ChemicalBook > CAS DataBase List > Dimethylphenylsilane

Dimethylphenylsilane

Product Name
Dimethylphenylsilane
CAS No.
766-77-8
Chemical Name
Dimethylphenylsilane
Synonyms
ACETATE BUFFER;BUFFER SOLUTION;SODIUM ACETATE BUFFER;PHENYLDIMETHYLSILANE;BUFFER PH7.20;BUFFER PH 4.65;DK894;DK391;FEMA 3900;DKFELEX0236
CBNumber
CB2854276
Molecular Formula
C8H12Si
Formula Weight
136.27
MOL File
766-77-8.mol
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Dimethylphenylsilane Property

Melting point:
323-329 °C(lit.)
Boiling point:
157 °C744 mm Hg(lit.)
Density 
0.889 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.497(lit.)
Flash point:
95 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
sol common organic solvent such as chloroform, 1,2- dichloroethane, benzene, ether, acetone, dioxane, THF; insol H2O.
form 
solid
color 
Colorless to Almost colorless
Specific Gravity
0.889
Water Solubility 
Not miscible in water.
Hydrolytic Sensitivity
3: reacts with aqueous base
BRN 
2204906
InChIKey
ZISUALSZTAEPJH-UHFFFAOYSA-N
CAS DataBase Reference
766-77-8(CAS DataBase Reference)
EPA Substance Registry System
Silane, dimethylphenyl- (766-77-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
10-36
Safety Statements 
26-36/39-24/25
RIDADR 
UN 1993 3/PG 3
WGK Germany 
1
RTECS 
AJ4375000
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P243Take precautionary measures against static discharge.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
235016
Product name
Dimethylphenylsilane
Purity
≥98%
Packaging
5g
Price
$46.8
Updated
2024/03/01
Sigma-Aldrich
Product number
235016
Product name
Dimethylphenylsilane
Purity
≥98%
Packaging
25g
Price
$129
Updated
2024/03/01
TCI Chemical
Product number
D2196
Product name
Dimethylphenylsilane
Purity
>97.0%(GC)
Packaging
5mL
Price
$38
Updated
2024/03/01
TCI Chemical
Product number
D2196
Product name
Dimethylphenylsilane
Purity
>97.0%(GC)
Packaging
25mL
Price
$128
Updated
2024/03/01
Alfa Aesar
Product number
L04558
Product name
Dimethylphenylsilane, 97%
Packaging
10g
Price
$53.8
Updated
2024/03/01
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Dimethylphenylsilane Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Physical properties

bp 157 °C/744 mmHg; d 0.889 g cm?3.

Uses

Diastereoselective Reduction of Carbonyl Compounds.
Hydrosilylation. With a transition metal catalyst, the hydrosilane adds to carbon–carbon double or triple bonds to give alkylsilanes or alkenylsilanes.
Hydrosilylating reagent; reductant in combination with acid or F?).

Uses

Dimethylphenylsilane is a reagent for enol ether synthesis. It acts as a catalyst. Also used as a precursor in Optical Emission Spectroscopy of Plasma Deposition Processes. It can react with vinylbenzene to produce (b-Phenyl-ethyl)-dimethylphenyl-silan.

Application

Used to reduce α-amino ketones to aminoethanols withhigh stereoselectivity. Used in the fluoride ion-catalyzedreduction of aldehydes and ketones, and α-substitutedalkanones to threo products. Erythro reduction of α-substituted alkanones to diols and aminoethanols. Together with CuCl reduces aryl ketones, but not dialkylketones. Used in the silylformylation of acetylenes.Excellent reducing agent for the reduction of enones tosaturated ketones. Shows better selectivity than LAH inthe reduction of oximes to alkoxyamines.

Dimethylphenylsilane Preparation Products And Raw materials

Raw materials

Preparation Products

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Dimethylphenylsilane Suppliers

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View Lastest Price from Dimethylphenylsilane manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
Dimethylphenylsilane 766-77-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Career Henan Chemical Co
Product
Dimethylphenylsilane 766-77-8
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-31

766-77-8, DimethylphenylsilaneRelated Search:

Chlorodimethylpentafluorophenylsilane Triphenylsilane DIPHENYLMETHYLSILANE Chlorodiphenylmethylsilane P-TOLYLTRIMETHYLSILANE AMINODIMETHYLPENTAFLUOROPHENYLSILANE Dimethylphenylsilane Chlorodimethylphenylsilane Tetraphenylsilane DIMETHYL(PENTAFLUOROPHENYL)SILANE tert-Butylchlorodiphenylsilane Triphenylsilyl chloride PHENYLTRIMETHYLSILANE Triphenylsilanol HEXAPHENYLDISILOXANE 1,4-Bis(trimethylsilyl)benzene 1,3-BIS(TRIMETHYLSILYL)BENZENE SODIUM ACETATE BUFFER SOLUTION,SODIUM ACETATE BUFFER

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