ChemicalBook > CAS DataBase List > Ametryn

Ametryn

Product Name
Ametryn
CAS No.
834-12-8
Chemical Name
Ametryn
Synonyms
EVIK;a1093;AMESIP;G34162;A 1093;Amigan;X-SIPAX;EVIK(R);Cemerin;gestene
CBNumber
CB2684343
Molecular Formula
C9H17N5S
Formula Weight
227.33
MOL File
834-12-8.mol
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Ametryn Property

Melting point:
84-85°C
Boiling point:
310.44°C (rough estimate)
Density 
1.1232 (rough estimate)
vapor pressure 
0Pa at 20℃
refractive index 
1.5500 (estimate)
Flash point:
11 °C
storage temp. 
Keep in dark place,Sealed in dry,2-8°C
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
Crystalline
pka
3.71±0.41(Predicted)
color 
White to off-white
Water Solubility 
209mg/L(25 ºC)
Merck 
13,391
BRN 
613099
InChIKey
RQVYBGPQFYCBGX-UHFFFAOYSA-N
LogP
3 at 20℃
CAS DataBase Reference
834-12-8(CAS DataBase Reference)
NIST Chemistry Reference
1,3,5-Triazine-2,4-diamine, N-ethyl-N'-(1-methylethyl)-6-(methylthio)-(834-12-8)
EPA Substance Registry System
Ametryn (834-12-8)
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Safety

Hazard Codes 
Xn;N,N,Xn,T,F
Risk Statements 
22-50/53-39/23/24/25-23/24/25-11
Safety Statements 
2-36-60-61-45-16-7
RIDADR 
UN 1230 3/PG 2
WGK Germany 
3
RTECS 
XY9100000
HS Code 
29336990
Hazardous Substances Data
834-12-8(Hazardous Substances Data)
Toxicity
LD50 in adult male, female rats (mg/kg): 508, 590 orally (Gaines, Linder)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
45321
Product name
Ametryn
Purity
PESTANAL
Packaging
250mg
Price
$63.7
Updated
2024/03/01
TRC
Product number
A576400
Product name
Ametryn
Packaging
5g
Price
$460
Updated
2021/12/16
AK Scientific
Product number
S263
Product name
Ametryn
Packaging
100mg
Price
$23
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
PST0000055
Product name
AMETRYN
Purity
95.00%
Packaging
1G
Price
$244.65
Updated
2021/12/16
AHH
Product number
MT-47027
Product name
Ametryn
Purity
98%
Packaging
500g
Price
$340
Updated
2021/12/16
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Ametryn Chemical Properties,Usage,Production

Chemical Properties

White, crystalline powder. Slightly soluble in water; soluble in organic solvents.

Chemical Properties

Ametryn is a colorless powder

Uses

Herbicide used to control broad-leaved and grass weeds in corn, sugarcane, certain citrus subtropical fruits (bananas, pineapple) and in noncropland. Preharvest and postharvest desiccant used in potatoes to control both crop and weeds

Uses

Pre-emergence and post-emergence herbicides.

Uses

Ametryn is a methylthiotriazine based herbicide which inhibits photosynthesis and other enzymatic processes. Ametryn is used to control broadleaf weeds and annual grasses in pineapple, sugarcane and b ananas.

Production Methods

Ametryn is a colorless crystal synthesized by reacting atrazine with methyl mercaptan in the presence of an equivalent of NaOH or by reacting 2-mercapto-4-ethylamino-6-isopropylamino- 1,3,5-triazine with a methylating agent in the presence of NaOH. It is stable in slightly acidic or alkaline media, but is hydrolyzed to the inactive 6-hydroxy derivative in strong acidic or basic media.

Definition

ChEBI: A methylthio-1,3,5-triazine that is 2-(methylsulfanyl)-1,3,5-triazine substituted by an ethylamino and an isopropylamino group at positions 4 and 6 respectively.

General Description

Crystals. Melting point 190-192°F (88-89°C). Used as a herbicide.

Reactivity Profile

An amine, organosulfide. Organosulfides are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Hazard

Toxic by ingestion.

Health Hazard

Moderately toxic by ingestion; human toxic-ity data not available; a mild irritant to skinand eye.
LD50 oral (rat): 508 mg/kg
LD50 oral (mouse): 965 mg/kg
LD50 skin (rabbit): >5000 mg/kg.

Flammability and Explosibility

Non flammable

Agricultural Uses

Herbicide: Ametryn is a herbicide which inhibits photosynthesis and other enzymatic processes. It is used to control broadleaf weeds and annual grasses in pineapple, sugarcane and bananas. Uses are being supported in the U.S. only for the following agricultural crops: field corn, popcorn, sugarcane, and pineapple (EPA, 2005). Used in premixes with atrazine, diuron, simazine, and terbutryn. Not approved for use in the EU.

Trade name

AMESIP®; AMERTREX®; AMETREX; AMETRON SC®; AMETRYNE TECHNICAL®; AMIGAN®; AMULEX; CRISATRINE®; CRISATRINA®; DORUPLANT®; EVIK®; G-34162®; GESAPAX®; HERBIPAK®; KRISMAT®; OXON PRIMATOL Z 80®; SANCOPAX®; TRINATOX-D®

Potential Exposure

Ametryn, a triazine and an organosulfide, amine compound A potential danger to those involved in the manufacture, formulation and application of this selective herbicide.

Carcinogenicity

No carcinogenic response was observed at the highest dose tested in lifetime studies, 2000 ppm, for both rats and mice.

Environmental Fate

Biological. Cook and Hütter (1982) reported that bacterial cultures were capable of degrading ametryne forming the corresponding hydroxy derivative (hydroxyametryne)
Soil. Although no products were reported, the half-life in soil is 70–120 days (Worthing and Hance, 1991)
Groundwater. According to the U.S. EPA (1986) ametryn has a high potential to leach to groundwater
Chemical/Physical. Hydrolyzes to the 6-hydroxy analog, especially in the presence of
Photolytic. The dye-sensitized photodecomposition of ametryn was studied in aqueous, aerated solutions (Rejto et al., 1983). When an aqueous ametryn solution was irradiated in sunlight for several hours, 2-(methylthio)-4-(isopropylamino)-6-amino-

Shipping

UN2763 Triazine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials

Incompatibilities

Triazines are incompatible with nitric acid. Amines are chemical bases, they neutralize acids to form salts plus water with an exothermic reaction. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents such as hydrides, nitrides, alkali metals, and sulfides.

Waste Disposal

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

Ametryn Preparation Products And Raw materials

Raw materials

Preparation Products

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Ametryn Suppliers

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Spectrum Chemical Manufacturing Corp.
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View Lastest Price from Ametryn manufacturers

qingdao trust agri chemical co.,ltd
Product
ametryn 834-12-8
Price
US $0.00/KG
Min. Order
100KG
Purity
98
Supply Ability
200TONS
Release date
2024-07-17
Shanghai Biolang Biotechnology Co., Ltd.
Product
Ametryn 834-12-8
Price
US $9.90-7.70/g
Min. Order
10g
Purity
99.99%HPLC.USP42——Powder、Oil、Pills、Capsules、Tablets,Customiz
Supply Ability
1000kgs
Release date
2022-02-18
Zhuozhou Wenxi import and Export Co., Ltd
Product
Ametryn 834-12-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-26

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