ChemicalBook > CAS DataBase List > Methyl 3-methyl-4-nitrobenzoate
Methyl 3-methyl-4-nitrobenzoate
- Product Name
- Methyl 3-methyl-4-nitrobenzoate
- CAS No.
- 24078-21-5
- Chemical Name
- Methyl 3-methyl-4-nitrobenzoate
- Synonyms
- -4-nitrobenzoate;BUTTPARK 62\04-20;Methyl 3-methyl-4-ni;Methyl 4-Nitro-m-toluate;3-methyl-4-nitro benzoate;Methyl 3-Methyl-4-nitrobe...;Methyl 3-methyl-4-nitrobenzoat;METHYL 3-METHYL-4-NITROBENZOATE;Methyl 4--Nitro-3-Methyl benzoate;Methyl3-Methyl-4-nitrobenzoate>
- CBNumber
- CB2494984
- Molecular Formula
- C9H9NO4
- Formula Weight
- 195.17
- MOL File
- 24078-21-5.mol
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Methyl 3-methyl-4-nitrobenzoate Property
- Melting point:
- 80 °C
- Boiling point:
- 318.5±30.0 °C(Predicted)
- Density
- 1?+-.0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to crystal
- color
- White to Yellow
- InChIKey
- IEFONJKJLZFGKQ-UHFFFAOYSA-N
- CAS DataBase Reference
- 24078-21-5(CAS DataBase Reference)
- NIST Chemistry Reference
- M-toluic acid, 4-nitro-, methyl ester(24078-21-5)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- S374652
- Product name
- METHYL 4-NITRO-3-METHYLBENZOATE
- Purity
- Aldrich<sup>CPR</sup>
- Packaging
- 1 unit
- Price
- $42.8
- Updated
- 2025/07/31
Sigma-Aldrich
- Product number
- S374652
- Product name
- METHYL 4-NITRO-3-METHYLBENZOATE
- Purity
- Aldrich
- Packaging
- 250mg
- Price
- $41.5
- Updated
- 2024/03/01
TCI Chemical
- Product number
- M2145
- Product name
- Methyl 3-Methyl-4-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $46
- Updated
- 2025/07/31
TCI Chemical
- Product number
- M2145
- Product name
- Methyl 3-Methyl-4-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $135
- Updated
- 2025/07/31
TRC
- Product number
- B451518
- Product name
- Methyl 3-Methyl-4-nitrobenzoate
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
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Methyl 3-methyl-4-nitrobenzoate Chemical Properties,Usage,Production
Chemical Properties
Off-white or light yellow powder
Uses
The presence of the nitro group contributes to its potential reactivity and polar nature, while the methyl ester group enhances its solubility in organic solvents. Methyl 3-methyl-4-nitrobenzoate is often used in organic synthesis and may serve as an intermediate in the production of various pharmaceuticals and agrochemicals.
Synthesis
67-56-1
3113-71-1
24078-21-5
Step 1. Synthesis of methyl 3-methyl-4-nitrobenzoate 3-Methyl-4-nitrobenzoic acid (30 g, 165.61 mmol) was dissolved in methanol (300 mL), stirred at 0°C and thionyl chloride (25 mL) was added slowly and dropwise. The reaction mixture was warmed to 80°C and stirring was continued for 1 hour. Upon completion of the reaction, the mixture was concentrated under reduced pressure to give the crude product. The crude product was dissolved in petroleum ether (100 mL) and filtered to give methyl 3-methyl-4-nitrobenzoate as a white solid (31 g, 96% yield). Product Characterization: LC/MS (ES, m/z): [M + H]+ 196.01 1H-NMR (300MHz, CD3Cl) δ 7.99-8.04 (m, 3H), 3.98 (s, 3H), 2.64 (s, 3H)
References
[1] Patent: US2012/277224, 2012, A1. Location in patent: Page/Page column 33
[2] Chemical Communications, 2012, vol. 48, # 94, p. 11558 - 11560
[3] Chemical Communications, 2007, # 5, p. 504 - 506
[4] Bioorganic and Medicinal Chemistry, 2012, vol. 20, # 14, p. 4582 - 4589
[5] Chemistry - An Asian Journal, 2010, vol. 5, # 7, p. 1573 - 1585
Methyl 3-methyl-4-nitrobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 3-methyl-4-nitrobenzoate manufacturers
Shaanxi Dideu New Materials Co. Ltd
- Product
- Methyl 3-methyl-4-nitrobenzoate 24078-21-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-05-13
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- Methyl 3-methyl-4-nitrobenzoate 24078-21-5
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-29
Hebei Chuanghai Biotechnology Co., Ltd
- Product
- Methyl 3-methyl-4-nitrobenzoate 24078-21-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-30
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