2-Amino-4-methoxy-6-methyl-1,3,5-triazine
- Product Name
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine
- CAS No.
- 1668-54-8
- Chemical Name
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine
- Synonyms
- 4-Methoxy-6-methyl-1,3,5-triazin-2-amine;2-amino-4-methoxy-6-methyl-s-triazin;2-methyl-4-amino-6-methoxy-s-triazine;2-Amino-4-methyl-6-methoxy-s-triazine;2-AMINO-4-METHOXY-6-METHYL-1,3,5-TRIAZIN;cv399;CGA-150829;Homotriazine;2-AMino-4-Meth;-1,3,5-triazine
- CBNumber
- CB5379990
- Molecular Formula
- C5H8N4O
- Formula Weight
- 140.14
- MOL File
- 1668-54-8.mol
2-Amino-4-methoxy-6-methyl-1,3,5-triazine Property
- Melting point:
- 258-261 °C(lit.)
- Boiling point:
- 114℃
- Density
- 1.2945 (rough estimate)
- refractive index
- 1.8300 (estimate)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- solubility
- Chloroform (Slightly), DMSO (Slightly)
- form
- Solid
- pka
- 3.65±0.10(Predicted)
- color
- White to Light Yellow
- InChI
- InChI=1S/C5H8N4O/c1-3-7-4(6)9-5(8-3)10-2/h1-2H3,(H2,6,7,8,9)
- InChIKey
- NXFQWRWXEYTOTK-UHFFFAOYSA-N
- SMILES
- N1=C(C)N=C(OC)N=C1N
- CAS DataBase Reference
- 1668-54-8(CAS DataBase Reference)
- EPA Substance Registry System
- 1,3,5-Triazin-2-amine, 4-methoxy-6-methyl- (1668-54-8)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26-36-37/39
- WGK Germany
- 1
- RTECS
- XY3193000
- HazardClass
- IRRITANT
- HS Code
- 29336990
- Toxicity
- LD50 oral in mouse: 1010mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 522996
- Product name
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine
- Purity
- 97%
- Packaging
- 10g
- Price
- $139
- Updated
- 2023/06/20
- Product number
- A1560
- Product name
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $19
- Updated
- 2025/07/31
- Product number
- A1560
- Product name
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine
- Purity
- >98.0%(T)
- Packaging
- 25g
- Price
- $47
- Updated
- 2025/07/31
- Product number
- A616880
- Product name
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine
- Packaging
- 25g
- Price
- $110
- Updated
- 2021/12/16
- Product number
- FA38173
- Product name
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine
- Packaging
- 250g
- Price
- $120
- Updated
- 2021/12/16
2-Amino-4-methoxy-6-methyl-1,3,5-triazine Chemical Properties,Usage,Production
Chemical Properties
off-white to light yellow powder
Uses
2-Amino-4-methoxy-6-methyl-1,3,5-triazine may be used in the synthesis of thifensulfuron.
Definition
ChEBI: A monoamino-1,3,5-triazine that is 1,3,5-triazin-2-amine substituted by a methoxy group at position 4 and a methyl group at position 6. It is a metabolite of the herbicide thifensulfuron-methyl.
General Description
2-Amino-4-methoxy-6-methyl-1,3,5-triazine is formed during the photocatalytic decomposition of sulfonylurea (Sus) herbicide. It is also formed as a thermal decomposition product of chlorsulfuron (a sulfonylurea herbicide) and has been determined by GC using nitrogen-phosphorus detection (NPD).
Synthesis
24771-25-3
124-42-5
1668-54-8
Example 2: Acetamidine hydrochloride (9.5 g) was added to a solution of methanol (50 mL) and potassium hydroxide particles (6.8 g) pre-cooled to 10°C. Subsequently, dimethyl N-cyanoimido carbonate (11.4 g) was dissolved in 40 mL of methanol and this solution was slowly added dropwise to the above reaction mixture. After the dropwise addition was completed, the reaction mixture was stirred continuously at 25°C for 2 hours. Upon completion of the reaction, the mixture was poured into 40 mL of ice water to quench the reaction. The resulting solid crystals were collected by filtration and washed sequentially with water and methanol. Finally, the product was dried at 70 °C overnight to afford 11.8 g of 2-amino-4-methyl-6-methoxy-1,3,5-triazine in 84% yield.
References
[1] Patent: US5070199, 1991, A
2-Amino-4-methoxy-6-methyl-1,3,5-triazine Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Amino-4-methoxy-6-methyl-1,3,5-triazine manufacturers
- Product
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine 1668-54-8
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2022-11-03
- Product
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine 1668-54-8
- Price
- US $40.00/KG
- Min. Order
- 1KG
- Purity
- 0.99
- Supply Ability
- 10 tons
- Release date
- 2023-10-20
- Product
- 2-Amino-4-methoxy-6-methyl-1,3,5-triazine 1668-54-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2018-08-20