ChemicalBook > CAS DataBase List > 2-BROMO-5-METHOXYBENZYL BROMIDE 97

2-BROMO-5-METHOXYBENZYL BROMIDE 97

Product Name
2-BROMO-5-METHOXYBENZYL BROMIDE 97
CAS No.
19614-12-1
Chemical Name
2-BROMO-5-METHOXYBENZYL BROMIDE 97
Synonyms
Atogepant Impurity 33;2-bromo-5-methoxybromobenzyl;4-Bromo-3-bromomethyl anisole;2-Bromo-5-methyoxybenzyl bromide;5-BroMo-2-Methoxy Benzyl BroMide;2-BROMO-5-METHOXYBENZYL BROMIDE 97;2-Bromo-5-methoxybenzyl Bromide >2-Bromo-5-methoxybenzyl bromide 97%;Benzene, 1-bromo-2-(bromomethyl)-4-methoxy-
CBNumber
CB2499808
Molecular Formula
C8H8Br2O
Formula Weight
279.96
MOL File
19614-12-1.mol
More
Less

2-BROMO-5-METHOXYBENZYL BROMIDE 97 Property

Melting point:
90-94 °C (lit.)
Boiling point:
299.6±25.0 °C(Predicted)
Density 
1.759±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Solid
color 
White to beige
Water Solubility 
Soluble in hot methanol. Slightly soluble in water.
InChI
InChI=1S/C8H8Br2O/c1-11-7-2-3-8(10)6(4-7)5-9/h2-4H,5H2,1H3
InChIKey
MURVUTUZSUEIGI-UHFFFAOYSA-N
SMILES
C1(Br)=CC=C(OC)C=C1CBr
More
Less

Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
Ⅱ
HS Code 
2909303890
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
553387
Product name
2-Bromo-5-methoxybenzyl bromide
Purity
97%
Packaging
25g
Price
$143
Updated
2023/06/20
TCI Chemical
Product number
B4423
Product name
2-Bromo-5-methoxybenzyl Bromide
Purity
>98.0%(GC)
Packaging
5g
Price
$56
Updated
2025/07/31
TCI Chemical
Product number
B4423
Product name
2-Bromo-5-methoxybenzyl Bromide
Purity
>98.0%(GC)
Packaging
25g
Price
$221
Updated
2025/07/31
TRC
Product number
B696633
Product name
2-Bromo-5-methoxybenzyl bromide
Packaging
1g
Price
$75
Updated
2021/12/16
TRC
Product number
B696633
Product name
2-Bromo-5-methoxybenzyl bromide
Packaging
250mg
Price
$55
Updated
2021/12/16
More
Less

2-BROMO-5-METHOXYBENZYL BROMIDE 97 Chemical Properties,Usage,Production

Uses

Employed as an important intermediate for raw material for organic synthesis, agrochemical, pharmaceutical and dyestuff field

Synthesis

27060-75-9

19614-12-1

The general procedure for the synthesis of 2-bromo-5-methoxybenzyl bromide from 2-bromo-5-methoxytoluene was as follows: 2-bromo-5-methoxytoluene (0.050 mol) and N-bromosuccinimide (NBS, 0.055 mol) were dissolved in carbon tetrachloride (125 mL), and azobisisobutyronitrile (AIBN, 0.001 mol) was added as initiator. The reaction mixture was stirred at 80 °C for 18 hours. Upon completion of the reaction, the mixture was diluted with hexane and subsequently filtered through a diatomaceous earth pad to remove insoluble impurities. The filtrate was concentrated under reduced pressure to remove the solvent and the residue was washed with ethyl acetate to give the final target product 4-bromo-3-(bromomethyl)anisole.

References

[1] Tetrahedron, 2004, vol. 60, # 49, p. 11075 - 11087
[2] Journal of the American Chemical Society, 2005, vol. 127, # 29, p. 10124 - 10125
[3] Journal of Organic Chemistry, 2014, vol. 79, # 11, p. 4973 - 4983
[4] Synlett, 2011, # 17, p. 2525 - 2528
[5] Journal of Medicinal Chemistry, 2000, vol. 43, # 1, p. 22 - 26

2-BROMO-5-METHOXYBENZYL BROMIDE 97 Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

2-BROMO-5-METHOXYBENZYL BROMIDE 97 Suppliers

Americas 1 China 123 Europe 1 India 9 Japan 1 Switzerland 1 United Kingdom 2 United States 12 Global 150
ChangShu Haitian Fine Chemicals Co.,Ltd
Tel
13913622609
Fax
86-512-52893680
Email
974295387@qq.com
Country
China
ProdList
192
Advantage
61
Shanghai Aoyeah Chemical Technology Co., Ltd.
Tel
021-021-64367138 15900495324
Fax
QQ：2504753890
Email
sales@aoyeahchem.com
Country
China
ProdList
197
Advantage
55
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Beijing Eternalchem Co,. Ltd.
Tel
010-59484199 18611897322
Email
sales@eternalchem.com
Country
China
ProdList
4383
Advantage
60
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
18270980682
Fax
021 51613951
Email
mlcheng@sunwaypharm.cn
Country
China
ProdList
8669
Advantage
57
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9510
Advantage
58
Shanghai Topbiochem Technology Co., Ltd
Tel
+86-21-60341587
Fax
+86-21-61294319
Email
sales@topbiochem.com
Country
China
ProdList
6175
Advantage
58
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9891
Advantage
58
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
150-2103-5486 18017383231
Fax
qq：2817624287
Email
983544897@qq.com
Country
China
ProdList
9342
Advantage
55
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-6206333 13167063860
Fax
021-50323701
Email
anhua.mao@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
SynAsst Chemical.
Tel
021-60343070
Fax
021-35122006
Country
China
ProdList
12740
Advantage
55
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9979
Advantage
55
Taizhou Tongxin Bio-Tech Co., Ltd
Tel
0523-86818997 18652728585
Email
sales@allyrise.com
Country
China
ProdList
2966
Advantage
60
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Chengdu HuaXia Chemical Reagent Co. Ltd
Tel
400-1166-196 13458535857
Fax
QQ：800101999
Email
cdhxsj@163.com
Country
China
ProdList
13350
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66028182 18626450290
Email
yftan@aikonchem.com
Country
China
ProdList
16679
Advantage
50
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51395
Advantage
80
Changzhou Anxuan Chemical, Co., Ltd.
Tel
13912302692 13912302692;
Fax
0519-88064678
Email
sales@anxuanchem.com
Country
China
ProdList
4828
Advantage
58
Struchem Co., Ltd.
Tel
0512-63009836 18994340901
Fax
0512-63006936
Email
helen@struchem.com
Country
China
ProdList
3981
Advantage
60
NovoChemy Ltd.
Tel
86-(0)21-31261262 373522135
Fax
86-(0)21-33250524
Email
sales@novochemy.com
Country
China
ProdList
6498
Advantage
58
Hubei Chuangliankangcheng Pharmaceutical Co., Ltd.
Tel
027-65388397 18164111589
Fax
027-65388397
Email
3321478047@qq.com
Country
China
ProdList
2007
Advantage
55
Codow Chemical Co.,Ltd.
Tel
18620099427
Fax
+86-20-62619665
Email
amy@howeipharm.com
Country
China
ProdList
6687
Advantage
55
Shanghai Xilong Biochemical Technology Co., Ltd.
Tel
021-52907766-8042
Fax
021-52906523
Country
China
ProdList
9941
Advantage
58
Shanghai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847; 18021002903
Fax
QQ:3008007432
Email
3008007409@qq.com
Country
China
ProdList
71826
Advantage
60
Shanghai QianYan Bio-technology Co., Ltd
Tel
02781293128
Email
orders@biochemsafebuy.com
Country
China
ProdList
9923
Advantage
55
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20794
Advantage
60
ChengDu TongChuangYuan Pharmaceutical Co.Ltd
Tel
028-83379370 13880556291
Fax
028-87747383
Email
tcy@tcypharm.com
Country
China
ProdList
7218
Advantage
58
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Shanghai CR Corporation Limited
Tel
13062833949; 4006653949 4006653949
Fax
QQ: 2136646215
Email
fred.wen@crcorporation.cn
Country
China
ProdList
9757
Advantage
58
Shandong Ono Chemical Co., Ltd.
Tel
0539-6362799 20）
Fax
0539-6362799（To 20）
Country
China
ProdList
10007
Advantage
58
Shanghai BaiShun Biological Technology Co., Ltd
Tel
021-37581181
Fax
021-57456066
Email
sales@chem-mall.com
Country
China
ProdList
10330
Advantage
58
Capot Chemical Co.,Ltd.
Tel
+86-（0）57185586718; +8613336195806
Fax
+86-571-85864795
Email
sales@capot.com
Country
China
ProdList
29735
Advantage
60
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 400821072
Fax
021-58955996
Email
malulu@leyan.com
Country
China
ProdList
25000
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52687
Advantage
58
Cool Pharm, Ltd
Tel
021-58581007 18019463053
Fax
021-50966098
Email
sales@coolpharm.com
Country
China
ProdList
12878
Advantage
58
Henan Alfa Chemical Co., Ltd
Tel
+8615838112936
Email
alfa10@alfachem.cn
Country
China
ProdList
12921
Advantage
58
CR Corporation Limited
Tel
+8613062833949
Email
fred.wen@crcorporation.cn
Country
China
ProdList
8645
Advantage
58
Nanjing Hengbei Chemicals Co., Ltd.
Tel
+86-25-58393656
Fax
+86-25-58393656
Email
sales@hengbeichem.cn
Country
China
ProdList
6854
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418671 +8618949823763
Fax
0551-65418697
Email
sales@tnjchem.com
Country
China
ProdList
34563
Advantage
58
Labnetwork lnc.
Tel
+86-27-50766799 +8618062016861
Email
contact@labnetwork.com
Country
China
ProdList
19987
Advantage
58
Dayang Chem (Hangzhou) Co.,Ltd.
Tel
+86-0571-88938639 +8617705817739
Fax
+86-571-88938652，+86-571- 88492614
Email
info@dycnchem.com
Country
China
ProdList
52846
Advantage
58
Win-Win chemical CO., Limited
Tel
+86-0086-577-64498589 +86-15355981851
Fax
0086-577-56994596
Email
sales@win-winchemical.com
Country
China
ProdList
14359
Advantage
58
Hebei Chuanghai Biotechnology Co., Ltd
Tel
+8615350571055
Fax
whatapp+8619930503282
Email
Sibel@chuanghaibio.com
Country
China
ProdList
8768
Advantage
58
More
Less

View Lastest Price from 2-BROMO-5-METHOXYBENZYL BROMIDE 97 manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd
Product
2-BROMO-5-METHOXYBENZYL BROMIDE 97 19614-12-1
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
Customise
Release date
2025-11-13
Hebei Chuanghai Biotechnology Co., Ltd
Product
2-BROMO-5-METHOXYBENZYL BROMIDE 19614-12-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-22
Career Henan Chemical Co
Product
2-BROMO-5-METHOXYBENZYL BROMIDE 97 19614-12-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-26

19614-12-1, 2-BROMO-5-METHOXYBENZYL BROMIDE 97Related Search:

4-Bromo-2-methylphenol 2-Bromo-5-methoxytoluene 4-Bromo-3-methylphenol 1-BROMO-2-BROMOMETHYL-4-METHOXY-3,5,6-TRIMETHYL-BENZENE 2-Bromo-4,5-Dimethoxybenzyl Bromide 2-BROMO-5-(TRIFLUOROMETHOXY)BENZYL BROMIDE 2-BROMO-5-METHOXYBENZYL BROMIDE 97 5-BROMO-6-BROMOMETHYL-1,3-BENZODIOXOLE

  • 2-bromo-5-methoxybromobenzyl
  • 5-BroMo-2-Methoxy Benzyl BroMide
  • 2-BROMO-5-METHOXYBENZYL BROMIDE 97
  • 4-Bromo-3-bromomethyl anisole
  • 2-Bromo-5-methyoxybenzyl bromide
  • 2-Bromo-5-methoxybenzyl bromide 97%
  • 2-Bromo-5-methoxybenzyl Bromide &gt
  • Benzene, 1-bromo-2-(bromomethyl)-4-methoxy-
  • Atogepant Impurity 33
  • 19614-12-1
  • BrC6H3CH2BrOCH3
  • Building Blocks
  • C2 to C8
  • Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds
  • alkyl bromide