Dimethylphenylsilane
- Product Name
- Dimethylphenylsilane
- CAS No.
- 766-77-8
- Chemical Name
- Dimethylphenylsilane
- Synonyms
- ACETATE BUFFER;BUFFER SOLUTION;SODIUM ACETATE BUFFER;PHENYLDIMETHYLSILANE;BUFFER PH7.20;BUFFER PH 4.65;DK894;DK391;FEMA 3900;BUFFER ACETATE
- CBNumber
- CB2854276
- Molecular Formula
- C8H12Si
- Formula Weight
- 136.27
- MOL File
- 766-77-8.mol
Dimethylphenylsilane Property
- Melting point:
- 323-329 °C(lit.)
- Boiling point:
- 157 °C744 mm Hg(lit.)
- Density
- 0.889 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.497(lit.)
- Flash point:
- 95 °F
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- sol common organic solvent such as chloroform, 1,2- dichloroethane, benzene, ether, acetone, dioxane, THF; insol H2O.
- form
- solid
- color
- Colorless to Almost colorless
- Specific Gravity
- 0.889
- Water Solubility
- Not miscible in water.
- Hydrolytic Sensitivity
- 3: reacts with aqueous base
- BRN
- 2204906
- InChIKey
- ZISUALSZTAEPJH-UHFFFAOYSA-N
- CAS DataBase Reference
- 766-77-8(CAS DataBase Reference)
- EPA Substance Registry System
- Silane, dimethylphenyl- (766-77-8)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 10-36
- Safety Statements
- 26-36/39-24/25
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 1
- RTECS
- AJ4375000
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P243Take precautionary measures against static discharge.
N-Bromosuccinimide Price
- Product number
- 235016
- Product name
- Dimethylphenylsilane
- Purity
- ≥98%
- Packaging
- 5g
- Price
- $46.8
- Updated
- 2024/03/01
- Product number
- 235016
- Product name
- Dimethylphenylsilane
- Purity
- ≥98%
- Packaging
- 25g
- Price
- $129
- Updated
- 2024/03/01
- Product number
- D2196
- Product name
- Dimethylphenylsilane
- Purity
- >97.0%(GC)
- Packaging
- 5mL
- Price
- $38
- Updated
- 2024/03/01
- Product number
- D2196
- Product name
- Dimethylphenylsilane
- Purity
- >97.0%(GC)
- Packaging
- 25mL
- Price
- $128
- Updated
- 2024/03/01
- Product number
- L04558
- Product name
- Dimethylphenylsilane, 97%
- Packaging
- 10g
- Price
- $53.8
- Updated
- 2024/03/01
Dimethylphenylsilane Chemical Properties,Usage,Production
Chemical Properties
Clear colorless liquid
Physical properties
bp 157 °C/744 mmHg; d 0.889 g cm?3.
Uses
Diastereoselective Reduction of Carbonyl Compounds.
Hydrosilylation. With a transition metal catalyst, the
hydrosilane adds to carbon–carbon double or triple bonds to
give alkylsilanes or alkenylsilanes.
Hydrosilylating reagent; reductant in combination with acid
or F?).
Uses
Dimethylphenylsilane is a reagent for enol ether synthesis. It acts as a catalyst. Also used as a precursor in Optical Emission Spectroscopy of Plasma Deposition Processes. It can react with vinylbenzene to produce (b-Phenyl-ethyl)-dimethylphenyl-silan.
Application
Used to reduce α-amino ketones to aminoethanols withhigh stereoselectivity. Used in the fluoride ion-catalyzedreduction of aldehydes and ketones, and α-substitutedalkanones to threo products. Erythro reduction of α-substituted alkanones to diols and aminoethanols. Together with CuCl reduces aryl ketones, but not dialkylketones. Used in the silylformylation of acetylenes.Excellent reducing agent for the reduction of enones tosaturated ketones. Shows better selectivity than LAH inthe reduction of oximes to alkoxyamines.
Dimethylphenylsilane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Dimethylphenylsilane manufacturers
- Product
- Dimethylphenylsilane 766-77-8
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1ton
- Release date
- 2022-09-30
- Product
- Dimethylphenylsilane 766-77-8
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2019-12-31