METHYL 2,6-DIFLUORO-3-NITROBENZOATE

Product Name: METHYL 2,6-DIFLUORO-3-NITROBENZOATE
CAS No.: 84832-01-9
Chemical Name: METHYL 2,6-DIFLUORO-3-NITROBENZOATE
Synonyms: METHYL 2,6-DIFLUORO-3-NITROBENZOATE;Benzoic acid, 2,6-difluoro-3-nitro-, methyl ester;Benzoic acid,2,6-difluoro-3-nitro-, methyl ester (Related Reference)
CBNumber: CB31012922
Molecular Formula: C8H5F2NO4
Formula Weight: 217.13
MOL File: 84832-01-9.mol

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METHYL 2,6-DIFLUORO-3-NITROBENZOATE Property

Melting point:: 59.0 to 63.0 °C
Boiling point:: 151°C/9mmHg(lit.)
Density: 1.471±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: Solid
color: White to Almost white
InChI: InChI=1S/C8H5F2NO4/c1-15-8(12)6-4(9)2-3-5(7(6)10)11(13)14/h2-3H,1H3
InChIKey: CIHHBTMZOLRCRL-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=C(F)C=CC([N+]([O-])=O)=C1F

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M2749
Product name: Methyl 2,6-Difluoro-3-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 1g
Price: $24
Updated: 2025/07/31

TCI Chemical

Product number: M2749
Product name: Methyl 2,6-Difluoro-3-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $68
Updated: 2025/07/31

AK Scientific

Product number: Z1808
Product name: Methyl 2,6-Difluoro-3-nitrobenzoate
Packaging: 5g
Price: $52
Updated: 2021/12/16

AK Scientific

Product number: J96465
Product name: Methyl 2,6-Difluoro-3-nitrobenzoate
Packaging: 25g
Price: $120
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0353880
Product name: Methyl 2,6-Difluoro-3-nitrobenzoate
Purity: 95.00%
Packaging: 1G
Price: $137.55
Updated: 2021/12/16

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METHYL 2,6-DIFLUORO-3-NITROBENZOATE Chemical Properties,Usage,Production

Synthesis

13671-00-6

84832-01-9

Step 3: Methyl 2,6-difluorobenzoate (68.8 g, 0.4 mol) was dissolved in methanol. Potassium nitroperoxide (48.5 g, 0.48 mol) was added to concentrated sulfuric acid (300 mL) in three portions under stirring. The reaction mixture was stirred continuously at room temperature for 2 hours. Upon completion of the reaction, the mixture was slowly dripped into ice water (500 mL) and subsequently filtered. The solid product was washed with water and dried to give methyl 2,6-difluoro-3-nitrobenzoate (89 g, 100% yield). The product was characterized by 1H NMR (DMSO-d6): δ 8.49-8.43 (1H, m), 7.56-7.51 (1H, m), 3.95 (3H, s).

References

[1] Patent: WO2013/71865, 2013, A1. Location in patent: Page/Page column 26
[2] Patent: CN103102349, 2017, B. Location in patent: Paragraph 0150-0153
[3] Bioorganic and Medicinal Chemistry Letters, 2013, vol. 23, # 4, p. 1017 - 1021
[4] Patent: WO2011/59610, 2011, A1. Location in patent: Page/Page column 102
[5] Patent: CN104003979, 2016, B. Location in patent: Paragraph 0385-0387

METHYL 2,6-DIFLUORO-3-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 2,6-DIFLUORO-3-NITROBENZOATE Suppliers

Americas 1 China 102 Europe 1 France 1 India 3 Japan 1 Switzerland 1 The Netherlands 1 United Kingdom 3 United States 14 Global 128

Alfa Aesar

Tel: 400-6106006
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Ark Pharm, Inc.

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Accela ChemBio Co.,Ltd.

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Beijing Eternalchem Co,. Ltd.

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Jinan Trio PharmaTech Co., Ltd.

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Suzhou BEC Biological Technology Co., Ltd

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Shanghai potentpharm CO.,Ltd

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TOKYO CHEMICAL INDUSTRY CO., LTD.

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TCI Europe

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TCI AMERICA

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View Lastest Price from METHYL 2,6-DIFLUORO-3-NITROBENZOATE manufacturers

NANJING ACE CHEMICAL CO.,LTD

Product: Methyl 2,6-Difluoro-3-Nitrobenzoate 84832-01-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50 TONS
Release date: 2024-11-11

Career Henan Chemical Co

Product: METHYL 2,6-DIFLUORO-3-NITROBENZOATE 84832-01-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1ton
Release date: 2018-08-06

84832-01-9, METHYL 2,6-DIFLUORO-3-NITROBENZOATERelated Search:

Dimethyl carbonate Methyl 2,6-difluoro-4-Methylbenzoate 4,6-Dibromo-3-hydroxypyridine-2-carboxylic acid methyl ester METHYL 3-BROMO-2-OXO-2H-PYRAN-5-CARBOXYLATE Methyl 2-nitro-4-(trifluoromethyl)benzoate METHYL 4-FLUORO-2-HYDROXYBENZOATE 3-HYDROXY-PYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Methyl 4-(4,4,4-trifluorobutanoyl)benzoate METHYL 3-AMINO-2,6-DIFLUOROBENZOATE Methyl 3-formyl-2-nitrobenzoate

METHYL 2,6-DIFLUORO-3-NITROBENZOATE

Benzoic acid,2,6-difluoro-3-nitro-, methyl ester (Related Reference)

Benzoic acid, 2,6-difluoro-3-nitro-, methyl ester

84832-01-9