METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97

Product Name: METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97
CAS No.: 913836-22-3
Chemical Name: METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97
Synonyms: 5-Bromo-4-(methoxycarbonyl)-1,3-thiazole;METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97;Methyl 5-bromo-1,3-thiazole-4-carboxylate 97%;4-Thiazolecarboxylic acid, 5-bromo-, methyl ester
CBNumber: CB2501309
Molecular Formula: C5H4BrNO2S
Formula Weight: 222.06
MOL File: 913836-22-3.mol

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METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 Property

Melting point:: 98-101
Boiling point:: 276℃
Density: 1.759
Flash point:: 121℃
storage temp.: Inert atmosphere,2-8°C
pka: -1.48±0.10(Predicted)
form: solid
color: Light yellow to orange
InChI: InChI=1S/C5H4BrNO2S/c1-9-5(8)3-4(6)10-2-7-3/h2H,1H3
InChIKey: AUJMFWXVFMHABB-UHFFFAOYSA-N
SMILES: S1C(Br)=C(C(OC)=O)N=C1

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Safety

Hazard Codes: Xi
Hazard Note: Irritant/Keep Cold
HS Code: 2934100090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: SYX00326
Product name: Methyl 5-bromothiazole-4-carboxylate
Packaging: 1g
Price: $107
Updated: 2025/07/31

Ark Pharm

Product number: P000097791
Product name: Methyl 5-bromothiazole-4-carboxylate
Purity: 98%
Packaging: 250mg
Price: $22
Updated: 2021/12/16

Apolloscientific

Product number: OR3365
Product name: Methyl5-bromo-1,3-thiazole-4-carboxylate
Purity: 97%
Packaging: 1g
Price: $24
Updated: 2021/12/16

SynQuest Laboratories

Product number: 8H23-9-X0
Product name: Methyl 5-bromo-1,3-thiazole-4-carboxylate
Purity: 97%
Packaging: 1g
Price: $28
Updated: 2021/12/16

Ark Pharm

Product number: P000097791
Product name: Methyl 5-bromothiazole-4-carboxylate
Purity: 98%
Packaging: 1g
Price: $55
Updated: 2021/12/16

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METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 Chemical Properties,Usage,Production

Synthesis

850429-60-6

913836-22-3

General procedure for the synthesis of methyl 5-bromo-4-thiazolecarboxylate from methyl 2-amino-5-bromothiazole-4-carboxylate: Methyl 2-amino-5-bromothiazole-4-carboxylate (1.0 equiv, 100 mg, 0.42 mmol) was dissolved in anhydrous DMF (0.8 mL). The reaction mixture was heated to 80 °C under nitrogen protection. A solution of tert-butyl nitrite (1.2 eq, 60 μL, 0.50 mmol) in DMF (0.8 mL) was slowly added dropwise to the hot solution. After several minutes of reaction, no gas escaped indicating completion of the reaction. The reaction mixture was cooled to room temperature and then sampled directly onto a preloaded silica gel column. Rapid column chromatographic separation was carried out sequentially using hexane and ethyl acetate/hexane (2:8, v/v) as eluents to afford methyl 5-bromothiazole-4-carboxylate as a yellow solid (49 mg, 53% yield). The product was analyzed by LCMS (ES) showing a purity of 95%, m/z 222 [M]+, 224 [M+2]+.

References

[1] Patent: WO2008/28168, 2008, A2. Location in patent: Page/Page column 157
[2] Patent: US2009/93465, 2009, A1. Location in patent: Page/Page column 49
[3] Patent: US2009/239859, 2009, A1. Location in patent: Page/Page column 138

METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 Suppliers

China 88 India 2 United Kingdom 1 United States 13 Global 104

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View Lastest Price from METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 913836-22-3
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1000kg
Release date: 2025-06-29

Career Henan Chemical Co

Product: METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 913836-22-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500kg
Release date: 2019-12-25

913836-22-3, METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97Related Search:

Methyl 5-broMothiophene-3-carboxylate Ethyl 5-bromothiazole-4-carboxylate 5-Bromothiazole-4-carboxylic acid Methyl 2-bromothiazole-5-carboxylate METHYL 2-BROMOTHIAZOLE-4-CARBOXYLATE Ethyl 2-amino-5-bromothiazole-4-carboxylate Methyl 2-amino-5-bromothiazole-4-carboxylate METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97 2,5-DIBROMO-THIAZOLE-4-CARBOXYLIC ACID ETHYL ESTER 5-BROMO-2-TERT-BUTOXYCARBONYLAMINOTHIAZOLE-4-CARBOXYLIC ACID METHYL ESTER 2,5-DIBROMOTHIAZOLE-4-CARBOXYLIC ACID METHYL ESTER 5-BROMO-2-PHENYLTHIAZOLE-4-CARBOXYLIC ACID ETHYL ESTER Methyl 5-bromo-2-methyl-1,3-thiazole-4-carboxylate 5-Bromothiazole 5-Bromo-thiophene-2-carboxylic acid methyl ester

5-Bromo-4-(methoxycarbonyl)-1,3-thiazole

METHYL 5-BROMO-1,3-THIAZOLE-4-CARBOXYLATE 97

Methyl 5-bromo-1,3-thiazole-4-carboxylate 97%

4-Thiazolecarboxylic acid, 5-bromo-, methyl ester

913836-22-3

Building Blocks

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