ChemicalBook > CAS DataBase List > D-(+)-Camphoric acid
D-(+)-Camphoric acid
- Product Name
- D-(+)-Camphoric acid
- CAS No.
- 124-83-4
- Chemical Name
- D-(+)-Camphoric acid
- Synonyms
- (1R,3S)-CAMPHORIC ACID;(1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid;(1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-;D-caMphor acid;D-(+)-Camphoric;(+)-CAMPHORIC ACID;D-(+)-Camphoricaci;D-(+)-Camphoric acid;Dextro-camphoric acid
- CBNumber
- CB5296789
- Molecular Formula
- C10H16O4
- Formula Weight
- 200.23
- MOL File
- 124-83-4.mol
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D-(+)-Camphoric acid Property
- Melting point:
- 186-189 °C
- alpha
- 46.5 º (c=10, C2H5OH)
- Boiling point:
- 297.96°C (rough estimate)
- Density
- 1.1860
- refractive index
- 1.4459 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly)
- pka
- pK1: 4.57;pK2: 5.10 (25°C)
- form
- Crystalline Powder
- color
- White
- optical activity
- [α]20/D 46°, c = 1 in ethanol
- Water Solubility
- 0.8 g/100 mL
- Merck
- 14,1733
- BRN
- 2050204
- CAS DataBase Reference
- 124-83-4(CAS DataBase Reference)
- NIST Chemistry Reference
- D-camphoric acid(124-83-4)
- EPA Substance Registry System
- 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R,3S)- (124-83-4)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- C409
- Product name
- (1R,3S)-(+)-Camphoric acid
- Purity
- 99%
- Packaging
- 5g
- Price
- $49.6
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- C409
- Product name
- (1R,3S)-(+)-Camphoric acid
- Purity
- 99%
- Packaging
- 100g
- Price
- $101
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C0012
- Product name
- (+)-Camphoric Acid
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $85
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C0012
- Product name
- (+)-Camphoric Acid
- Purity
- >98.0%(GC)(T)
- Packaging
- 100g
- Price
- $233
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- B23106
- Product name
- (1R,3S)-(+)-Camphoric acid, 98+%
- Packaging
- 25g
- Price
- $30.65
- Updated
- 2024/03/01
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D-(+)-Camphoric acid Chemical Properties,Usage,Production
Chemical Properties
white to light yellow crystal powde
Uses
D-(+)-Camphoric acid is used primarily as a reagent in syntheses of crystalline structures. It is used in the preparation of polymeric transition metal dipyridylamine D-camphorate complexes.
Uses
(1R,3S)-(+)-Camphoric acid may be used in the preparation (1R,2S,3R,5S)-2,3-dibenzyl-1,8,8-trimethyl-3-thianiumbicyclo[3.2.1]octane perchlorate. It reacts with uranyl nitrate in pyridine(py) or py/methanol(MeOH) to form novel uranyl-organic assemblages.
Definition
ChEBI: (?)-Camphoric acid is a dicarboxylic acid.
General Description
Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.
storage
+4°C
Purification Methods
Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933
D-(+)-Camphoric acid Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from D-(+)-Camphoric acid manufacturers
Baoji Guokang Bio-Technology Co., Ltd.
- Product
- D-(+)-Camphoric acid 124-83-4
- Price
- US $300.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 10000KG
- Release date
- 2021-06-02
Hebei Weibang Biotechnology Co., Ltd
- Product
- D-(+)-Camphoric acid 124-83-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2022-11-11
henan kanbei chemical co.,ltd
- Product
- D-(+)-Camphoric acid 124-83-4
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-19
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