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2-BROMO-5-METHOXYBENZYL BROMIDE 97

Product Name
2-BROMO-5-METHOXYBENZYL BROMIDE 97
CAS No.
19614-12-1
Chemical Name
2-BROMO-5-METHOXYBENZYL BROMIDE 97
Synonyms
Atogepant Impurity 33;2-bromo-5-methoxybromobenzyl;4-Bromo-3-bromomethyl anisole;2-Bromo-5-methyoxybenzyl bromide;5-BroMo-2-Methoxy Benzyl BroMide;2-BROMO-5-METHOXYBENZYL BROMIDE 97;2-Bromo-5-methoxybenzyl Bromide >2-Bromo-5-methoxybenzyl bromide 97%;Benzene, 1-bromo-2-(bromomethyl)-4-methoxy-
CBNumber
CB2499808
Molecular Formula
C8H8Br2O
Formula Weight
279.96
MOL File
19614-12-1.mol
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2-BROMO-5-METHOXYBENZYL BROMIDE 97 Property

Melting point:
90-94 °C (lit.)
Boiling point:
299.6±25.0 °C(Predicted)
Density 
1.759±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Solid
color 
White to beige
Water Solubility 
Soluble in hot methanol. Slightly soluble in water.
InChI
InChI=1S/C8H8Br2O/c1-11-7-2-3-8(10)6(4-7)5-9/h2-4H,5H2,1H3
InChIKey
MURVUTUZSUEIGI-UHFFFAOYSA-N
SMILES
C1(Br)=CC=C(OC)C=C1CBr
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
HazardClass 
8
PackingGroup 
Ⅱ
HS Code 
2909303890
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
553387
Product name
2-Bromo-5-methoxybenzyl bromide
Purity
97%
Packaging
25g
Price
$143
Updated
2023/06/20
TCI Chemical
Product number
B4423
Product name
2-Bromo-5-methoxybenzyl Bromide
Purity
>98.0%(GC)
Packaging
5g
Price
$56
Updated
2025/07/31
TCI Chemical
Product number
B4423
Product name
2-Bromo-5-methoxybenzyl Bromide
Purity
>98.0%(GC)
Packaging
25g
Price
$221
Updated
2025/07/31
TRC
Product number
B696633
Product name
2-Bromo-5-methoxybenzyl bromide
Packaging
1g
Price
$75
Updated
2021/12/16
TRC
Product number
B696633
Product name
2-Bromo-5-methoxybenzyl bromide
Packaging
250mg
Price
$55
Updated
2021/12/16
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2-BROMO-5-METHOXYBENZYL BROMIDE 97 Chemical Properties,Usage,Production

Uses

Employed as an important intermediate for raw material for organic synthesis, agrochemical, pharmaceutical and dyestuff field

Synthesis

27060-75-9

19614-12-1

The general procedure for the synthesis of 2-bromo-5-methoxybenzyl bromide from 2-bromo-5-methoxytoluene was as follows: 2-bromo-5-methoxytoluene (0.050 mol) and N-bromosuccinimide (NBS, 0.055 mol) were dissolved in carbon tetrachloride (125 mL), and azobisisobutyronitrile (AIBN, 0.001 mol) was added as initiator. The reaction mixture was stirred at 80 °C for 18 hours. Upon completion of the reaction, the mixture was diluted with hexane and subsequently filtered through a diatomaceous earth pad to remove insoluble impurities. The filtrate was concentrated under reduced pressure to remove the solvent and the residue was washed with ethyl acetate to give the final target product 4-bromo-3-(bromomethyl)anisole.

References

[1] Tetrahedron, 2004, vol. 60, # 49, p. 11075 - 11087
[2] Journal of the American Chemical Society, 2005, vol. 127, # 29, p. 10124 - 10125
[3] Journal of Organic Chemistry, 2014, vol. 79, # 11, p. 4973 - 4983
[4] Synlett, 2011, # 17, p. 2525 - 2528
[5] Journal of Medicinal Chemistry, 2000, vol. 43, # 1, p. 22 - 26

2-BROMO-5-METHOXYBENZYL BROMIDE 97 Preparation Products And Raw materials

Raw materials

Preparation Products

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2-BROMO-5-METHOXYBENZYL BROMIDE 97 Suppliers

Americas 1 China 123 Europe 1 India 9 Japan 1 Switzerland 1 United Kingdom 2 United States 12 Global 150
TCI Chemicals (India) Pvt. Ltd.
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Fax
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sales-in@tcichemicals.com
Country
India
ProdList
6768
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58
Alfa Aesar
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tech@alfa.com
Country
India
ProdList
6905
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A.J Chemicals
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sales@ajchem.in
Country
India
ProdList
6100
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View Lastest Price from 2-BROMO-5-METHOXYBENZYL BROMIDE 97 manufacturers

Hefei Lbao Physical & Chemical Science Co.,Ltd
Product
2-BROMO-5-METHOXYBENZYL BROMIDE 97 19614-12-1
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
Customise
Release date
2025-11-13
Hebei Chuanghai Biotechnology Co., Ltd
Product
2-BROMO-5-METHOXYBENZYL BROMIDE 19614-12-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-11-22
Career Henan Chemical Co
Product
2-BROMO-5-METHOXYBENZYL BROMIDE 97 19614-12-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-26

19614-12-1, 2-BROMO-5-METHOXYBENZYL BROMIDE 97Related Search:

4-Bromo-2-methylphenol 2-Bromo-5-methoxytoluene 4-Bromo-3-methylphenol 1-BROMO-2-BROMOMETHYL-4-METHOXY-3,5,6-TRIMETHYL-BENZENE 2-Bromo-4,5-Dimethoxybenzyl Bromide 2-BROMO-5-(TRIFLUOROMETHOXY)BENZYL BROMIDE 2-BROMO-5-METHOXYBENZYL BROMIDE 97 5-BROMO-6-BROMOMETHYL-1,3-BENZODIOXOLE

  • 2-bromo-5-methoxybromobenzyl
  • 5-BroMo-2-Methoxy Benzyl BroMide
  • 2-BROMO-5-METHOXYBENZYL BROMIDE 97
  • 4-Bromo-3-bromomethyl anisole
  • 2-Bromo-5-methyoxybenzyl bromide
  • 2-Bromo-5-methoxybenzyl bromide 97%
  • 2-Bromo-5-methoxybenzyl Bromide &gt
  • Benzene, 1-bromo-2-(bromomethyl)-4-methoxy-
  • Atogepant Impurity 33
  • 19614-12-1
  • BrC6H3CH2BrOCH3
  • Building Blocks
  • C2 to C8
  • Chemical Synthesis
  • Organic Building Blocks
  • Oxygen Compounds
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds
  • alkyl bromide