ChemicalBook > CAS DataBase List > (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID

(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID

Product Name
(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
CAS No.
560-09-8
Chemical Name
(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
Synonyms
Acid, L-caMphor;(-)-CAMPHORIC ACID;(+)-Camphoric Acid;(-)-Camphoric acid;L-(-)-CAMPHORIC ACID;(1S,3R)-CAMPHORIC ACID;(1S,3R)-(-)-CAMPHORIC ACID;(1S,3R)-(-)-CaMphoric acid 99%;(-)-CAMPHORIC ACID, UNNATURAL FORM;(1S,3R)-(-)-Camphoric Acid
CBNumber
CB2738895
Molecular Formula
C10H16O4
Formula Weight
200.23
MOL File
560-09-8.mol
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(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Property

Melting point:
188-190 °C(lit.)
Boiling point:
312.0±25.0 °C(Predicted)
Density 
1.177±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO, Ethanol, Methanol
form 
Solid
pka
4.57±0.60(Predicted)
color 
White to Off-White
optical activity
[α]20/D 48°, c = 10 in ethanol
BRN 
1874674
CAS DataBase Reference
560-09-8(CAS DataBase Reference)
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Safety

Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29172090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
376345
Product name
(1S,3R)-(?)-Camphoric acid
Purity
99%
Packaging
1g
Price
$136
Updated
2024/03/01
TCI Chemical
Product number
C3237
Product name
(1S,3R)-(-)-Camphoric Acid
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$102
Updated
2024/03/01
Alfa Aesar
Product number
H54042
Product name
(1S,3R)-(-)-Camphoric acid, 98%
Packaging
1g
Price
$99.65
Updated
2024/03/01
Alfa Aesar
Product number
H54042
Product name
(1S,3R)-(-)-Camphoric acid, 98%
Packaging
5g
Price
$486.65
Updated
2024/03/01
Alfa Aesar
Product number
H54042
Product name
(1S,3R)-(-)-Camphoric acid, 98%
Packaging
250mg
Price
$38.65
Updated
2024/03/01
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(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

(1S,3R)-(?)-Camphoric acid can be used:

  • As an enantiomeric linker in the preparation of chiral surface-anchored metal-organic frameworks (MOFs).
  • To prepare porous MOFs having multifunctional properties; used in gas adsorption and separation of racemic alcohols.
  • To prepare a cobalt(II) coordination polymer named {Co(phen)(H2O)[C8H14(COO)2]}n·(CH3OH)n , wherein “phen” is 1,10-phenanthroline and C8H14(COOH)2 is [(1S,3R)-camphoric acid.

storage

+4°C

Purification Methods

Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933

(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Suppliers

Americas 1 Canada 1 China 86 Europe 2 India 5 Japan 1 South Korea 1 Switzerland 2 The Netherlands 1 United Kingdom 4 United States 19 Global 123
TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(1S,3R)-()-Camphoric acid 560-09-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID 560-09-8
Price
US $1.00/KG
Min. Order
1KG
Purity
95-99%
Supply Ability
1ton
Release date
2020-01-03

560-09-8, (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACIDRelated Search:

(1S)-(-)-Camphanic acid BARIUM D-3-TRIFLUOROACETYLCAMPHORATE D-(+)-Camphoric acid (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID DL-CAMPHORIC ACID PR(FACAM)3 EUROPIUM TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-(+)-CAMPHORATE] (-)-Camphanic acid chloride DL-CAMPHORIC ACID EUROPIUM D-3-TRIFLUOROACETYLCAMPHORATE DL-CAMPHORIC ANHYDRIDE PRASEODYM(III)-TRIS[3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-I-CAMPHORATE] YTTERBIUM D-3-TRIFLUOROACETYLCAMPHORATE 1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid 1-[1-(4-methylphenyl)ethyl] ester 1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid hydrogen 1-(1-phenylpentyl) ester 1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid dimethyl ester [1R,3R,(-)]-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid 1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid disodium salt

  • (-)-Camphoric acid, (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
  • (1S)-1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid
  • (1S,3R)-1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid
  • [1S,(-)]-1,2,2-Trimethyl-1α,3α-cyclopentanedicarboxylic acid
  • 1,2,2-Trimethylcyclopentane-1α,3α-dicarboxylic acid
  • (-)-CAMPHORIC ACID, UNNATURAL FORM
  • Acid, L-caMphor
  • (1S,3R)-(-)-CaMphoric acid 99%
  • (1<i>S</i>,3<i>R</i>)-(-)-Camphoric Acid
  • (-)-CAMPHORIC ACID
  • L-(-)-CAMPHORIC ACID
  • (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
  • (1S,3R)-(-)-CAMPHORIC ACID
  • (1S,3R)-CAMPHORIC ACID
  • 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1S,3R)-
  • (+)-Camphoric Acid
  • (-)-Camphoric acid
  • 560-09-8
  • Chiral Resolving Reagents
  • Chiral Resolution Reagents
  • Asymmetric Synthesis
  • Chiral Reagents
  • Miscellaneous Reagents
  • Chiral Compound