(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
- Product Name
- (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
- CAS No.
- 560-09-8
- Chemical Name
- (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID
- Synonyms
- Acid, L-caMphor;(-)-CAMPHORIC ACID;(+)-Camphoric Acid;(-)-Camphoric acid;L-(-)-CAMPHORIC ACID;(1S,3R)-CAMPHORIC ACID;(1S,3R)-(-)-CAMPHORIC ACID;(1S,3R)-(-)-CaMphoric acid 99%;(-)-CAMPHORIC ACID, UNNATURAL FORM;(1S,3R)-(-)-Camphoric Acid
- CBNumber
- CB2738895
- Molecular Formula
- C10H16O4
- Formula Weight
- 200.23
- MOL File
- 560-09-8.mol
(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Property
- Melting point:
- 188-190 °C(lit.)
- Boiling point:
- 312.0±25.0 °C(Predicted)
- Density
- 1.177±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- DMSO, Ethanol, Methanol
- form
- Solid
- pka
- 4.57±0.60(Predicted)
- color
- White to Off-White
- optical activity
- [α]20/D 48°, c = 10 in ethanol
- BRN
- 1874674
- CAS DataBase Reference
- 560-09-8(CAS DataBase Reference)
Safety
- Safety Statements
- 22-24/25
- WGK Germany
- 3
- HS Code
- 29172090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 376345
- Product name
- (1S,3R)-(?)-Camphoric acid
- Purity
- 99%
- Packaging
- 1g
- Price
- $136
- Updated
- 2024/03/01
- Product number
- C3237
- Product name
- (1S,3R)-(-)-Camphoric Acid
- Purity
- >98.0%(GC)(T)
- Packaging
- 1g
- Price
- $102
- Updated
- 2024/03/01
- Product number
- H54042
- Product name
- (1S,3R)-(-)-Camphoric acid, 98%
- Packaging
- 1g
- Price
- $99.65
- Updated
- 2024/03/01
- Product number
- H54042
- Product name
- (1S,3R)-(-)-Camphoric acid, 98%
- Packaging
- 5g
- Price
- $486.65
- Updated
- 2024/03/01
- Product number
- H54042
- Product name
- (1S,3R)-(-)-Camphoric acid, 98%
- Packaging
- 250mg
- Price
- $38.65
- Updated
- 2024/03/01
(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Chemical Properties,Usage,Production
Chemical Properties
White Solid
Uses
(1S,3R)-(?)-Camphoric acid can be used:
- As an enantiomeric linker in the preparation of chiral surface-anchored metal-organic frameworks (MOFs).
- To prepare porous MOFs having multifunctional properties; used in gas adsorption and separation of racemic alcohols.
- To prepare a cobalt(II) coordination polymer named {Co(phen)(H2O)[C8H14(COO)2]}n·(CH3OH)n , wherein “phen” is 1,10-phenanthroline and C8H14(COOH)2 is [(1S,3R)-camphoric acid.
storage
+4°C
Purification Methods
Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933
(1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID manufacturers
- Product
- (1S,3R)-()-Camphoric acid 560-09-8
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- (1S,3R)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID 560-09-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 95-99%
- Supply Ability
- 1ton
- Release date
- 2020-01-03