Synthesis
ChemicalBook > CAS DataBase List > 4-Methyl-3-nitrobenzoic acid methyl ester

4-Methyl-3-nitrobenzoic acid methyl ester

Synthesis
Product Name
4-Methyl-3-nitrobenzoic acid methyl ester
CAS No.
7356-11-8
Chemical Name
4-Methyl-3-nitrobenzoic acid methyl ester
Synonyms
NSC29086;NSC 29086;ST5331831;ZINC01651943;632171_ALDRICH;EINECS 230-886-6;RARECHEM AL BF 0233;Telmisartan Impurity 29;METHYL 4-METHYL-3-NITROBENZOATE;METHYL 3-NITRO-4-METHYLBENZOATE
CBNumber
CB5337101
Molecular Formula
C9H9NO4
Formula Weight
195.17
MOL File
7356-11-8.mol
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4-Methyl-3-nitrobenzoic acid methyl ester Property

Melting point:
49-53°C
Boiling point:
298.0±20.0 °C(Predicted)
Density 
1?+-.0.06 g/cm3(Predicted)
Flash point:
110 °C
storage temp. 
Sealed in dry,Room Temperature
solubility 
Soluble in methanol.
form 
powder to crystal
color 
White to Light yellow
CAS DataBase Reference
7356-11-8(CAS DataBase Reference)
EPA Substance Registry System
Benzoic acid, 4-methyl-3-nitro-, methyl ester (7356-11-8)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-43
Safety Statements 
37/39
WGK Germany 
2
TSCA 
Yes
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
632171
Product name
Methyl 4-methyl-3-nitrobenzoate
Packaging
5g
Price
$69
Updated
2023/06/20
TCI Chemical
Product number
M2146
Product name
Methyl 4-Methyl-3-nitrobenzoate
Purity
>98.0%(GC)
Packaging
5g
Price
$40
Updated
2024/03/01
TCI Chemical
Product number
M2146
Product name
Methyl 4-Methyl-3-nitrobenzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$115
Updated
2024/03/01
Alfa Aesar
Product number
B25299
Product name
Methyl 4-methyl-3-nitrobenzoate, 99%
Packaging
5g
Price
$39
Updated
2021/12/16
Alfa Aesar
Product number
B25299
Product name
Methyl 4-methyl-3-nitrobenzoate, 99%
Packaging
25g
Price
$135
Updated
2021/12/16
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4-Methyl-3-nitrobenzoic acid methyl ester Chemical Properties,Usage,Production

Synthesis

Methyl 4-methyl-3-nitrobenzoate is synthesized by the following steps:Acid 33 (100 g, 0.552 mol) was dissolved in MeOH (1000 ml). Conc.  H2SO4 (30 ml) was added cautiously to this solution. The mixture was  refluxed for 8 hours. Solvent was distilled off. Ice-cold water was added  to the residue. It was then extracted with EtOAc, washed with NaHCO3 solution, water, dried (anhydrous Na2SO4), filtered and concentrated in  vacuo to furnish faint yellow a solid. (91.57 g).

Chemical Properties

White solid

Uses

Methyl 4-methyl-3-nitrobenzoate is used as pharmaceutical intermediate.

4-Methyl-3-nitrobenzoic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Methyl-3-nitrobenzoic acid methyl ester Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
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62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
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TAIYUAN RHF CO.,LTD.
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+86 351 7031519
Fax
+86 351 7031519
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sales@RHFChem.com
Country
China
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TCI (Shanghai) Development Co., Ltd.
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021-67121386
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021-67121385
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Sales-CN@TCIchemicals.com
Country
China
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24539
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Energy Chemical
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sales8178@energy-chemical.com
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China
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Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35906
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
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Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
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Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
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Advantage
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View Lastest Price from 4-Methyl-3-nitrobenzoic acid methyl ester manufacturers

Asia Chem I and E (Jiangsu) Co Ltd
Product
4-Methyl-3-nitrobenzoate 7356-11-8
Price
US $55.82/Kg/Drum
Min. Order
25Kg/Drum
Purity
99.00%HPLC
Supply Ability
13tons/month
Release date
2021-09-22
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Methyl-3-nitrobenzoic acid methyl ester 7356-11-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
4-Methyl-3-nitrobenzoic acid methyl ester 7356-11-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09

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