Benzyl formate
- Product Name
- Benzyl formate
- CAS No.
- 104-57-4
- Chemical Name
- Benzyl formate
- Synonyms
- Benzyl alcohol, formate;jiasuanbianzhi;BENZYL METHANOATE;NSC 8049;FEMA 2145;Benzylformiat;BENZYL FORMATE;N-BENZYL FORMATE;BenzylFormate>Benzyl methanoater
- CBNumber
- CB7737035
- Molecular Formula
- C8H8O2
- Formula Weight
- 136.15
- MOL File
- 104-57-4.mol
Benzyl formate Property
- Melting point:
- 3.6℃
- Boiling point:
- 203 °C(lit.)
- Density
- 1.088 g/mL at 25 °C(lit.)
- vapor pressure
- 1.69hPa at 20℃
- refractive index
- n20/D 1.511(lit.)
- FEMA
- 2145 | BENZYL FORMATE
- Flash point:
- 180 °F
- storage temp.
- Inert atmosphere,Room Temperature
- form
- clear liquid
- color
- Colorless liquid
- Specific Gravity
- 1.091 (20/4℃)
- Odor
- powerful fruity, spicy odor
- Odor Type
- floral
- Water Solubility
- Insoluble in water, soluble in organic solvents, oils.
- Merck
- 14,1134
- JECFA Number
- 841
- BRN
- 2041319
- LogP
- 1.79 at 21.9℃
- CAS DataBase Reference
- 104-57-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Formic acid, phenylmethyl ester(104-57-4)
- EPA Substance Registry System
- Formic acid, phenylmethyl ester (104-57-4)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 21/22
- Safety Statements
- 36-36/37-23
- RIDADR
- NA 1993 / PGIII
- WGK Germany
- 1
- RTECS
- LQ5400000
- TSCA
- Yes
- HS Code
- 29151300
- Toxicity
- LD50 orl-rat: 1400 mg/kg FCTXAV 11,1019,73
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
N-Bromosuccinimide Price
- Product number
- W214507
- Product name
- Benzyl formate
- Purity
- ≥95%, FCC, FG
- Packaging
- sample-k
- Price
- $54.6
- Updated
- 2024/03/01
- Product number
- W214507
- Product name
- Benzyl formate
- Purity
- ≥95%, FCC, FG
- Packaging
- 1kg
- Price
- $80.9
- Updated
- 2024/03/01
- Product number
- W214507
- Product name
- Benzyl formate
- Purity
- ≥95%, FCC, FG
- Packaging
- 5kg
- Price
- $229
- Updated
- 2024/03/01
- Product number
- W214507
- Product name
- Benzyl formate
- Purity
- ≥95%, FCC, FG
- Packaging
- 10Kg
- Price
- $320
- Updated
- 2024/03/01
- Product number
- W214520
- Product name
- Benzyl formate
- Purity
- natural, 97%, FG
- Packaging
- 100g
- Price
- $154
- Updated
- 2023/01/07
Benzyl formate Chemical Properties,Usage,Production
Chemical Properties
Benzyl formate has an intense, pleasant, floral-fruity odor and sweet taste reminiscent of apricot and pineapple.
Chemical Properties
Colorless liquid; fruity-spicy odor. Resembles benzyl acetate in many respects but differs in its greater volatility. Miscible with alcohols, ketones, oils, aromatic, aliphatic and halogenated hydrocarbons; insoluble in water.
Occurrence
Reported found in the oil of Rosa rugosa, sour cherry, American cranberry, ligonberry, coffee, black tea, Agaricus mushroom, Ocimum basilicum, Bourbon vanilla and crowberry (Empetrum nigrum Coll.).
Uses
Solvent for cellulose esters; in perfumery.
Preparation
By heating a mixture of formic/acetic anhydride and benzyl alcohol to 50°C; by passing a mixture of formic acid and excess benzyl alcohol over a catalyst (ThO2 or TiO2) at high temperature.
Definition
ChEBI: Benzylformate is a carboxylic ester. It is functionally related to a benzyl alcohol.
Taste threshold values
Taste characteristics at 10 ppm: fresh cherry with a berry, strawberry fruity nuance.
Synthesis Reference(s)
Journal of the American Chemical Society, 82, p. 2380, 1960 DOI: 10.1021/ja01494a065
The Journal of Organic Chemistry, 55, p. 2952, 1990 DOI: 10.1021/jo00296a072
Hazard
May be narcotic in high concentration.
Safety Profile
Moderately toxic by ingestion andskin contact. Mutation data reported. Probably narcotic inhigh concentrations. When heated todecomposition it emits acrid, irritating fumes.
Benzyl formate Preparation Products And Raw materials
Raw materials
Preparation Products
Benzyl formate Suppliers
- Tel
- 010-82848833 400-666-7788
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 4006608290; 18621169109
- Fax
- 86-21-61259102
- market03@meryer.com
- Country
- China
- ProdList
- 40241
- Advantage
- 62
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30132
- Advantage
- 84
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24539
- Advantage
- 81
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44751
- Advantage
- 61
- Tel
- 021-58099652-8005 13585536065
- Fax
- 021-58099609
- bin.wu@shlschem.com
- Country
- China
- ProdList
- 9816
- Advantage
- 59
- Tel
- 021-54306202 13764082696;
- info@hanhongsci.com
- Country
- China
- ProdList
- 42982
- Advantage
- 64
- Tel
- 21-62165282 15801962796;
- Fax
- 021 61153784
- bidingchem@163.com
- Country
- China
- ProdList
- 1165
- Advantage
- 60
- Tel
- 13355009207 13355009207
- Fax
- 0539-6365991
- 3007715519@qq.com
- Country
- China
- ProdList
- 18739
- Advantage
- 57
- Tel
- Fax
- E-Mail Inquiry
- info@syntechem.com
- Country
- China
- ProdList
- 12990
- Advantage
- 57
View Lastest Price from Benzyl formate manufacturers
- Product
- Benzyl formate 104-57-4
- Price
- US $1.00/mL
- Min. Order
- 1mL
- Purity
- 99%
- Supply Ability
- 50000tons
- Release date
- 2023-05-22
- Product
- Benzyl formate 104-57-4
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 95%
- Supply Ability
- 10000kg
- Release date
- 2023-01-14
- Product
- Benzyl formate 104-57-4
- Price
- US $150.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000tons
- Release date
- 2023-08-09