ChemicalBook > CAS DataBase List > Methyl 3-amino-2-methylbenzoate

Methyl 3-amino-2-methylbenzoate

Product Name
Methyl 3-amino-2-methylbenzoate
CAS No.
18583-89-6
Chemical Name
Methyl 3-amino-2-methylbenzoate
Synonyms
AKOS BB-3100;3-Amino-2-Methylbenzoate;METHYL 3-AMINO-O-TOLUATE;Lenalidomide Impurity 27;Lenalidomide Impurity 98;3-aminotoluene methyl ester;METHYL 3-AMINO-2-METHYLBENZOATE;METHYL 2-METHYL-3-AMINO BENZOATE;Methyl 3-Amino-2-melthyl benzoate;Methyl 3-amino-2-methylbenzoate 96%
CBNumber
CB7702334
Molecular Formula
C9H11NO2
Formula Weight
165.19
MOL File
18583-89-6.mol
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Methyl 3-amino-2-methylbenzoate Property

Boiling point:
300 °C (lit.)
Density 
1.146 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.573(lit.)
Flash point:
220 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
Liquid
pka
3.31±0.10(Predicted)
color 
Colorless to brown
CAS DataBase Reference
18583-89-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
2922498590
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
530271
Product name
Methyl 3-amino-2-methylbenzoate
Purity
96%
Packaging
25g
Price
$162
Updated
2023/06/20
TCI Chemical
Product number
A1563
Product name
Methyl 3-Amino-2-methylbenzoate
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$79
Updated
2025/07/31
TCI Chemical
Product number
A1563
Product name
Methyl 3-Amino-2-methylbenzoate
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$228
Updated
2025/07/31
TRC
Product number
M331018
Product name
Methyl 3-amino-2-methylbenzoate
Packaging
250mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
007478
Product name
Methyl 3-amino-2-methylbenzoate
Purity
98%
Packaging
5g
Price
$11
Updated
2021/12/16
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Methyl 3-amino-2-methylbenzoate Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Uses

Methyl 3-Amino-2-methylbenzoate can be used in petroleum recovery process.

Synthesis

52130-17-3

18583-89-6

A. General procedure for the synthesis of methyl 3-amino-2-methylbenzoate: 10 g (66.2 mmol) of 3-amino-2-methylbenzoic acid and 20 g of p-toluenesulfonic acid monohydrate were dissolved in 400 mL of methanol and the reaction was carried out at reflux overnight. After completion of the reaction, the reaction solution was diluted with a mixture of ethyl acetate and 1 M potassium carbonate solution. After cooling, the organic and aqueous layers were separated. The organic layer was washed sequentially with 1M potassium carbonate solution and saturated brine, dried over anhydrous sodium sulfate, filtered, and concentrated to give 9.23 g of an orange oily product in 85% yield. The product was characterized as follows: 1H NMR (CDCl3): δ 2.34 (s, 3H), 3.73 (br.s, 2H), 3.88 (s, 3H), 6.81 (d, J = 7.96 Hz, 1H), 7.05 (t, J = 7.78 Hz, 1H), 7.19-7.30 (m, 1H). IR (CHCl3): 3406, 3027, 3012, 2.30 (m). 3027, 3012, 2978, 2953, 1718, 1621, 1467, 1435, 1315, 1301, 1265, 1196, 1159, 1108, 1066, 1045, 810 cm-1. MS (FD): m/e 165 (M+, 100).

References

[1] Patent: US5952343, 1999, A
[2] Patent: US5461154, 1995, A
[3] Patent: US5484926, 1996, A
[4] Patent: US6555541, 2003, B1

Methyl 3-amino-2-methylbenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 3-amino-2-methylbenzoate Suppliers

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View Lastest Price from Methyl 3-amino-2-methylbenzoate manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
Methyl 3-amino-2-methylbenzoate 18583-89-6
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
10000KGS
Release date
2025-05-12
Hebei Chuanghai Biotechnology Co., Ltd
Product
Methyl 3-amino-2-methylbenzoate 18583-89-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2025-03-10
Career Henan Chemical Co
Product
Methyl 3-amino-2-methylbenzoate 18583-89-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11

18583-89-6, Methyl 3-amino-2-methylbenzoateRelated Search:

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  • 18583-89-6
  • CH3C6H3NH2CO2CH3
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