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D-(+)-Camphoric acid

Product Name
D-(+)-Camphoric acid
CAS No.
124-83-4
Chemical Name
D-(+)-Camphoric acid
Synonyms
(1R,3S)-CAMPHORIC ACID;(1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid;(1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-;D-caMphor acid;D-(+)-Camphoric;(+)-CAMPHORIC ACID;D-(+)-Camphoricaci;D-(+)-Camphoric acid;Dextro-camphoric acid
CBNumber
CB5296789
Molecular Formula
C10H16O4
Formula Weight
200.23
MOL File
124-83-4.mol
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D-(+)-Camphoric acid Property

Melting point:
186-189 °C
alpha 
46.5 º (c=10, C2H5OH)
Boiling point:
297.96°C (rough estimate)
Density 
1.1860
refractive index 
1.4459 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly)
form 
Crystalline Powder
pka
pK1: 4.57;pK2: 5.10 (25°C)
color 
White
optical activity
[α]20/D 46°, c = 1 in ethanol
Water Solubility 
0.8 g/100 mL
Merck 
14,1733
BRN 
2050204
CAS DataBase Reference
124-83-4(CAS DataBase Reference)
NIST Chemistry Reference
D-camphoric acid(124-83-4)
EPA Substance Registry System
1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R,3S)- (124-83-4)
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Safety

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
24/25
WGK Germany 
2
TSCA 
Yes
HS Code 
29172090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
C409
Product name
(1R,3S)-(+)-Camphoric acid
Purity
99%
Packaging
5g
Price
$49.6
Updated
2024/03/01
Sigma-Aldrich
Product number
C409
Product name
(1R,3S)-(+)-Camphoric acid
Purity
99%
Packaging
100g
Price
$101
Updated
2024/03/01
TCI Chemical
Product number
C0012
Product name
(+)-Camphoric Acid
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$85
Updated
2024/03/01
TCI Chemical
Product number
C0012
Product name
(+)-Camphoric Acid
Purity
>98.0%(GC)(T)
Packaging
100g
Price
$233
Updated
2024/03/01
Alfa Aesar
Product number
B23106
Product name
(1R,3S)-(+)-Camphoric acid, 98+%
Packaging
25g
Price
$30.65
Updated
2024/03/01
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D-(+)-Camphoric acid Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

D-(+)-Camphoric acid is used primarily as a reagent in syntheses of crystalline structures. It is used in the preparation of polymeric transition metal dipyridylamine D-camphorate complexes.

Uses

(1R,3S)-(+)-Camphoric acid may be used in the preparation (1R,2S,3R,5S)-2,3-dibenzyl-1,8,8-trimethyl-3-thianiumbicyclo[3.2.1]octane perchlorate. It reacts with uranyl nitrate in pyridine(py) or py/methanol(MeOH) to form novel uranyl-organic assemblages.

Definition

ChEBI: (?)-Camphoric acid is a dicarboxylic acid.

General Description

Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.

storage

+4°C

Purification Methods

Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933

D-(+)-Camphoric acid Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from D-(+)-Camphoric acid manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
D-(+)-Camphoric acid 124-83-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-11-11
Baoji Guokang Bio-Technology Co., Ltd.
Product
D-(+)-Camphoric acid 124-83-4
Price
US $300.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
10000KG
Release date
2021-06-02
henan kanbei chemical co.,ltd
Product
D-(+)-Camphoric acid 124-83-4
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-19

124-83-4, D-(+)-Camphoric acidRelated Search:


  • (1R,3S)-(+)-CAMPHORIC ACID
  • (1R,3S)-CAMPHORIC ACID
  • (1R,3S)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
  • (+)-CAMPHORIC ACID
  • 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-
  • D-caMphor acid
  • D(+)-CaMphoric acid, 99% 100GR
  • (1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid
  • (1RS,3SR)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid(caMphoric acid)
  • (1R,3S)-(+)-Camphoric acid 99%
  • (1R,3S)-(+)-Camphoric acid, >=99%
  • 1,3-Cyclopentanedicarboxylicacid, 1,2,2-trimethyl-, (1R,3S)-
  • (1R,3S)-(+)-Camphoric acid D(+)-Camphoric acid (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
  • Levocarnitine EP Impurity B
  • Levocarnitine Impurity 2(Levocarnitine EP Impurity B)
  • 2,2-trimethyl-3-cyclopentanedicarboxylicaci(1theta-cis)-1
  • Cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylicacid
  • Dextro-camphoric acid
  • (+)-CAMPHORIC ACID, NATURAL
  • 1,2,2-Trimethyl-1,3-cyclopentanedicarbonsaeure
  • D-(+)-Camphoric
  • (1R,3S)-(+)-Camphoric acid, 98+%
  • (+)-Camphoric acid, (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
  • (1R)-cis-Camphoric acid
  • cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid, (1R)
  • 1,2,2-Trimethyl-1β,3β-cyclopentanedicarboxylic acid
  • D(+)-Camphoric acid,99%
  • D-(+)-Camphoric acid
  • (1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid
  • (+)-Camphoric Acid &gt
  • Levocarnitine Impurity B (D-(+)-Camphoric Acid)
  • D-(+)-Camphoric acid USP/EP/BP
  • (1R,3S)-1,2,2-trimethylcyclopentane-1,3-dicarboxylate
  • D-(+)-Camphoricaci
  • 124-83-4
  • Chiral Resolving Reagents
  • Chiral Resolution Reagents
  • Asymmetric Synthesis
  • Optical Resolution
  • Bicyclic Monoterpenes
  • for Resolution of Bases
  • Terpenes
  • Bicyclic Monoterpenes
  • Biochemistry
  • for Resolution of Bases
  • Optical Resolution
  • Synthetic Organic Chemistry
  • Terpenes
  • Chiral Compound
  • Pharmaceutical Intermediates
  • FINE Chemical & INTERMEDIATES
  • Miscellaneous Natural Products
  • chiral