D-(+)-Camphoric acid

Product Name: D-(+)-Camphoric acid
CAS No.: 124-83-4
Chemical Name: D-(+)-Camphoric acid
Synonyms: (1R,3S)-CAMPHORIC ACID;(1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid;(1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-;D-caMphor acid;D-(+)-Camphoric;(+)-CAMPHORIC ACID;D-(+)-Camphoricaci;D-(+)-Camphoric acid;Dextro-camphoric acid
CBNumber: CB5296789
Molecular Formula: C10H16O4
Formula Weight: 200.23
MOL File: 124-83-4.mol

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D-(+)-Camphoric acid Property

Melting point:: 186-189 °C
alpha: 46.5 º (c=10, C2H5OH)
Boiling point:: 297.96°C (rough estimate)
Density: 1.1860
refractive index: 1.4459 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly)
pka: pK1: 4.57;pK2: 5.10 (25°C)
form: Crystalline Powder
color: White
optical activity: [α]20/D 46°, c = 1 in ethanol
Water Solubility: 0.8 g/100 mL
Merck: 14,1733
BRN: 2050204
CAS DataBase Reference: 124-83-4(CAS DataBase Reference)
NIST Chemistry Reference: D-camphoric acid(124-83-4)
EPA Substance Registry System: 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R,3S)- (124-83-4)

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Safety

Hazard Codes: Xn
Risk Statements: 22
Safety Statements: 24/25
WGK Germany: 2
TSCA: Yes
HS Code: 29172090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: C409
Product name: (1R,3S)-(+)-Camphoric acid
Purity: 99%
Packaging: 5g
Price: $49.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: C409
Product name: (1R,3S)-(+)-Camphoric acid
Purity: 99%
Packaging: 100g
Price: $101
Updated: 2024/03/01

TCI Chemical

Product number: C0012
Product name: (+)-Camphoric Acid
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $85
Updated: 2024/03/01

TCI Chemical

Product number: C0012
Product name: (+)-Camphoric Acid
Purity: >98.0%(GC)(T)
Packaging: 100g
Price: $233
Updated: 2024/03/01

Alfa Aesar

Product number: B23106
Product name: (1R,3S)-(+)-Camphoric acid, 98+%
Packaging: 25g
Price: $30.65
Updated: 2024/03/01

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D-(+)-Camphoric acid Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

D-(+)-Camphoric acid is used primarily as a reagent in syntheses of crystalline structures. It is used in the preparation of polymeric transition metal dipyridylamine D-camphorate complexes.

Uses

(1R,3S)-(+)-Camphoric acid may be used in the preparation (1R,2S,3R,5S)-2,3-dibenzyl-1,8,8-trimethyl-3-thianiumbicyclo[3.2.1]octane perchlorate. It reacts with uranyl nitrate in pyridine(py) or py/methanol(MeOH) to form novel uranyl-organic assemblages.

Definition

ChEBI: (?)-Camphoric acid is a dicarboxylic acid.

General Description

Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.

storage

+4°C

Purification Methods

Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933

D-(+)-Camphoric acid Preparation Products And Raw materials

Raw materials

Camphor

Preparation Products

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D-(+)-Camphoric acid Suppliers

Americas 1 Belgium 1 Canada 1 China 247 Europe 3 Germany 3 India 9 Japan 5 Poland 1 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 2 Ukraine 1 United Kingdom 11 United States 38 Global 327

HUNAN CHEMFISH SCIENTIFIC CO.,LTD

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Alfa Aesar

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Beijing HwrkChemical Technology Co., Ltd

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Energy Chemical

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View Lastest Price from D-(+)-Camphoric acid manufacturers

Baoji Guokang Bio-Technology Co., Ltd.

Product: D-(+)-Camphoric acid 124-83-4
Price: US $300.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 10000KG
Release date: 2021-06-02

Hebei Weibang Biotechnology Co., Ltd

Product: D-(+)-Camphoric acid 124-83-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2022-11-11

henan kanbei chemical co.,ltd

Product: D-(+)-Camphoric acid 124-83-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-19

124-83-4, D-(+)-Camphoric acidRelated Search:

Citric acid (+/-)-10-CAMPHORSULFONIC ACID SODIUM SALT DL-Camphor Camphor Bromocyclopentane Cyclopentane Ethyl 2-(Chlorosulfonyl)acetate Methylcyclopentane Hyaluronic acid Cyclopentyl chloride Trimethyl borate Stearic acid (1R)-(-)-10-Camphorsulfonic acid Folic acid White camphor oil LEVOCARNITINE RELATED COMPOUND A (100 MG) (3-CARBOXY-N,N,N-TRIMETHYL-2-PROPEN-1-AMINIUM CHLORIDE) 4-CHLORO-3-HYDROXY BUTYRONITRILE Levocarnitine iMpurity

(1R,3S)-(+)-CAMPHORIC ACID

(1R,3S)-CAMPHORIC ACID

(1R,3S)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID

(+)-CAMPHORIC ACID

1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-

D-caMphor acid

D(+)-CaMphoric acid, 99% 100GR

(1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid

(1RS,3SR)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid(caMphoric acid)

(1R,3S)-(+)-Camphoric acid 99%

(1R,3S)-(+)-Camphoric acid, >=99%

1,3-Cyclopentanedicarboxylicacid, 1,2,2-trimethyl-, (1R,3S)-

(1R,3S)-(+)-Camphoric acid D(+)-Camphoric acid (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid

Levocarnitine EP Impurity B

Levocarnitine Impurity 2（Levocarnitine EP Impurity B）

2,2-trimethyl-3-cyclopentanedicarboxylicaci(1theta-cis)-1

Cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylicacid

Dextro-camphoric acid

(+)-CAMPHORIC ACID, NATURAL

1,2,2-Trimethyl-1,3-cyclopentanedicarbonsaeure

D-(+)-Camphoric

(1R,3S)-(+)-Camphoric acid, 98+%

(+)-Camphoric acid, (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid

(1R)-cis-Camphoric acid

cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid, (1R)

1,2,2-Trimethyl-1β,3β-cyclopentanedicarboxylic acid

D(+)-Camphoric acid,99%

D-(+)-Camphoric acid

(1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid

(+)-Camphoric Acid &gt

Levocarnitine Impurity B (D-(+)-Camphoric Acid)

D-(+)-Camphoric acid USP/EP/BP

(1R,3S)-1,2,2-trimethylcyclopentane-1,3-dicarboxylate

D-(+)-Camphoricaci

124-83-4

Chiral Resolving Reagents

Chiral Resolution Reagents

Asymmetric Synthesis

Optical Resolution

Bicyclic Monoterpenes

for Resolution of Bases

Terpenes

Bicyclic Monoterpenes

Biochemistry

for Resolution of Bases

Optical Resolution

Synthetic Organic Chemistry

Terpenes

Chiral Compound

Pharmaceutical Intermediates

FINE Chemical & INTERMEDIATES

Miscellaneous Natural Products

chiral

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