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2-Nitrobiphenyl

Product Name
2-Nitrobiphenyl
CAS No.
86-00-0
Chemical Name
2-Nitrobiphenyl
Synonyms
2-NITROBIPHENYL;Onb;cp368;Nitrodiphenyl;2-Nitrobiphneyl;o-Nitrobiphenyl;O-NITRODIPHENYL;2-NITROBIPHENYL;2-NITRODIPHENYL;2-nitro-bipheny
CBNumber
CB2854478
Molecular Formula
C12H9NO2
Formula Weight
199.21
MOL File
86-00-0.mol
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2-Nitrobiphenyl Property

Melting point:
36-38 °C(lit.)
Boiling point:
320 °C
Density 
1.44
vapor density 
5.9 (vs air)
vapor pressure 
2 mm Hg ( 140 °C)
refractive index 
1.613-1.615
Flash point:
>230 °F
form 
powder to lump
color 
White to Yellow to Green
Water Solubility 
Insoluble
Merck 
14,6591
InChI
InChI=1S/C12H9NO2/c14-13(15)12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9H
InChIKey
YOJKKXRJMXIKSR-UHFFFAOYSA-N
SMILES
C1(C2=CC=CC=C2)=CC=CC=C1[N+]([O-])=O
CAS DataBase Reference
86-00-0(CAS DataBase Reference)
NIST Chemistry Reference
1,1'-Biphenyl, 2-nitro-(86-00-0)
EPA Substance Registry System
o-Nitrobiphenyl (86-00-0)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-40-68-22
Safety Statements 
2-7-36-45-36/37
WGK Germany 
3
RTECS 
DV5530000
HS Code 
2904.20.5000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
N0194
Product name
2-Nitrobiphenyl
Purity
>98.0%(GC)
Packaging
25g
Price
$23
Updated
2025/07/31
TCI Chemical
Product number
N0194
Product name
2-Nitrobiphenyl
Purity
>98.0%(GC)
Packaging
500g
Price
$218
Updated
2024/03/01
TRC
Product number
N495803
Product name
2-Nitrobiphenyl
Packaging
2.5g
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
172523
Product name
2-Nitrobiphenyl
Packaging
25g
Price
$100
Updated
2021/12/16
AK Scientific
Product number
Q969
Product name
2-Nitrobiphenyl
Packaging
5g
Price
$34
Updated
2021/12/16
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2-Nitrobiphenyl Chemical Properties,Usage,Production

Chemical Properties

Clear yellow liquid after melting. Insoluble in water, soluble in methanol, ethanol, acetone, dimethylformamide, and tetrahydrofurfuryl alcohol.

Uses

2-Nitrobiphenyl is used as a plasticizer for resins, cellulose acetate, cellulose nitrate, and polystyrenes; as a fungicide for textiles; as a wood preservative; and as a dye intermediate.

Synthesis Reference(s)

Tetrahedron Letters, 36, p. 6567, 1995 DOI: 10.1016/0040-4039(95)01327-E

General Description

Gold to tan crystals or brown solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Aromatic nitro compounds, such as 2-Nitrodiphenyl, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.

Fire Hazard

2-Nitrodiphenyl is combustible.

Purification Methods

Crystallise it from EtOH (seeding required). Sublime it under vacuum. [Beilstein 5 H 582, 5 I 273, 5 II 487, 5 III 1750.]

References

[1] A. SEKINE. 2-nitrobiphenyl and 2,2’-dinitrobiphenyl[J]. Acta crystallographica. Section C, Crystal structure communications, 1994, 26 1: 1101-1104. DOI:10.1107/S0108270194001009.
[2] YOST Y. Carbazole from o-biphenylhydroxylamine and from 2-nitrobiphenyl and phenylmagnesium bromide[J]. Journal of Heterocyclic Chemistry, 1972, 9 1: 151-152. DOI:10.1002/jhet.5570090128.
[3] EVA HORAKOVA. Voltammetric Determination of 2-Nitrobiphenyl and 4-Nitrobiphenyl Using a Mercury Meniscus Modified Silver Solid Amalgam Electrode[J]. International Journal of Electrochemical Science, 2015, 10 3: Pages 2155-2169. DOI:10.1016/S1452-3981(23)04837-X.
[4] JIRO HIGUCHI. Electron paramagnetic resonance study on the triplet species produced from 2-nitrobiphenyl derivatives by UV irradiation[J]. Journal of Photochemistry and Photobiology A-chemistry, 1999, 124 1: Pages 53-65. DOI:10.1016/S1010-6030(99)00075-1.

2-Nitrobiphenyl Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Nitrobiphenyl Suppliers

Suzhou Ankai Technology Co. Ltd.
Tel
0512-68079103 18914035853
Email
401371329@qq.com
Country
China
ProdList
1
Advantage
58
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
China Langchem Inc.
Tel
0086-21-58956006
Fax
0086-21-58956100
Country
China
ProdList
7811
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
6387
Advantage
52
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19913
Advantage
55
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View Lastest Price from 2-Nitrobiphenyl manufacturers

Kindchem(Nanjing)Co.,Ltd
Product
2-Nitrodiphenyl 86-00-0
Price
US $0.00-0.00/kgkg
Min. Order
0.1kgkg
Purity
98%
Supply Ability
2000kg
Release date
2023-06-08
Career Henan Chemical Co
Product
2-Nitrodiphenyl 86-00-0
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100KG
Release date
2018-12-18

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