2-Bromo-4-methylphenol

Product Name: 2-Bromo-4-methylphenol
CAS No.: 6627-55-0
Chemical Name: 2-Bromo-4-methylphenol
Synonyms: AKOS BBB/368;2-bromo-p-cres;2-bromo-p-creso;2-BROMO-P-CRESOL;2-Bromo-4-cresol;p-Cresol, 2-bromo-;2-Bromo-p-cresol >2-Bromo-p-methylphenol;2-BROMO-4-METHYLPHENOL;4-Methyl-2-bromophenol
CBNumber: CB2703260
Molecular Formula: C7H7BrO
Formula Weight: 187.03
MOL File: 6627-55-0.mol

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2-Bromo-4-methylphenol Property

Melting point:: 54-55 °C
Boiling point:: 245-247 °C
Density: 1.554±0.06 g/cm3 | Condition: Temp: 20 °C Press: 760 Torr
refractive index: n20/D 1.578(lit.)
Flash point:: >230 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in Chloroform, Methanol
pka: 8.73±0.18(Predicted)
form: powder to lump to clear liquid
color: White or Colorless to Light yellow
Water Solubility: Slightly soluble in water.
InChI: InChI=1S/C7H7BrO/c1-5-2-3-7(9)6(8)4-5/h2-4,9H,1H3
InChIKey: MTIDYGLTAOZOGU-UHFFFAOYSA-N
SMILES: C1(O)=CC=C(C)C=C1Br
CAS DataBase Reference: 6627-55-0(CAS DataBase Reference)
NIST Chemistry Reference: Phenol, 2-bromo-4-methyl-(6627-55-0)
EPA Substance Registry System: Phenol, 2-bromo-4-methyl- (6627-55-0)

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-21/22
Safety Statements: 26-37/39-36/37/39-24/25
WGK Germany: 3
RTECS: GO6868200
TSCA: Yes
HazardClass: IRRITANT
HS Code: 29071990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: B72809
Product name: 2-Bromo-4-methylphenol
Purity: 96%
Packaging: 5g
Price: $60
Updated: 2025/07/31

Sigma-Aldrich

Product number: B72809
Product name: 2-Bromo-4-methylphenol
Purity: 96%
Packaging: 25g
Price: $229
Updated: 2023/06/20

TCI Chemical

Product number: B0808
Product name: 2-Bromo-p-cresol
Purity: >98.0%(GC)
Packaging: 25g
Price: $95
Updated: 2025/07/31

TCI Chemical

Product number: B0808
Product name: 2-Bromo-p-cresol
Purity: >98.0%(GC)
Packaging: 500g
Price: $1134
Updated: 2025/07/31

TRC

Product number: B686105
Product name: 2-Bromo-4-methylphenol
Packaging: 250g
Price: $305
Updated: 2021/12/16

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2-Bromo-4-methylphenol Chemical Properties,Usage,Production

Chemical Properties

clear colourless to pale yellow liquid

Uses

It is applied as a compound responsible for iodine off-flavor in wines.

Synthesis

25458-49-5

6627-55-0

General procedure for the synthesis of 2-bromo-4-methylphenol from 4-(methoxymethoxy)toluene: To a 10 mL round-bottomed flask equipped with a magnetic stirring bar were added 4-(methoxymethoxy)toluene (0.1 mmol), carbon tetrabromide (33 mg, 0.1 mmol), anhydrous acetonitrile (1 mL), and tris(2,2'-bipyridine) ruthenium (II) dichloride (3.8 mg, 0.005 mmol). The reaction mixture was irradiated at room temperature using a blue LED (1 W) and air was continuously passed until the complete disappearance of the feedstock was shown by thin layer chromatography (TLC) monitoring. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was purified by fast column chromatography to afford the target product 2-bromo-4-methylphenol.

References

[1] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 622 - 627

2-Bromo-4-methylphenol Preparation Products And Raw materials

Raw materials

dilute sulphuric acid 2-Bromo-4-methylaniline p-Cresol

Preparation Products

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2-Bromo-4-methylphenol Suppliers

Americas 1 Belgium 2 China 237 Europe 3 France 1 Germany 4 India 10 Japan 2 Russia 1 Slovakia 1 Switzerland 2 Ukraine 1 United Kingdom 12 United States 27 Global 304

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View Lastest Price from 2-Bromo-4-methylphenol manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: 2-Bromo-4-methylphenol 6627-55-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-31

Henan Aochuang Chemical Co.,Ltd.

Product: 2-Bromo-4-methylphenol 6627-55-0
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-08

Hebei Yanxi Chemical Co., Ltd.

Product: 2-Bromo-4-methylphenol 6627-55-0
Price: US $30.00-10.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 20 tons
Release date: 2023-10-08

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C7H7BrO

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