4-AMINO-3-BROMO-5-NITROPYRIDINE

Product Name: 4-AMINO-3-BROMO-5-NITROPYRIDINE
CAS No.: 89284-05-9
Chemical Name: 4-AMINO-3-BROMO-5-NITROPYRIDINE
Synonyms: 4-AMino-3-broMo-5-nitropy...;3-bromo-5-nitro-4-pyridinamine;4-AMino-3-nitro-5-broMopyridine;4-AMINO-3-BROMO-5-NITROPYRIDINE;3-Bromo-4-amino-5-nitropyridine;4-Pyridinamine, 3-bromo-5-nitro-;4-Amino-3-bromo-5-nitropyridine 97%;4-AMINO-3-BROMO-5-NITROPYRIDINE ISO 9001：2015 REACH
CBNumber: CB31076135
Molecular Formula: C5H4BrN3O2
Formula Weight: 218.01
MOL File: 89284-05-9.mol

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4-AMINO-3-BROMO-5-NITROPYRIDINE Property

Melting point:: 174-175℃
Boiling point:: 346.5±37.0 °C(Predicted)
Density: 1.929
refractive index: 1.682
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: claggy powder
pka: 2.87±0.24(Predicted)
color: Amber/gold
InChI: InChI=1S/C5H4BrN3O2/c6-3-1-8-2-4(5(3)7)9(10)11/h1-2H,(H2,7,8)
InChIKey: UXDLBXRMNSJEPB-UHFFFAOYSA-N
SMILES: C1=NC=C([N+]([O-])=O)C(N)=C1Br

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Safety

HS Code: 2933399990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC

Product number: A602458
Product name: 4-Amino-3-bromo-5-nitropyridine
Packaging: 1g
Price: $75
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H55-9-02
Product name: 4-Amino-3-bromo-5-nitropyridine
Packaging: 1g
Price: $75
Updated: 2021/12/16

AK Scientific

Product number: W9221
Product name: 3-Bromo-5-nitropyridin-4-amine
Packaging: 5g
Price: $78
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139502
Product name: 3-Bromo-5-nitropyridin-4-amine
Packaging: 5G
Price: $110
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0037552
Product name: 4-AMINO-3-BROMO-5-NITROPYRIDINE
Purity: 95.00%
Packaging: 50MG
Price: $117.6
Updated: 2021/12/16

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4-AMINO-3-BROMO-5-NITROPYRIDINE Chemical Properties,Usage,Production

Synthesis

1681-37-4

89284-05-9

The general procedure for the synthesis of 4-amino-3-bromo-5-nitropyridine from 4-amino-3-nitropyridine was as follows: 3-nitropyridin-4-amine (LXVIII) (10 g, 71.88 mmol) was mixed with acetic acid (100 ml) in a sealed tube, followed by the addition of sodium acetate (NaOAc) (29.50 g, 359 mmol), and the slow dropwise addition of bromine ( 4.43 ml, 86.3 mmol). The sealed tube was heated at 100 °C for overnight reaction under stirring conditions. Upon completion of the reaction, the mixture was concentrated under vacuum and the resulting solid was dissolved in water, alkalized with saturated aqueous sodium bicarbonate (NaHCO3) and extracted with dichloromethane (DCM). The organic phases were combined, dried and concentrated to give 3-bromo-5-nitropyridin-4-amine (LXIX) as a yellow solid (13.7 g, 62.8 mmol, 87% yield). The product was identified by 1H NMR (DMSO-d6, 500 MHz): δ 8.58 (s, 1H), 9.19 (s, 1H); ESIMS analysis showed the molecular ion peak m/z 218.1 (M + H), corresponding to the molecular formula C5H4BrN3O2.

References

[1] Patent: US2013/296302, 2013, A1. Location in patent: Paragraph 0563
[2] Patent: WO2011/84486, 2011, A1. Location in patent: Page/Page column 119-120
[3] Patent: US2013/267495, 2013, A1. Location in patent: Paragraph 0460-0461
[4] Patent: EP2464232, 2015, B1. Location in patent: Paragraph 0087; 0088
[5] Patent: US2016/68548, 2016, A1. Location in patent: Paragraph 0852

4-AMINO-3-BROMO-5-NITROPYRIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-AMINO-3-BROMO-5-NITROPYRIDINE Suppliers

China 112 Germany 1 India 1 United Kingdom 2 United States 9 Global 125

Alichem(Changzhou) Co., Ltd.

Tel: 19941333411
Fax: QQ:749741756
Email: sales@alichem.cn
Country: China
ProdList: 523
Advantage: 58

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Country: China
ProdList: 18207
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JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
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Nan Jing Dirise Chemcial Co.,LTD

Tel: 025-52161033 15312098939
Fax: 025-83254025
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Country: China
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Jinan Trio PharmaTech Co., Ltd.

Tel: 0531-88811783
Fax: +86 (531) 55696010 QQ 1762738062
Email: sales@trio-pharmatech.com
Country: China
ProdList: 1856
Advantage: 62

PSN Pharmaceutical Technology Co., Ltd.

Tel: 86-25-57062118
Fax: 86-25-57065896
Email: sales@jspsn.com
Country: China
ProdList: 496
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China Langchem Inc.

Tel: 0086-21-58956006
Fax: 0086-21-58956100
Country: China
ProdList: 7811
Advantage: 57

Wuhan Arike Technology Co., Ltd.

Tel: 027- 51832457 94518350
Fax: E-Mail Inquiry
Country: China
ProdList: 746
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View Lastest Price from 4-AMINO-3-BROMO-5-NITROPYRIDINE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 4-Amino-3-bromo-5-nitropyridine 89284-05-9
Price: US $1.00-1.00/Kg/Drum
Min. Order: 1g
Purity: 98%
Supply Ability: 50tons
Release date: 2020-05-12

Dideu Industries Group Limited

Product: 4-AMINO-3-BROMO-5-NITROPYRIDINE 89284-05-9
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons min
Release date: 2021-09-08

Career Henan Chemical Co

Product: 4-AMINO-3-BROMO-5-NITROPYRIDINE 89284-05-9
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 1000KGS
Release date: 2019-12-20

89284-05-9, 4-AMINO-3-BROMO-5-NITROPYRIDINERelated Search:

4-Amino-3-methylbenzonitrile 4-AMINO-5-IODO-3-PICOLINE 2-AMINO-5-BROMO-3-NITROPYRIDINE 2-AMINO-3-BROMO-5-NITROPYRIDINE,2-Amino-3-bromo-5-nitropyridine 98% 3-AMINO-5-BROMO-2-NITROPYRIDINE 3-BROMO-5-NITROPYRIDINE 4-AMINO-3-BROMO-5-NITROPYRIDINE 4-AMINO-2-BROMO-3-NITROPYRIDINE 3-bromo-N-ethyl-5-nitropyridin-4-amine 2-Amino-6-bromo-3-nitropyridine 6-AMINO-5-BROMO-3-NITROPYRIDINE-2-CARBOXAMIDE N-benzyl-3-bromo-5-nitropyridin-4-amine 3-bromo-5-nitro-N-(2-pyrrolidin-1-ylethyl)pyridin-4-amine 3-bromo-N-methyl-5-nitropyridin-4-amine 3-bromo-5-nitro-N-(pyridin-2-ylmethyl)pyridin-4-amine 3-bromo-N-(1-methylethyl)-5-nitropyridin-4-amine 3-bromo-N-cyclopropyl-5-nitropyridin-4-amine N'-(3-bromo-5-nitropyridin-4-yl)-N,N-dimethylethane-1,2-diamine

4-AMINO-3-BROMO-5-NITROPYRIDINE

4-AMino-3-nitro-5-broMopyridine

4-AMino-3-broMo-5-nitropy...

4-Amino-3-bromo-5-nitropyridine 97%

3-bromo-5-nitro-4-pyridinamine

3-Bromo-4-amino-5-nitropyridine

4-Pyridinamine, 3-bromo-5-nitro-

4-AMINO-3-BROMO-5-NITROPYRIDINE ISO 9001：2015 REACH

89284-05-9

Pyridine