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Diallyldimethylammonium chloride

Product Name
Diallyldimethylammonium chloride
CAS No.
7398-69-8
Chemical Name
Diallyldimethylammonium chloride
Synonyms
DADMAC;diallyldimethylammonium chloride solution;dadmac 65%;Dimethyldiallylaminium·chloride;DIMETHYLDIALLYLAMMONIUM CHLORIDE;N,N-Diallyl-N,N-dimethylammonium chloride;Nsc59284;oride soL;Elionfix G conc;(CH2=CHCH2)2N(Cl)(CH3)2
CBNumber
CB3101991
Molecular Formula
C8H16ClN
Formula Weight
161.67
MOL File
7398-69-8.mol
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Diallyldimethylammonium chloride Property

Melting point:
140-148 °C
Boiling point:
118℃ at 101.325kPa
Density 
1.03-1.05g/cm3 at 25℃
refractive index 
n20/D 1.460
storage temp. 
Sealed in dry,Room Temperature
solubility 
Methanol (Slightly), Water
form 
Oil
color 
Colourless
BRN 
5830817
InChI
InChI=1S/C8H16N.ClH/c1-5-7-9(3,4)8-6-2;/h5-6H,1-2,7-8H2,3-4H3;1H/q+1;/p-1
InChIKey
GQOKIYDTHHZSCJ-UHFFFAOYSA-M
SMILES
[N+](C)(C)(CC=C)CC=C.[Cl-]
LogP
-2.49 at 20℃ and pH7
CAS DataBase Reference
7398-69-8(CAS DataBase Reference)
EPA Substance Registry System
Dimethyldiallylammonium chloride (7398-69-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-24/25
WGK Germany 
1
RTECS 
UC6660000
3-10
HS Code 
29239000
Hazardous Substances Data
7398-69-8(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
348279
Product name
Diallyldimethylammonium chloride solution
Purity
65wt. % in H
Packaging
1l
Price
$152
Updated
2025/07/31
Sigma-Aldrich
Product number
32598
Product name
Diallyldimethylammonium chloride
Purity
≥97.0% (AT)
Packaging
10g
Price
$225
Updated
2025/07/31
TCI Chemical
Product number
D2003
Product name
Diallyldimethylammonium Chloride (60% in Water)
Packaging
25mL
Price
$25
Updated
2025/07/31
TCI Chemical
Product number
D2003
Product name
Diallyldimethylammonium Chloride (60% in Water)
Packaging
500mL
Price
$55
Updated
2025/07/31
Sigma-Aldrich
Product number
348279
Product name
Diallyldimethylammonium chloride solution
Purity
65wt. % in H
Packaging
3l
Price
$298.35
Updated
2025/07/31
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Diallyldimethylammonium chloride Chemical Properties,Usage,Production

Description

Diallyldimethylammonium chloride solution (DADMAC) is a hydrophilic quaternary ammonium compound that can be dissolved in an aqueous solution as a positively charged colloid.

Chemical Properties

Colorless to Light yellow to Light orange clear liquid.
Diallyldimethylammonium chloride (DADMAC) and Polydiallyldimethylammonium chloride (polyDADMAC) are contaminants that may be present in potential drinking water sources.
PolyDADMAC is a polymer manufactured from DADMAC. PolyDADMAC is often used to help remove suspended particulates from water. DADMAC has no direct uses, but may be present when polyDADMAC is used.
PolyDADMAC is used in:
Wastewater treatment
Paper making
Textile printing
Silica sand mining

Uses

DADMAC is used as a cationic monomer solution for the fabrication of ion-selective polyelectrolytic anodized aluminium oxide (AAO) membranes which can be used for the development of electrical power generation systems. It may be grafted on carboxymethyl cellulose (CMC) for use as an absorbent for cationic dyes.

Uses

Diallyldimethylammonium chloride (DADMAC) is a viscous, colourless to pale yellow liquid with slight odour. mainly used as cationic monomer in resins production. DADMAC is a quaternary ammonium salt with high density charge and can be dissolved in water very easily. It is non-flammable, non-explosive and stable at room temperature. The polymers occurring by DADMAC reaction is also known as poly-DADMAC and finds its application in a wide range of industrial application.

Application

Diallyldimethylammonium chloride (DADMAC) is a polymer monomer belonging to the quaternary ammonium compounds. The structure of DADMAC is strongly charged and has good water solubility. Therefore, DADMAC and PolyDADMAC are widely used in the field of water treatment as flocculants and flocculation aids, which can effectively flocculate and remove suspended solids, algae, organic matter and other substances. In addition, it can be used as an antimicrobial agent, surfactant or binder in various industrial applications, commonly found in paper, textiles and personal care products.

Synthesis

124-40-3

107-05-1

7398-69-8

1. 150 parts of a 33% solution of dimethylamine are added to the reactor, heated and stirred until foaming starts at 30°C. Subsequently, 43 parts of 33% dimethylamine solution were added from the receiving tank and the temperature was controlled at 7°C. 2. Two parts of 50% sodium hydroxide solution were added, stirred and heated to 85°C to promote evaporation of the dimethylamine. Continue heating to 100 °C to end this step. An incomplete product of 83.4 parts with 2.2% dimethylamine content was obtained; and 103 parts of dimethylamine solution (including the absorbent) with 56.4% dimethylamine content. 3. In a three-necked flask equipped with a stirrer, a thermometer, a condenser tube and a titration funnel, 100 parts of a 56.4% solution of dimethylamine were added and 30% allyl chloride was slowly added at 0 °C. 4. 180 parts of allyl chloride and 100 parts of 50% sodium hydroxide solution were added dropwise simultaneously at 3°C to 5°C to control the pH between 9.5 and 10.5. 5. After completion of the addition, the temperature was raised to 44°C for refluxing until the pH of the reaction dropped to 6.4, the heating was stopped and cooling was carried out. 6. The reaction mixture was filtered to obtain 64.8 parts of NaCl and 325.3 parts of an aqueous solution of dimethyldiallylammonium chloride. The content of dimethyldiallylammonium chloride was determined to be 60.8% and the yield was 97.65% (based on amine calculations).

References

[1] Patent: CN104557569, 2016, B. Location in patent: Paragraph 0031; 0032; 0033
[2] Patent: CN108329217, 2018, A. Location in patent: Paragraph 0020-0021; 0025-0026; 0030-0031
[3] Russian Chemical Bulletin, 2007, vol. 56, # 3, p. 535 - 539
[4] Patent: CN104370754, 2016, B. Location in patent: Paragraph 0025; 0026

Diallyldimethylammonium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Diallyldimethylammonium chloride Suppliers

Wuhan Jushun Chemical Co., Ltd
Tel
027-83238443 13349917800
Email
3629602341@qq.com
Country
China
ProdList
4948
Advantage
58
Minglong (Xianning) Pharmaceutical Co., LTD
Tel
186-7296-9259 18771307593
Email
3919539926@qq.com
Country
China
ProdList
4258
Advantage
58
Zhejiang Xinhaitian Bio-Technology Co., Ltd.
Tel
008615925805416
Email
elainexu_zjxht@163.com
Country
China
ProdList
22
Advantage
58
Tianjin Zhongxin Chemtech Co., Ltd.
Tel
022-66880623
Fax
86(0)22-66880086
Email
sales@tjzxchem.com
Country
China
ProdList
613
Advantage
60
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9400
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-010-82967028 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12000
Advantage
60
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View Lastest Price from Diallyldimethylammonium chloride manufacturers

HANGZHOU HAILAN CHEMICAL CO.,LTD.
Product
Diallyldimethylammonium chloride 7398-69-8
Price
US $0.00/kg
Min. Order
1kg
Purity
99%min
Supply Ability
20tons
Release date
2025-09-04
Shaanxi Didu New Materials Co. Ltd
Product
Diallyldimethylammonium chloride 7398-69-8
Price
US $1.50/g
Min. Order
1g
Purity
99.0% Min
Supply Ability
10 Tons
Release date
2025-06-24
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Diallyldimethylammonium chloride 7398-69-8
Price
US $0.00/KG
Min. Order
200KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-02

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