(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID

Product Name: (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
CAS No.: 560-09-8
Chemical Name: (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
Synonyms: Acid, L-caMphor;(-)-CAMPHORIC ACID;(+)-Camphoric Acid;(-)-Camphoric acid;L-(-)-CAMPHORIC ACID;(1S,3R)-CAMPHORIC ACID;(1S,3R)-(-)-CAMPHORIC ACID;(1S,3R)-(-)-CaMphoric acid 99%;(-)-CAMPHORIC ACID, UNNATURAL FORM;L-Camphoric acid|||Camphoric acid, (-)-
CBNumber: CB2738895
Molecular Formula: C10H16O4
Formula Weight: 200.23
MOL File: 560-09-8.mol

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(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Property

Melting point:: 188-190 °C(lit.)
Boiling point:: 312.0±25.0 °C(Predicted)
Density: 1.177±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: DMSO, Ethanol, Methanol
form: Solid
pka: 4.57±0.60(Predicted)
color: White to Off-White
optical activity: [α]20/D 48°, c = 10 in ethanol
BRN: 1874674
CAS DataBase Reference: 560-09-8(CAS DataBase Reference)

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
HS Code: 29172090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 376345
Product name: (1S,3R)-(?)-Camphoric acid
Purity: 99%
Packaging: 1g
Price: $136
Updated: 2024/03/01

TCI Chemical

Product number: C3237
Product name: (1S,3R)-(-)-Camphoric Acid
Purity: >98.0%(GC)(T)
Packaging: 1g
Price: $102
Updated: 2024/03/01

Alfa Aesar

Product number: H54042
Product name: (1S,3R)-(-)-Camphoric acid, 98%
Packaging: 1g
Price: $99.65
Updated: 2024/03/01

Alfa Aesar

Product number: H54042
Product name: (1S,3R)-(-)-Camphoric acid, 98%
Packaging: 5g
Price: $486.65
Updated: 2024/03/01

Alfa Aesar

Product number: H54042
Product name: (1S,3R)-(-)-Camphoric acid, 98%
Packaging: 250mg
Price: $38.65
Updated: 2024/03/01

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(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

(1S,3R)-(?)-Camphoric acid can be used:

As an enantiomeric linker in the preparation of chiral surface-anchored metal-organic frameworks (MOFs).
To prepare porous MOFs having multifunctional properties; used in gas adsorption and separation of racemic alcohols.
To prepare a cobalt(II) coordination polymer named {Co(phen)(H₂O)[C₈H₁₄(COO)₂]}_n·(CH₃OH)_n , wherein “phen” is 1,10-phenanthroline and C₈H₁₄(COOH)₂ is [(1S,3R)-camphoric acid.

storage

+4°C

Purification Methods

Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933

(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Suppliers

Americas 1 Canada 1 China 88 Europe 2 India 5 Japan 1 South Korea 1 Switzerland 2 The Netherlands 1 United Kingdom 4 United States 18 Global 124

TCI AMERICA

Tel: 800-4238616
Fax: +1-888-520-1075 / +1-503-283-1987
Email: sales@tciamerica.com
Country: Americas
ProdList: 23653
Advantage: 75

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View Lastest Price from (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (1S,3R)-()-Camphoric acid 560-09-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID 560-09-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95-99%
Supply Ability: 1ton
Release date: 2020-01-03

560-09-8, (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACIDRelated Search:

(1S)-(-)-Camphanic acid BARIUM D-3-TRIFLUOROACETYLCAMPHORATE D-(+)-Camphoric acid (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID DL-CAMPHORIC ACID PR(FACAM)3 EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE] (-)-Camphanic acid chloride DL-CAMPHORIC ACID EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE DL-CAMPHORIC ANHYDRIDE PRASEODYM(III)-TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-I-CAMPHORATE] YTTERBIUM D-3-TRIFLUOROACETYLCAMPHORATE 1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid 1-[1-(4-methylphenyl)ethyl] ester 1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid hydrogen 1-(1-phenylpentyl) ester 1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid dimethyl ester [1R,3R,(-)]-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid 1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid disodium salt

(-)-Camphoric acid, (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid

(1S)-1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid

(1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid

[1S,(-)]-1,2,2-Trimethyl-1α,3α-cyclopentanedicarboxylic acid

1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid

(-)-CAMPHORIC ACID, UNNATURAL FORM

Acid, L-caMphor

(1S,3R)-(-)-CaMphoric acid 99%

(1<i>S</i>,3<i>R</i>)-(-)-Camphoric Acid

(-)-CAMPHORIC ACID

L-(-)-CAMPHORIC ACID

(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID

(1S,3R)-(-)-CAMPHORIC ACID

(1S,3R)-CAMPHORIC ACID

1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1S,3R)-

(+)-Camphoric Acid

(-)-Camphoric acid

L-Camphoric acid|||Camphoric acid, (-)-

560-09-8

Chiral Resolving Reagents

Chiral Resolution Reagents

Asymmetric Synthesis

Chiral Reagents

Miscellaneous Reagents

Chiral Compound