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2-Amino-4-methoxy-6-methyl-1,3,5-triazine

Product Name
2-Amino-4-methoxy-6-methyl-1,3,5-triazine
CAS No.
1668-54-8
Chemical Name
2-Amino-4-methoxy-6-methyl-1,3,5-triazine
Synonyms
4-Methoxy-6-methyl-1,3,5-triazin-2-amine;2-amino-4-methoxy-6-methyl-s-triazin;2-methyl-4-amino-6-methoxy-s-triazine;2-Amino-4-methyl-6-methoxy-s-triazine;2-AMINO-4-METHOXY-6-METHYL-1,3,5-TRIAZIN;cv399;CGA-150829;Homotriazine;2-AMino-4-Meth;-1,3,5-triazine
CBNumber
CB5379990
Molecular Formula
C5H8N4O
Formula Weight
140.14
MOL File
1668-54-8.mol
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2-Amino-4-methoxy-6-methyl-1,3,5-triazine Property

Melting point:
258-261 °C(lit.)
Boiling point:
114℃
Density 
1.2945 (rough estimate)
refractive index 
1.8300 (estimate)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
Chloroform (Slightly), DMSO (Slightly)
form 
Solid
pka
3.65±0.10(Predicted)
color 
White to Light Yellow
InChI
InChI=1S/C5H8N4O/c1-3-7-4(6)9-5(8-3)10-2/h1-2H3,(H2,6,7,8,9)
InChIKey
NXFQWRWXEYTOTK-UHFFFAOYSA-N
SMILES
N1=C(C)N=C(OC)N=C1N
CAS DataBase Reference
1668-54-8(CAS DataBase Reference)
EPA Substance Registry System
1,3,5-Triazin-2-amine, 4-methoxy-6-methyl- (1668-54-8)
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Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
1
RTECS 
XY3193000
HazardClass 
IRRITANT
HS Code 
29336990
Toxicity
LD50 oral in mouse: 1010mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
522996
Product name
2-Amino-4-methoxy-6-methyl-1,3,5-triazine
Purity
97%
Packaging
10g
Price
$139
Updated
2023/06/20
TCI Chemical
Product number
A1560
Product name
2-Amino-4-methoxy-6-methyl-1,3,5-triazine
Purity
>98.0%(T)
Packaging
5g
Price
$19
Updated
2025/07/31
TCI Chemical
Product number
A1560
Product name
2-Amino-4-methoxy-6-methyl-1,3,5-triazine
Purity
>98.0%(T)
Packaging
25g
Price
$47
Updated
2025/07/31
TRC
Product number
A616880
Product name
2-Amino-4-methoxy-6-methyl-1,3,5-triazine
Packaging
25g
Price
$110
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA38173
Product name
2-Amino-4-methoxy-6-methyl-1,3,5-triazine
Packaging
250g
Price
$120
Updated
2021/12/16
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2-Amino-4-methoxy-6-methyl-1,3,5-triazine Chemical Properties,Usage,Production

Chemical Properties

off-white to light yellow powder

Uses

2-Amino-4-methoxy-6-methyl-1,3,5-triazine may be used in the synthesis of thifensulfuron.

Definition

ChEBI: A monoamino-1,3,5-triazine that is 1,3,5-triazin-2-amine substituted by a methoxy group at position 4 and a methyl group at position 6. It is a metabolite of the herbicide thifensulfuron-methyl.

General Description

2-Amino-4-methoxy-6-methyl-1,3,5-triazine is formed during the photocatalytic decomposition of sulfonylurea (Sus) herbicide. It is also formed as a thermal decomposition product of chlorsulfuron (a sulfonylurea herbicide) and has been determined by GC using nitrogen-phosphorus detection (NPD).

Synthesis

24771-25-3

124-42-5

1668-54-8

Example 2: Acetamidine hydrochloride (9.5 g) was added to a solution of methanol (50 mL) and potassium hydroxide particles (6.8 g) pre-cooled to 10°C. Subsequently, dimethyl N-cyanoimido carbonate (11.4 g) was dissolved in 40 mL of methanol and this solution was slowly added dropwise to the above reaction mixture. After the dropwise addition was completed, the reaction mixture was stirred continuously at 25°C for 2 hours. Upon completion of the reaction, the mixture was poured into 40 mL of ice water to quench the reaction. The resulting solid crystals were collected by filtration and washed sequentially with water and methanol. Finally, the product was dried at 70 °C overnight to afford 11.8 g of 2-amino-4-methyl-6-methoxy-1,3,5-triazine in 84% yield.

References

[1] Patent: US5070199, 1991, A

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2-Amino-4-methoxy-6-methyl-1,3,5-triazine Suppliers

Nanjing Gold Pharmaceutical Technology Co. Ltd.
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028-025-84209270 15380463325
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China
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Shandong Yukun Chemical Industry Co. LTD
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18660690289
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Energy Chemical
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View Lastest Price from 2-Amino-4-methoxy-6-methyl-1,3,5-triazine manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2-Amino-4-methoxy-6-methyl-1,3,5-triazine 1668-54-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-11-03
Hebei Yanxi Chemical Co., Ltd.
Product
2-Amino-4-methoxy-6-methyl-1,3,5-triazine 1668-54-8
Price
US $40.00/KG
Min. Order
1KG
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-20
Career Henan Chemical Co
Product
2-Amino-4-methoxy-6-methyl-1,3,5-triazine 1668-54-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2018-08-20

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