ChemicalBook > CAS DataBase List > 2,3-DIAMINOTOLUENE

2,3-DIAMINOTOLUENE

Product Name
2,3-DIAMINOTOLUENE
CAS No.
2687-25-4
Chemical Name
2,3-DIAMINOTOLUENE
Synonyms
Toluene-2,3-diamine;2,3-DAT;25KGS/DRUM;2.3-DiaMinotol;2,3-Dhamphetamine;2,3-Diaminotoluone;2,3-Diaminetoluene;2,3-TOLUENEDIAMINE;2,3-DIAMINOTOLUENE;2,3-Tolylenediamine
CBNumber
CB2736932
Molecular Formula
C7H10N2
Formula Weight
122.17
MOL File
2687-25-4.mol
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2,3-DIAMINOTOLUENE Property

Melting point:
59-65 °C (lit.)
Boiling point:
225°C
Density 
1.0343 (rough estimate)
refractive index 
1.5103 (estimate)
Flash point:
225°C
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Dichloromethane
pka
4.28±0.10(Predicted)
form 
Powder or Crystals
color 
Brown to dark brown
BRN 
907184
InChI
InChI=1S/C7H10N2/c1-5-3-2-4-6(8)7(5)9/h2-4H,8-9H2,1H3
InChIKey
AXNUJYHFQHQZBE-UHFFFAOYSA-N
SMILES
C1(N)=CC=CC(C)=C1N
CAS DataBase Reference
2687-25-4(CAS DataBase Reference)
EPA Substance Registry System
1,2-Benzenediamine, 3-methyl- (2687-25-4)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36-36/37/39
RIDADR 
2811
WGK Germany 
3
RTECS 
XS9550000
Hazard Note 
Harmful/Irritant
TSCA 
Yes
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29214990
Hazardous Substances Data
2687-25-4(Hazardous Substances Data)
Toxicity
mouse,LD50,intraperitoneal,286mg/kg (286mg/kg),Genetica Polonica. Vol. 26, Pg. 109, 1985.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
272361
Product name
2,3-Diaminotoluene
Purity
97%
Packaging
5g
Price
$99.8
Updated
2025/07/31
TCI Chemical
Product number
D3788
Product name
2,3-Diaminotoluene
Purity
>97.0%(GC)(T)
Packaging
5g
Price
$177
Updated
2025/07/31
TCI Chemical
Product number
D3788
Product name
2,3-Diaminotoluene
Purity
>97.0%(GC)(T)
Packaging
25g
Price
$654
Updated
2025/07/31
TRC
Product number
D416825
Product name
2,3-Diaminotoluene
Packaging
5g
Price
$75
Updated
2021/12/16
SynQuest Laboratories
Product number
3730-1-Z9
Product name
2,3-Diaminotoluene
Purity
98%
Packaging
1g
Price
$16
Updated
2021/12/16
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2,3-DIAMINOTOLUENE Chemical Properties,Usage,Production

Chemical Properties

brown powder

Uses

Inducer of CYP1A activity, and possible mutagenic carcinogen.

General Description

The antitumour activity of Pd(II) and Pt(II) new complexes with 2,3-diaminotoluene was studied. 2,3-Diaminotoluene induced CYP1A activity.

Synthesis

570-24-1

2687-25-4

General procedure for the synthesis of 2,3-diaminotoluene from 2-methyl-6-nitroaniline: 4.0 g of 10% palladium-carbon catalyst (51.5% in water) was added to 200 ml of ethanol solution containing 8.50 g (55.9 mmol) of 2-methyl-6-nitroaniline. The reaction mixture was stirred at room temperature and atmospheric pressure in a hydrogen atmosphere for 4 hours. Upon completion of the reaction, the catalyst was removed by filtration and the solvent was subsequently removed by evaporation from the filtrate to afford 6.64 g (97% yield) of 2,3-diaminotoluene crude product in the form of black crystals. The product could be used directly in the subsequent reaction without further purification.1H-NMR (CDCl3) δ: 2.22 (3H, s), 3.35-3.40 (4H, m), 6.62-6.68 (3H, m).

References

[1] Patent: EP1479681, 2004, A1. Location in patent: Page 110
[2] Polyhedron, 2016, vol. 105, p. 137 - 149
[3] Patent: US2012/130078, 2012, A1. Location in patent: Page/Page column 6
[4] Heterocycles, 1997, vol. 45, # 5, p. 955 - 962
[5] ACS Medicinal Chemistry Letters, 2017, vol. 8, # 5, p. 543 - 548

2,3-DIAMINOTOLUENE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,3-DIAMINOTOLUENE Suppliers

Liling Chuangli Technology Co. LTD
Tel
0534-8101711 13606437406
Fax
0534-8101711
Email
sales@chuanglichem.com
Country
China
ProdList
46
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58
Shanghai Arbor Chemical Co., Ltd.
Tel
021-60451683 15021268886
Fax
+86-21-60451682
Email
sales@arborchemical.com
Country
China
ProdList
896
Advantage
55
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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81
Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9400
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55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
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66
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9883
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59
Shanghai Harvest Chemical Industrial Co., Ltd.
Tel
021-31038972,31038973 17321035817
Fax
+86-21-51385350
Email
sales@harvest-chem.com
Country
China
ProdList
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View Lastest Price from 2,3-DIAMINOTOLUENE manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
2,3-DIAMINOTOLUENE 2687-25-4
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-26
Shijiazhuang tongyang Import and Export Co., LTD
Product
2,3-DIAMINOTOLUENE 2687-25-4
Price
US $22.00/KG
Min. Order
1g
Purity
99.9%
Supply Ability
500000kgs
Release date
2021-08-13
Career Henan Chemical Co
Product
2,3-DIAMINOTOLUENE 2687-25-4
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-11

2687-25-4, 2,3-DIAMINOTOLUENERelated Search:


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