Benzyl formate

Product Name: Benzyl formate
CAS No.: 104-57-4
Chemical Name: Benzyl formate
Synonyms: Benzyl alcohol, formate;jiasuanbianzhi;BENZYL METHANOATE;NSC 8049;FEMA 2145;Benzylformiat;BENZYL FORMATE;N-BENZYL FORMATE;BenzylFormate>Benzyl methanoater
CBNumber: CB7737035
Molecular Formula: C8H8O2
Formula Weight: 136.15
MOL File: 104-57-4.mol

More

Less

Benzyl formate Property

Melting point:: 3.6℃
Boiling point:: 203 °C(lit.)
Density: 1.088 g/mL at 25 °C(lit.)
vapor pressure: 1.69hPa at 20℃
FEMA: 2145 | BENZYL FORMATE
refractive index: n20/D 1.511(lit.)
Flash point:: 180 °F
storage temp.: Inert atmosphere,Room Temperature
form: clear liquid
color: Colorless liquid
Specific Gravity: 1.091 (20/4℃)
Odor: powerful fruity, spicy odor
Odor Type: floral
Water Solubility: Insoluble in water, soluble in organic solvents, oils.
Merck: 14,1134
JECFA Number: 841
BRN: 2041319
LogP: 1.79 at 21.9℃
CAS DataBase Reference: 104-57-4(CAS DataBase Reference)
NIST Chemistry Reference: Formic acid, phenylmethyl ester(104-57-4)
EPA Substance Registry System: Formic acid, phenylmethyl ester (104-57-4)

More

Less

Safety

Hazard Codes: Xn
Risk Statements: 21/22
Safety Statements: 36-36/37-23
RIDADR: NA 1993 / PGIII
WGK Germany: 1
RTECS: LQ5400000
TSCA: Yes
HS Code: 29151300
Toxicity: LD50 orl-rat: 1400 mg/kg FCTXAV 11,1019,73

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W214507
Product name: Benzyl formate
Purity: ≥95%, FCC, FG
Packaging: sample-k
Price: $54.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214507
Product name: Benzyl formate
Purity: ≥95%, FCC, FG
Packaging: 1kg
Price: $80.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214507
Product name: Benzyl formate
Purity: ≥95%, FCC, FG
Packaging: 5kg
Price: $229
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214507
Product name: Benzyl formate
Purity: ≥95%, FCC, FG
Packaging: 10Kg
Price: $320
Updated: 2024/03/01

Sigma-Aldrich

Product number: W214520
Product name: Benzyl formate
Purity: natural, 97%, FG
Packaging: 100g
Price: $154
Updated: 2023/01/07

More

Less

Benzyl formate Chemical Properties,Usage,Production

Chemical Properties

Benzyl formate has an intense, pleasant, floral-fruity odor and sweet taste reminiscent of apricot and pineapple.

Chemical Properties

Colorless liquid; fruity-spicy odor. Resembles benzyl acetate in many respects but differs in its greater volatility. Miscible with alcohols, ketones, oils, aromatic, aliphatic and halogenated hydrocarbons; insoluble in water.

Occurrence

Reported found in the oil of Rosa rugosa, sour cherry, American cranberry, ligonberry, coffee, black tea, Agaricus mushroom, Ocimum basilicum, Bourbon vanilla and crowberry (Empetrum nigrum Coll.).

Uses

Solvent for cellulose esters; in perfumery.
It has a very sweet taste, more fruity than floral, spicy Banana-type. It is used quite frequently in perfume compositions, for floral bases such as Jasmin, Gardenia, NeroIi, Hyacinth, Carnation, and Fougeres and used in flavour compositions for imitation: Apricot, Banana, Cherry, Chocolate, Honey, Liquor, Nut, Peach, Plum, Prune, Pineapple, etc. Concentrations are usually about 12-15 ppm in the finished product. In chewing gum, the concentration may be as high as 35 ppm.

Preparation

By heating a mixture of formic/acetic anhydride and benzyl alcohol to 50°C; by passing a mixture of formic acid and excess benzyl alcohol over a catalyst (ThO2 or TiO2) at high temperature.

Definition

ChEBI: Benzylformate is a carboxylic ester. It is functionally related to a benzyl alcohol.

Taste threshold values

Taste characteristics at 10 ppm: fresh cherry with a berry, strawberry fruity nuance.

Synthesis Reference(s)

Journal of the American Chemical Society, 82, p. 2380, 1960 DOI: 10.1021/ja01494a065
The Journal of Organic Chemistry, 55, p. 2952, 1990 DOI: 10.1021/jo00296a072

Hazard

May be narcotic in high concentration.

Safety Profile

Moderately toxic by ingestion andskin contact. Mutation data reported. Probably narcotic inhigh concentrations. When heated todecomposition it emits acrid, irritating fumes.

Benzyl formate Preparation Products And Raw materials

Raw materials

Benzyl chloride Acetic anhydride Benzyl alcohol Formic acid (-)-MENTHYL CHLOROFORMATE Sodium formate

Preparation Products

(S)-2-(N，N-disubstitued aminomethy)indoline

More

Less

Benzyl formate Suppliers

Americas 1 Australia 1 China 139 Europe 1 Germany 5 India 30 Ireland 1 Italy 1 Japan 6 Mexico 1 Slovakia 1 South Africa 1 South Korea 1 Spain 2 Switzerland 1 United Kingdom 10 United States 62 Global 264

TCI Chemicals (India) Pvt. Ltd.

Tel: --
Fax: --
Email: sales-in@tcichemicals.com
Country: India
ProdList: 6768
Advantage: 58

S.G. Arochem Industries

Tel: --
Fax: --
Country: India
ProdList: 42
Advantage: 58

S.G. Arochem Industries.

Tel: --
Fax: --
Email: a1.akshat@gmail.com
Country: India
ProdList: 19
Advantage: 58

Omkar fine organics pvt Ltd.

Tel: --
Fax: --
Country: India
ProdList: 87
Advantage: 58

Mapin Industrial Company

Tel: --
Fax: --
Email: info@mapinchem.com
Country: India
ProdList: 77
Advantage: 58

Astrra Chemicals

Tel: --
Fax: --
Email: ac@astrrachemicals.in
Country: India
ProdList: 32
Advantage: 58

Silverline Chemicals

Tel: --
Fax: --
Country: India
ProdList: 61
Advantage: 58

Burgoyne Burbidges (India) Private Limited

Tel: --
Fax: --
Country: India
ProdList: 57
Advantage: 58

HiMedia Laboratories

Tel: --
Fax: --
Email: o@himedialabs.com
Country: India
ProdList: 1841
Advantage: 58

Vijay Trading Company

Tel: --
Fax: --
Email: info@viijaygroup.com
Country: India
ProdList: 109
Advantage: 58

Muby Chemicals

Tel: --
Fax: --
Country: India
ProdList: 30
Advantage: 58

Vee Kay International

Tel: --
Fax: --
Email: vki@vki.co.in
Country: India
ProdList: 57
Advantage: 58

Jayshree Aromatics Pvt. Ltd.

Tel: --
Fax: --
Email: info@jayshreeind.com
Country: India
ProdList: 81
Advantage: 58

U.K. Aromatics And Chemicals

Tel: --
Fax: --
Email: info@ukaromatics.com
Country: India
ProdList: 26
Advantage: 58

Jayshree Industries

Tel: --
Fax: --
Country: India
ProdList: 28
Advantage: 58

Karnataka Aromas

Tel: --
Fax: --
Country: India
ProdList: 104
Advantage: 58

Premier Chem Corporation

Tel: --
Fax: --
Country: India
ProdList: 83
Advantage: 58

Shraddha Organics

Tel: --
Fax: --
Country: India
ProdList: 14
Advantage: 58

Oxford laboratories

Tel: --
Fax: --
Country: India
ProdList: 652
Advantage: 58

Aroma Sales Corporation

Tel: --
Fax: --
Country: India
ProdList: 131
Advantage: 58

Amines Biotech Private Limited

Tel: --
Fax: --
Country: India
ProdList: 103
Advantage: 58

A.J Chemicals

Tel: --
Fax: --
Email: sales@ajchem.in
Country: India
ProdList: 6100
Advantage: 58

SRC Laboratories Pvt Ltd

Tel: --
Fax: --
Email: info@srclaboratories.com
Country: India
ProdList: 243
Advantage: 50

CHEMSWORTH

Tel: --
Fax: --
Email: info@chemsworth.com
Country: India
ProdList: 6700
Advantage: 30

More

Less

View Lastest Price from Benzyl formate manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: Benzyl Formate 104-57-4
Price: US $99.00-45.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-12-19

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Benzyl formate 104-57-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 95%
Supply Ability: 10000kg
Release date: 2023-01-14

Wuhan Boyuan Import & Export Co., LTD

Product: Benzyl formate 104-57-4
Price: US $1.00/mL
Min. Order: 1mL
Purity: 99%
Supply Ability: 50000tons
Release date: 2023-05-22

104-57-4, Benzyl formateRelated Search:

Benzyl benzoate Benzyl isocyanate Calcium formate Sodium formate Benzyl nicotinate Benzyl alcohol Benzyl chloride Butyl formate Methyl formate FORMATE ION CHROMATOGRAPHY STANDARD Benzyl carbamate 2,2,2-Trichloro-1-phenylethyl acetate Nalpha-Cbz-L-Arginine N-Carbobenzyloxy-L-aspartic acid N-Carbobenzyloxy-L-alanine Benzyl 2-bromoacetate Benzyl chloroformate Carbobenzoxyhydrazide

Benzyl alcohol, formate

benzylalcohol,formate

Benzylester kyseliny mravenci

benzylesterkyselinymravenci

Benzylformiat

Formicacid,phenylmethylester

formicacidphenylmethylester

Natural Benzyl formate

jiasuanbianzhi

BENZYL FORMATE

BENZYL METHANOATE

Benzyl methanoater

FORMIC ACID BENZYL ESTER

FORMIC ACID:BENZYL ESTER

FEMA 2145

N-BENZYL FORMATE

BENZYL FORMATE 95+% FCC

FORMIC ACID BENZYL ESTER 95+%

Formic acid benzyl

phenylmethyl formate

phenylmethyl methanoate

NSC 8049

BenzylFormate&gt

Benzyl formate USP/EP/BP

Benzyl formate(kosher)

104-57-4

140-57-4

HCO2CH2C6H5

HCOOCH2C6H5

ESTER

Industrial/Fine Chemicals

A-B

Alphabetical Listings

Flavors and Fragrances