ChemicalBook > CAS DataBase List > 4-Nitrophenylboronic acid

4-Nitrophenylboronic acid

Product Name
4-Nitrophenylboronic acid
CAS No.
24067-17-2
Chemical Name
4-Nitrophenylboronic acid
Synonyms
RARECHEM AH PB 0141;4-Borononitrobenzene;4-nitrophenylboric acid;P-NITROPHENYLBORONIC ACID;4-NITROPHENYLBORONIC ACID;(4-Nitrophenyl)boronicaci;4-NITROBENZENEBORONIC ACID;p-nitro-benzeneboronic acid;B-(4-nitrophenyl)boronic acid;4-Nitrophenylboronic acid ,97%
CBNumber
CB3116883
Molecular Formula
C6H6BNO4
Formula Weight
166.93
MOL File
24067-17-2.mol
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4-Nitrophenylboronic acid Property

Melting point:
285-290°C (dec.)
Boiling point:
373.7±44.0 °C(Predicted)
Density 
1.40±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMF: 15 mg/ml; DMSO: 15 mg/ml; Ethanol: 15 mg/ml; Ethanol:PBS (pH 7.2) (1:5): 0.16 mg/ml
pka
7.04±0.10(Predicted)
form 
Crystalline Powder
color 
White to yellow
Water Solubility 
Slightly soluble in water.
InChIKey
NSFJAFZHYOAMHL-UHFFFAOYSA-N
CAS DataBase Reference
24067-17-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
26-36/37/39-24/25
WGK Germany 
3
Hazard Note 
Harmful
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
673854
Product name
4-Nitrophenylboronic acid
Purity
≥95.0%
Packaging
1g
Price
$83.1
Updated
2024/03/01
Sigma-Aldrich
Product number
673854
Product name
4-Nitrophenylboronic acid
Purity
≥95.0%
Packaging
5g
Price
$191
Updated
2024/03/01
TCI Chemical
Product number
N0812
Product name
4-Nitrophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$28
Updated
2024/03/01
TCI Chemical
Product number
N0812
Product name
4-Nitrophenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$110
Updated
2024/03/01
Alfa Aesar
Product number
H27767
Product name
4-Nitrobenzeneboronic acid, 95%
Packaging
1g
Price
$63.65
Updated
2024/03/01
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4-Nitrophenylboronic acid Chemical Properties,Usage,Production

Description

4-Nitrobenzeneboronic acid is an arylboronic acid building block that has been used in the synthesis of phenols.

Chemical Properties

White to brown powder or crystal

Uses

4-Nitrophenylboronic Acid is a useful synthetic intermediate. It is a reagent used for ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings, Ruthenium catalyzed direct arylation of benzylic sp3 carbons of acyclic amines and Diels-Alder or C-H activation reactions.

Uses

Reagent used for

  • Ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings
  • Ruthenium catalyzed direct arylation of benzylic sp3 carbons of acyclic amines
  • Diels-Alder or C-H activation reactions
  • Regioselective Suzuki-Miyaura coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulations
  • N-arylation of phenylurea using copper acetylacetonate catalyst
  • Environmentally benign one-pot synthesis through a double arylation process
  • Copper-mediated cyanations
  • copper-catalyzed arylations
  • Regioselective glycosylations
  • Suzuki couplings followed by arylations
  • X-ray absorption on rhodium-grafted hydrotalcite catalyst for heterogeneous 1,4-addition reaction of organoboron reagents to electron deficient olefins

Reagent used in Preparation of
  • Combretastatin analogs as potential antitumor agents
  • Human immunodeficiency virus (HIV) protease inhibitors with antiviral activities against drug-resistant viruses

Uses

suzuki reaction

4-Nitrophenylboronic acid Preparation Products And Raw materials

Raw materials

1-Bromo-4-nitrobenzene [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Cuprous iodide Toluene Bis(pinacolato)diboron Tetrahydrofuran Hydrochloric acid Triisopropyl borate Sodium periodate Potassium Acetate n-Butyllithium

Preparation Products

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4-Nitrophenylboronic acid Suppliers

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HBCChem, Inc.
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View Lastest Price from 4-Nitrophenylboronic acid manufacturers

Henan Fengda Chemical Co., Ltd
Product
4-Nitrophenylboronic acid 24067-17-2
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Hebei Xinsheng New Material Technology Co., LTD.
Product
4-Nitrophenylboronic acid 24067-17-2
Price
US $35.00-25.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 Ton
Release date
2023-10-31
Hebei Xinsheng New Material Technology Co., LTD.
Product
4-Nitrophenylboronic acid 24067-17-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
30000 Kg
Release date
2023-12-01

24067-17-2, 4-Nitrophenylboronic acidRelated Search:

Zinc borate Phenylboronic acid 3-(CYCLOHEXYLCARBAMOYL)-5-NITROPHENYLBORONIC ACID 3-(N,N-DIETHYLAMINOCARBONYL)-5-NITROPHENYLBORONIC ACID 3-NITROPHENYLBORONIC ACID,M-NITROPHENYLBORONIC ACID 3-NITROPHENYLBORONIC ACID, PINACOL ESTER 4-METHOXY-3-NITROPHENYLBORONIC ACID, PINACOL ESTER 4-METHOXY-3-NITROPHENYLBORONIC ACID Nitromethane 4-NITROPHENYLBORONIC ACID PINACOL ESTER Phenylacetone 2,4,6-Trinitrotoluene Nitrobenzene 4-Methoxy-2-nitrophenylboronic acid 3-(MORPHOLINE-4-CARBONYL)-5-NITROPHENYLBORONIC ACID 4-TERT-BUTYL-3-NITROPHENYLBORONIC ACID 4-Ethoxycarbonyl-2-nitrophenylboronic acid 4-AMINO-3-NITROPHENYLBORONIC ACID

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  • Boronic Acids
  • Organometallic Reagents
  • Boronate Ester
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  • B (Classes of Boron Compounds)
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