2-Nitrobiphenyl
- Product Name
- 2-Nitrobiphenyl
- CAS No.
- 86-00-0
- Chemical Name
- 2-Nitrobiphenyl
- Synonyms
- 2-NITROBIPHENYL;Onb;cp368;Nitrodiphenyl;2-Nitrobiphneyl;o-Nitrobiphenyl;O-NITRODIPHENYL;2-NITROBIPHENYL;2-NITRODIPHENYL;2-nitro-bipheny
- CBNumber
- CB2854478
- Molecular Formula
- C12H9NO2
- Formula Weight
- 199.21
- MOL File
- 86-00-0.mol
2-Nitrobiphenyl Property
- Melting point:
- 36-38 °C(lit.)
- Boiling point:
- 320 °C
- Density
- 1.44
- vapor density
- 5.9 (vs air)
- vapor pressure
- 2 mm Hg ( 140 °C)
- refractive index
- 1.613-1.615
- Flash point:
- >230 °F
- form
- powder to lump
- color
- White to Yellow to Green
- Water Solubility
- Insoluble
- Merck
- 14,6591
- InChI
- InChI=1S/C12H9NO2/c14-13(15)12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9H
- InChIKey
- YOJKKXRJMXIKSR-UHFFFAOYSA-N
- SMILES
- C1(C2=CC=CC=C2)=CC=CC=C1[N+]([O-])=O
- CAS DataBase Reference
- 86-00-0(CAS DataBase Reference)
- NIST Chemistry Reference
- 1,1'-Biphenyl, 2-nitro-(86-00-0)
- EPA Substance Registry System
- o-Nitrobiphenyl (86-00-0)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21/22-40-68-22
- Safety Statements
- 2-7-36-45-36/37
- WGK Germany
- 3
- RTECS
- DV5530000
- HS Code
- 2904.20.5000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- N0194
- Product name
- 2-Nitrobiphenyl
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $23
- Updated
- 2025/07/31
- Product number
- N0194
- Product name
- 2-Nitrobiphenyl
- Purity
- >98.0%(GC)
- Packaging
- 500g
- Price
- $218
- Updated
- 2024/03/01
- Product number
- N495803
- Product name
- 2-Nitrobiphenyl
- Packaging
- 2.5g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 214987
- Product name
- 2-Nitro-1,1'-biphenyl
- Purity
- 98%
- Packaging
- 1g
- Price
- $11
- Updated
- 2021/12/16
- Product number
- Q969
- Product name
- 2-Nitrobiphenyl
- Packaging
- 5g
- Price
- $34
- Updated
- 2021/12/16
2-Nitrobiphenyl Chemical Properties,Usage,Production
Chemical Properties
Clear yellow liquid after melting. Insoluble in water, soluble in methanol, ethanol, acetone, dimethylformamide, and tetrahydrofurfuryl alcohol.
Uses
2-Nitrobiphenyl is used as a plasticizer for resins, cellulose acetate, cellulose nitrate, and polystyrenes; as a fungicide for textiles; as a wood preservative; and as a dye intermediate.
Synthesis Reference(s)
Tetrahedron Letters, 36, p. 6567, 1995 DOI: 10.1016/0040-4039(95)01327-E
General Description
Gold to tan crystals or brown solid.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Aromatic nitro compounds, such as 2-Nitrodiphenyl, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.
Fire Hazard
2-Nitrodiphenyl is combustible.
Purification Methods
Crystallise it from EtOH (seeding required). Sublime it under vacuum. [Beilstein 5 H 582, 5 I 273, 5 II 487, 5 III 1750.]
References
[1] A. SEKINE. 2-nitrobiphenyl and 2,2’-dinitrobiphenyl[J]. Acta crystallographica. Section C, Crystal structure communications, 1994, 26 1: 1101-1104. DOI:10.1107/S0108270194001009.
[2] YOST Y. Carbazole from o-biphenylhydroxylamine and from 2-nitrobiphenyl and phenylmagnesium bromide[J]. Journal of Heterocyclic Chemistry, 1972, 9 1: 151-152. DOI:10.1002/jhet.5570090128.
[3] EVA HORAKOVA. Voltammetric Determination of 2-Nitrobiphenyl and 4-Nitrobiphenyl Using a Mercury Meniscus Modified Silver Solid Amalgam Electrode[J]. International Journal of Electrochemical Science, 2015, 10 3: Pages 2155-2169. DOI:10.1016/S1452-3981(23)04837-X.
[4] JIRO HIGUCHI. Electron paramagnetic resonance study on the triplet species produced from 2-nitrobiphenyl derivatives by UV irradiation[J]. Journal of Photochemistry and Photobiology A-chemistry, 1999, 124 1: Pages 53-65. DOI:10.1016/S1010-6030(99)00075-1.
2-Nitrobiphenyl Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-Nitrobiphenyl manufacturers
- Product
- 2-Nitrodiphenyl 86-00-0
- Price
- US $0.00-0.00/kgkg
- Min. Order
- 0.1kgkg
- Purity
- 98%
- Supply Ability
- 2000kg
- Release date
- 2023-06-08
- Product
- 2-Nitrodiphenyl 86-00-0
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2018-12-18