarboxylic acid (3a) (2.1 g, 8.4 mmol, 84% yield). The melting point of the product was 290-294 °C (decomposition). High resolution mass spectrum (ESI+): m/z [M + 1]+ calculated value (C11H8BrO2) was 252.08591, measured value was 252.08582. 1H NMR (DMSO-d6) δ= 7.72 (1H, dd, J = 8.5 and 1.8 Hz, 7-naphthalenyl H), 7.99 (1H, d, J = 8.6 Hz, 4-naphthalenyl H) ), 8.02 (1H, dd, J = 8.6 and 1.4 Hz, 8-naphthalenyl H), 8.09 (1H, d, J = 8.8 Hz, 3-naphthalenyl H), 8.30 (1H, d, J = 1.6 Hz, 5-naphthalenyl H), 8.62 (1H, s, 1-naphthalenyl H), and 13.15 (1H, br.s, COOH).13C NMR ( 125.76 MHz, DMSO-d6) δ= 121.93, 126.50, 127.61, 128.81, 129.83, 130.01, 130.64, 130.90, 131.63, 136.11, 167.30.

References

[1] Organic and Biomolecular Chemistry, 2015, vol. 13, # 27, p. 7477 - 7486
[2] Organic and Biomolecular Chemistry, 2015, vol. 13, # 27, p. 7477 - 7486
[3] Bioorganic and Medicinal Chemistry, 2012, vol. 20, # 4, p. 1557 - 1568
[4] Bioorganic Chemistry, 2011, vol. 39, # 4, p. 151 - 158
[5] Patent: US2012/88746, 2012, A1. Location in patent: Page/Page column 47-48

6-Bromo-2-naphthoic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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6-Bromo-2-naphthoic acid Suppliers

Americas 1 Canada 3 CHINA 238 Europe 4 France 2 Germany 4 India 31 Japan 2 Ukraine 1 United Kingdom 13 United States 36 Global 335

Shandong Xingshun New Material Co., Ltd.

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View Lastest Price from 6-Bromo-2-naphthoic acid manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 6-Bromo-2-naphthoic acid 5773-80-8
Price: US $2.00-5.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons
Release date: 2025-07-10

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 6-Bromo-2-naphthoic acid 5773-80-8
Price: US $0.00/KG
Min. Order: 10KG
Purity: 98%min
Supply Ability: 500kg/month
Release date: 2023-01-09

Henan Aochuang Chemical Co.,Ltd.

Product: 6-Bromo-2-naphthoic acid 5773-80-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-10-12

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5773-80-8

C11H7O2Br

Carboxes

Naphthalene derivatives

Organic acids

Naphthalene series

blocks

Bromides