2,3-DIAMINOTOLUENE
- Product Name
- 2,3-DIAMINOTOLUENE
- CAS No.
- 2687-25-4
- Chemical Name
- 2,3-DIAMINOTOLUENE
- Synonyms
- Toluene-2,3-diamine;2,3-DAT;25KGS/DRUM;2.3-DiaMinotol;2,3-Dhamphetamine;2,3-Diaminotoluone;2,3-Diaminetoluene;2,3-TOLUENEDIAMINE;2,3-DIAMINOTOLUENE;2,3-Tolylenediamine
- CBNumber
- CB2736932
- Molecular Formula
- C7H10N2
- Formula Weight
- 122.17
- MOL File
- 2687-25-4.mol
2,3-DIAMINOTOLUENE Property
- Melting point:
- 59-65 °C (lit.)
- Boiling point:
- 225°C
- Density
- 1.0343 (rough estimate)
- refractive index
- 1.5103 (estimate)
- Flash point:
- 225°C
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Dichloromethane
- pka
- 4.28±0.10(Predicted)
- form
- Powder or Crystals
- color
- Brown to dark brown
- BRN
- 907184
- InChI
- InChI=1S/C7H10N2/c1-5-3-2-4-6(8)7(5)9/h2-4H,8-9H2,1H3
- InChIKey
- AXNUJYHFQHQZBE-UHFFFAOYSA-N
- SMILES
- C1(N)=CC=CC(C)=C1N
- CAS DataBase Reference
- 2687-25-4(CAS DataBase Reference)
- EPA Substance Registry System
- 1,2-Benzenediamine, 3-methyl- (2687-25-4)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36-36/37/39
- RIDADR
- 2811
- WGK Germany
- 3
- RTECS
- XS9550000
- Hazard Note
- Harmful/Irritant
- TSCA
- Yes
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29214990
- Hazardous Substances Data
- 2687-25-4(Hazardous Substances Data)
- Toxicity
- mouse,LD50,intraperitoneal,286mg/kg (286mg/kg),Genetica Polonica. Vol. 26, Pg. 109, 1985.
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 272361
- Product name
- 2,3-Diaminotoluene
- Purity
- 97%
- Packaging
- 5g
- Price
- $99.8
- Updated
- 2025/07/31
- Product number
- D3788
- Product name
- 2,3-Diaminotoluene
- Purity
- >97.0%(GC)(T)
- Packaging
- 5g
- Price
- $177
- Updated
- 2025/07/31
- Product number
- D3788
- Product name
- 2,3-Diaminotoluene
- Purity
- >97.0%(GC)(T)
- Packaging
- 25g
- Price
- $654
- Updated
- 2025/07/31
- Product number
- D416825
- Product name
- 2,3-Diaminotoluene
- Packaging
- 5g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 3730-1-Z9
- Product name
- 2,3-Diaminotoluene
- Purity
- 98%
- Packaging
- 1g
- Price
- $16
- Updated
- 2021/12/16
2,3-DIAMINOTOLUENE Chemical Properties,Usage,Production
Chemical Properties
brown powder
Uses
Inducer of CYP1A activity, and possible mutagenic carcinogen.
General Description
The antitumour activity of Pd(II) and Pt(II) new complexes with 2,3-diaminotoluene was studied. 2,3-Diaminotoluene induced CYP1A activity.
Synthesis
570-24-1
2687-25-4
General procedure for the synthesis of 2,3-diaminotoluene from 2-methyl-6-nitroaniline: 4.0 g of 10% palladium-carbon catalyst (51.5% in water) was added to 200 ml of ethanol solution containing 8.50 g (55.9 mmol) of 2-methyl-6-nitroaniline. The reaction mixture was stirred at room temperature and atmospheric pressure in a hydrogen atmosphere for 4 hours. Upon completion of the reaction, the catalyst was removed by filtration and the solvent was subsequently removed by evaporation from the filtrate to afford 6.64 g (97% yield) of 2,3-diaminotoluene crude product in the form of black crystals. The product could be used directly in the subsequent reaction without further purification.1H-NMR (CDCl3) δ: 2.22 (3H, s), 3.35-3.40 (4H, m), 6.62-6.68 (3H, m).
References
[1] Patent: EP1479681, 2004, A1. Location in patent: Page 110
[2] Polyhedron, 2016, vol. 105, p. 137 - 149
[3] Patent: US2012/130078, 2012, A1. Location in patent: Page/Page column 6
[4] Heterocycles, 1997, vol. 45, # 5, p. 955 - 962
[5] ACS Medicinal Chemistry Letters, 2017, vol. 8, # 5, p. 543 - 548
2,3-DIAMINOTOLUENE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,3-DIAMINOTOLUENE manufacturers
- Product
- 2,3-DIAMINOTOLUENE 2687-25-4
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-26
- Product
- 2,3-DIAMINOTOLUENE 2687-25-4
- Price
- US $22.00/KG
- Min. Order
- 1g
- Purity
- 99.9%
- Supply Ability
- 500000kgs
- Release date
- 2021-08-13
- Product
- 2,3-DIAMINOTOLUENE 2687-25-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-11