(S)-2-(Aminomethyl)-1-Cbz-pyrrolidine

Product Name: (S)-2-(Aminomethyl)-1-Cbz-pyrrolidine
CAS No.: 119020-03-0
Chemical Name: (S)-2-(Aminomethyl)-1-Cbz-pyrrolidine
Synonyms: BUTTPARK 93\50-51;N-CBZ-4-AMINOMETHYLPIPERIDINE;1-CBZ-2-AMINOMETHYL PYRROLIDINE;4-AMINOMETHYL-1-N-CBZ-PIPERIDINE;2-(Aminomethyl)-1-Cbz-pyrrolidine;(S)-1-CBZ-2-AMINOMETHYLPYRROLIDINE;1-N-CBZ-2-(AMINOMETHYL)PYRROLIDINE;(S)-2-(Aminomethyl)-1-Cbz-pyrrolidine;(S)-2-AMINOMETHYL-1-N-CBZ-PYRROLIDINE;(S)-1-N-CBZ-2-(AMINOMETHYL)PYRROLIDINE
CBNumber: CB3151325
Molecular Formula: C13H18N2O2
Formula Weight: 234.29
MOL File: 119020-03-0.mol

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(S)-2-(Aminomethyl)-1-Cbz-pyrrolidine Property

Boiling point:: 370.5±25.0 °C(Predicted)
Density: 1.155±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Inert atmosphere,2-8°C
pka: 9.91±0.29(Predicted)
Appearance: Colorless to light yellow Liquid
CAS DataBase Reference: 119020-03-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-41-37/38-22
Safety Statements: 26-36/37/39-39

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: A635033
Product name: 2-Aminomethyl-pyrrolidine-1-carboxylicAcidBenzylEster
Packaging: 100mg
Price: $65
Updated: 2021/12/16

TRC

Product number: A635033
Product name: 2-Aminomethyl-pyrrolidine-1-carboxylicAcidBenzylEster
Packaging: 500mg
Price: $220
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA56379
Product name: 2-Aminomethyl-pyrrolidine-1-carboxylic acid benzyl ester
Packaging: 1g
Price: $230
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA56379
Product name: 2-Aminomethyl-pyrrolidine-1-carboxylic acid benzyl ester
Packaging: 2g
Price: $368
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FA56379
Product name: 2-Aminomethyl-pyrrolidine-1-carboxylic acid benzyl ester
Packaging: 5G
Price: $588.8
Updated: 2021/12/16

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(S)-2-(Aminomethyl)-1-Cbz-pyrrolidine Chemical Properties,Usage,Production

Uses

(S)-Benzyl 2-(aminomethyl)pyrrolidine-1-carboxylate was a useful reagent in preparation of trifluoro-N-[(S)-pyrrolidinylmethyl]methanesulfonamide.

Synthesis

141774-67-6

119020-03-0

GENERAL METHOD: Under stirring conditions, azide derivatives 9a or 9b (4.03 mmol) were dissolved in THF (1 mL), followed by the addition of solid triphenylphosphine (Ph3P, 4.03 mmol) and water (H2O, 6.04 mmol). The reaction mixture was stirred continuously for 12 h at room temperature. After completion of the reaction, the solvent was removed by concentration under reduced pressure. The crude product was purified by rapid column chromatography on silica gel with the eluent being a solvent mixture of methanol-dichloromethane (9:1, v/v).

References

[1] Synthetic Communications, 2011, vol. 41, # 17, p. 2517 - 2523
[2] Synthesis (Germany), 2013, vol. 45, # 17, p. 2458 - 2468
[3] Tetrahedron Letters, 2010, vol. 51, # 1, p. 209 - 212
[4] Tetrahedron Letters, 1991, vol. 32, # 49, p. 7183 - 7186

(S)-2-(Aminomethyl)-1-Cbz-pyrrolidine Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-2-(Aminomethyl)-1-Cbz-pyrrolidine Suppliers

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View Lastest Price from (S)-2-(Aminomethyl)-1-Cbz-pyrrolidine manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: (S)-1-Cbz-2-aminomethylpyrrolidine 119020-03-0
Price: US $1.10-9.90/kg
Min. Order: 1kg
Purity: 99%min
Supply Ability: 100kg
Release date: 2025-08-18

Career Henan Chemical Co

Product: (S)-2-(Aminomethyl)-1-Cbz-pyrrolidine 119020-03-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-12-24

119020-03-0, (S)-2-(Aminomethyl)-1-Cbz-pyrrolidineRelated Search:

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(S)-1-N-CBZ-2-(AMINOMETHYL)PYRROLIDINE

(S)-2-AMINOMETHYL-PYRROLIDINE-1-CARBOXYLIC ACID BENZYL ESTER

(S)-2-(Aminomethyl)-1-Cbz-pyrrolidine

(S)-2-AMINOMETHYL-1-N-CBZ-PYRROLIDINE

(S)-BENZYL-2-(AMINOMETHYL)PYRROLIDINE-1-CARBOXYLATE

N-CBZ-4-AMINOMETHYLPIPERIDINE

2-(Aminomethyl)-1-Cbz-pyrrolidine

119020-03-0

119020-30-0

11902-03-0

Pyrrole&Pyrrolidine&Pyrroline