Benzyl formate

ChemicalBook > CAS DataBase List > Benzyl formate

Product Name: Benzyl formate
CAS No.: 104-57-4
Chemical Name: Benzyl formate
Synonyms: Benzyl alcohol, formate;jiasuanbianzhi;BENZYL METHANOATE;NSC 8049;FEMA 2145;Benzylformiat;BENZYL FORMATE;N-BENZYL FORMATE;BenzylFormate>Benzyl methanoater
CBNumber: CB7737035
Molecular Formula: C8H8O2
Formula Weight: 136.15
MOL File: 104-57-4.mol

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Benzyl formate Property

Melting point:: 3.6℃
Boiling point:: 203 °C(lit.)
Density: 1.088 g/mL at 25 °C(lit.)
vapor pressure: 1.69hPa at 20℃
refractive index: n20/D 1.511(lit.)
FEMA: 2145 | BENZYL FORMATE
Flash point:: 180 °F
storage temp.: Inert atmosphere,Room Temperature
form: clear liquid
color: Colorless liquid
Specific Gravity: 1.091 (20/4℃)
Odor: powerful fruity, spicy odor
Odor Type: floral
Water Solubility: Insoluble in water, soluble in organic solvents, oils.
Merck: 14,1134
JECFA Number: 841
BRN: 2041319
LogP: 1.79 at 21.9℃
CAS DataBase Reference: 104-57-4(CAS DataBase Reference)
NIST Chemistry Reference: Formic acid, phenylmethyl ester(104-57-4)
EPA Substance Registry System: Formic acid, phenylmethyl ester (104-57-4)

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Safety

Hazard Codes: Xn
Risk Statements: 21/22
Safety Statements: 36-36/37-23
RIDADR: NA 1993 / PGIII
WGK Germany: 1
RTECS: LQ5400000
TSCA: Yes
HS Code: 29151300
Toxicity: LD50 orl-rat: 1400 mg/kg FCTXAV 11,1019,73

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W214507
Product name: Benzyl formate
Purity: ≥95%, FCC, FG
Packaging: sample-k
Price: $54.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214507
Product name: Benzyl formate
Purity: ≥95%, FCC, FG
Packaging: 1kg
Price: $80.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214507
Product name: Benzyl formate
Purity: ≥95%, FCC, FG
Packaging: 5kg
Price: $229
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214507
Product name: Benzyl formate
Purity: ≥95%, FCC, FG
Packaging: 10Kg
Price: $320
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214520
Product name: Benzyl formate
Purity: natural, 97%, FG
Packaging: 100g
Price: $154
Updated: 2023/01/07

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Benzyl formate Chemical Properties,Usage,Production

Chemical Properties

Benzyl formate has an intense, pleasant, floral-fruity odor and sweet taste reminiscent of apricot and pineapple.

Chemical Properties

Colorless liquid; fruity-spicy odor. Resembles benzyl acetate in many respects but differs in its greater volatility. Miscible with alcohols, ketones, oils, aromatic, aliphatic and halogenated hydrocarbons; insoluble in water.

Occurrence

Reported found in the oil of Rosa rugosa, sour cherry, American cranberry, ligonberry, coffee, black tea, Agaricus mushroom, Ocimum basilicum, Bourbon vanilla and crowberry (Empetrum nigrum Coll.).

Uses

Solvent for cellulose esters; in perfumery.

Preparation

By heating a mixture of formic/acetic anhydride and benzyl alcohol to 50°C; by passing a mixture of formic acid and excess benzyl alcohol over a catalyst (ThO2 or TiO2) at high temperature.

Definition

ChEBI: Benzylformate is a carboxylic ester. It is functionally related to a benzyl alcohol.

Taste threshold values

Taste characteristics at 10 ppm: fresh cherry with a berry, strawberry fruity nuance.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 2380, 1960 DOI: 10.1021/ja01494a065
The Journal of Organic Chemistry, 55, p. 2952, 1990 DOI: 10.1021/jo00296a072

Hazard

May be narcotic in high concentration.

Safety Profile

Moderately toxic by ingestion andskin contact. Mutation data reported. Probably narcotic inhigh concentrations. When heated todecomposition it emits acrid, irritating fumes.

Benzyl formate Preparation Products And Raw materials

Raw materials

Benzyl chloride Acetic anhydride Benzyl alcohol Formic acid (-)-MENTHYL CHLOROFORMATE Sodium formate

Preparation Products

(S)-2-(N，N-disubstitued aminomethy)indoline

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Benzyl formate Suppliers

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View Lastest Price from Benzyl formate manufacturers

Wuhan Boyuan Import & Export Co., LTD

Product: Benzyl formate 104-57-4
Price: US $1.00/mL
Min. Order: 1mL
Purity: 99%
Supply Ability: 50000tons
Release date: 2023-05-22

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Benzyl formate 104-57-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 95%
Supply Ability: 10000kg
Release date: 2023-01-14

Henan Bao Enluo International TradeCo.，LTD

Product: Benzyl formate 104-57-4
Price: US $150.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000tons
Release date: 2023-08-09

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