ChemicalBook > CAS DataBase List > 1-Phenylcyclobutanecarboxylic acid

1-Phenylcyclobutanecarboxylic acid

Product Name
1-Phenylcyclobutanecarboxylic acid
CAS No.
37828-19-6
Chemical Name
1-Phenylcyclobutanecarboxylic acid
Synonyms
1-Phenylcyclobutanecarboxylic acid;Phenylcyclobutane-1-carboxylic acid;Cyclobutanecarboxylic acid, 1-phenyl-;2-phenyl-1-cyclobutanecarboxylic acid
CBNumber
CB31263487
Molecular Formula
C11H12O2
Formula Weight
176.21
MOL File
37828-19-6.mol
More
Less

1-Phenylcyclobutanecarboxylic acid Property

Melting point:
100-102℃
Boiling point:
323.9±21.0 °C(Predicted)
Density 
1.208±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
powder
pka
4.39±0.20(Predicted)
color 
White
More
Less

Safety

HS Code 
2916200090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

TRC
Product number
P336618
Product name
1-PhenylcyclobutanecarboxylicAcid
Packaging
100mg
Price
$60
Updated
2021/12/16
AK Scientific
Product number
J55188
Product name
1-Phenylcyclobutanecarboxylicacid
Packaging
1g
Price
$85
Updated
2021/12/16
Apolloscientific
Product number
OR2270
Product name
1-Phenylcyclobutane-1-carboxylicacid
Packaging
1g
Price
$92
Updated
2021/12/16
SynQuest Laboratories
Product number
2721-1-W3
Product name
Phenylcyclobutane-1-carboxylic acid
Packaging
1g
Price
$101
Updated
2021/12/16
Matrix Scientific
Product number
082053
Product name
1-Phenylcyclobutanecarboxylic acid
Purity
97%
Packaging
1g
Price
$230
Updated
2021/12/16
More
Less

1-Phenylcyclobutanecarboxylic acid Chemical Properties,Usage,Production

Synthesis

14377-68-5

37828-19-6

Part A. 1-Phenyl-1-cyclobutanecarbonitrile (5.0 g, 31.83 mmol) and potassium hydroxide (85%, 6.29 g, 95.49 mmol, 3 eq.) were dissolved in ethylene glycol (10 mL) and the reaction was heated for 6 h at 185-190 °C under nitrogen protection. The completion of the reaction was monitored by LC-MS. The reaction mixture was cooled and diluted with the addition of water. The mixture was extracted with ether (3 x 10 mL). The aqueous layer was acidified with concentrated hydrochloric acid to pH < 2 and subsequently extracted with chloroform (2 x 10 mL). The chloroform layers were combined, washed sequentially with water and saturated saline, dried over anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to give 1-phenyl-1-cyclobutanecarboxylic acid (4.43 g, yield 79.2%). lC-MS (ESI+) m/z: 177.4 [M+H]+, retention time tR = 2.56 min (mobile phase: 10-90% acetonitrile/water, run time 6 min) .

References

[1] Chemische Berichte, 1984, vol. 117, # 11, p. 3303 - 3319
[2] Journal of Medicinal Chemistry, 2015, vol. 58, # 18, p. 7341 - 7348
[3] Patent: WO2003/99276, 2003, A1. Location in patent: Page 316-317
[4] Journal of Organometallic Chemistry, 1993, vol. 448, # 1-2, p. 9 - 14
[5] Pharmaceutical Chemistry Journal, 1980, vol. 14, # 2, p. 114 - 118

1-Phenylcyclobutanecarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

1-Phenylcyclobutanecarboxylic acid Suppliers

A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
More
Less

View Lastest Price from 1-Phenylcyclobutanecarboxylic acid manufacturers

Career Henan Chemical Co
Product
1-Phenylcyclobutanecarboxylic acid 37828-19-6
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-25

37828-19-6, 1-Phenylcyclobutanecarboxylic acidRelated Search:


  • Phenylcyclobutane-1-carboxylic acid
  • 1-Phenylcyclobutanecarboxylic acid
  • 2-phenyl-1-cyclobutanecarboxylic acid
  • Cyclobutanecarboxylic acid, 1-phenyl-
  • 37828-19-6
  • Carboxylic Acids
  • Phenyls & Phenyl-Het
  • API intermediates
  • Acids and Derivatives