Methyl 3-amino-2-methylbenzoate
- Product Name
- Methyl 3-amino-2-methylbenzoate
- CAS No.
- 18583-89-6
- Chemical Name
- Methyl 3-amino-2-methylbenzoate
- Synonyms
- AKOS BB-3100;3-Amino-2-Methylbenzoate;METHYL 3-AMINO-O-TOLUATE;Lenalidomide Impurity 27;Lenalidomide Impurity 98;3-aminotoluene methyl ester;METHYL 3-AMINO-2-METHYLBENZOATE;METHYL 2-METHYL-3-AMINO BENZOATE;Methyl 3-Amino-2-melthyl benzoate;Methyl 3-amino-2-methylbenzoate 96%
- CBNumber
- CB7702334
- Molecular Formula
- C9H11NO2
- Formula Weight
- 165.19
- MOL File
- 18583-89-6.mol
Methyl 3-amino-2-methylbenzoate Property
- Boiling point:
- 300 °C (lit.)
- Density
- 1.146 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.573(lit.)
- Flash point:
- 220 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- solubility
- Chloroform (Sparingly), Methanol (Slightly)
- form
- Liquid
- pka
- 3.31±0.10(Predicted)
- color
- Colorless to brown
- CAS DataBase Reference
- 18583-89-6(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 530271
- Product name
- Methyl 3-amino-2-methylbenzoate
- Purity
- 96%
- Packaging
- 25g
- Price
- $162
- Updated
- 2023/06/20
- Product number
- A1563
- Product name
- Methyl 3-Amino-2-methylbenzoate
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $79
- Updated
- 2025/07/31
- Product number
- A1563
- Product name
- Methyl 3-Amino-2-methylbenzoate
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $228
- Updated
- 2025/07/31
- Product number
- M331018
- Product name
- Methyl 3-amino-2-methylbenzoate
- Packaging
- 250mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 4658-1-Z6
- Product name
- Methyl 3-amino-2-methylbenzoate
- Packaging
- 25g
- Price
- $48
- Updated
- 2021/12/16
Methyl 3-amino-2-methylbenzoate Chemical Properties,Usage,Production
Chemical Properties
off-white powder
Uses
Methyl 3-Amino-2-methylbenzoate can be used in petroleum recovery process.
Synthesis
52130-17-3
18583-89-6
A. General procedure for the synthesis of methyl 3-amino-2-methylbenzoate: 10 g (66.2 mmol) of 3-amino-2-methylbenzoic acid and 20 g of p-toluenesulfonic acid monohydrate were dissolved in 400 mL of methanol and the reaction was carried out at reflux overnight. After completion of the reaction, the reaction solution was diluted with a mixture of ethyl acetate and 1 M potassium carbonate solution. After cooling, the organic and aqueous layers were separated. The organic layer was washed sequentially with 1M potassium carbonate solution and saturated brine, dried over anhydrous sodium sulfate, filtered, and concentrated to give 9.23 g of an orange oily product in 85% yield. The product was characterized as follows: 1H NMR (CDCl3): δ 2.34 (s, 3H), 3.73 (br.s, 2H), 3.88 (s, 3H), 6.81 (d, J = 7.96 Hz, 1H), 7.05 (t, J = 7.78 Hz, 1H), 7.19-7.30 (m, 1H). IR (CHCl3): 3406, 3027, 3012, 2.30 (m). 3027, 3012, 2978, 2953, 1718, 1621, 1467, 1435, 1315, 1301, 1265, 1196, 1159, 1108, 1066, 1045, 810 cm-1. MS (FD): m/e 165 (M+, 100).
References
[1] Patent: US5952343, 1999, A
[2] Patent: US5461154, 1995, A
[3] Patent: US5484926, 1996, A
[4] Patent: US6555541, 2003, B1
Methyl 3-amino-2-methylbenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 3-amino-2-methylbenzoate manufacturers
- Product
- Methyl 3-amino-2-methylbenzoate 18583-89-6
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 10000KGS
- Release date
- 2025-05-12
- Product
- Methyl 3-amino-2-methylbenzoate 18583-89-6
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2025-03-10
- Product
- Methyl 3-amino-2-methylbenzoate 18583-89-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-11