Julolidine

ChemicalBook > CAS DataBase List > Julolidine

Product Name: Julolidine
CAS No.: 479-59-4
Chemical Name: Julolidine
Synonyms: JULOLIDINE;Julolidine>Julolidine,98%;Julolidine, 98% 25GR;Julolidine USP/EP/BP;Julolidine>97.0%(GC&T);5h-benzo[ij]quinolizine,2,3,6,7-tetrahydro-1;2,3,6,7-TETRAHYDRO-1H,5H-BENZO[IJ]QUINOLIZINE;1,2,3,5,6,7-Hexahydropyrido[3,2,1-ij]quinoline;2,3,6,7-Tetrahydro-1H,5H-benzop[ij]quinolizine
CBNumber: CB3167092
Molecular Formula: C12H15N
Formula Weight: 173.25
MOL File: 479-59-4.mol

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Julolidine Property

Melting point:: 34-36 °C(lit.)
Boiling point:: 170-173°C 31mm
Density: 1.0030
refractive index: 1.5680
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
pka: 6.54±0.20(Predicted)
form: Liquid After Melting
color: Clear yellow to orange-brown
Water Solubility: Soluble in toluene. Insoluble in water.
Sensitive: Air Sensitive
BRN: 139925
InChIKey: DZFWNZJKBJOGFQ-UHFFFAOYSA-N
CAS DataBase Reference: 479-59-4(CAS DataBase Reference)
NIST Chemistry Reference: Julolidine(479-59-4)
EPA Substance Registry System: 1H,5H-Benzo[ij]quinolizine, 2,3,6,7-tetrahydro- (479-59-4)

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Safety

Risk Statements: 52/53
Safety Statements: 24/25-61
WGK Germany: 3
TSCA: Yes
HS Code: 29339900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: J1001
Product name: Julolidine
Purity: 97%
Packaging: 5g
Price: $81
Updated: 2024/03/01

Sigma-Aldrich

Product number: J1001
Product name: Julolidine
Purity: 97%
Packaging: 25g
Price: $415
Updated: 2023/06/20

TCI Chemical

Product number: J0007
Product name: Julolidine
Purity: >97.0%(GC)(T)
Packaging: 5g
Price: $95
Updated: 2024/03/01

TCI Chemical

Product number: J0007
Product name: Julolidine
Purity: >97.0%(GC)(T)
Packaging: 25g
Price: $443
Updated: 2024/03/01

Alfa Aesar

Product number: B22976
Product name: Julolidine, 98%
Packaging: 1g
Price: $27.65
Updated: 2024/03/01

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Julolidine Chemical Properties,Usage,Production

Chemical Properties

CLEAR YELLOW TO ORANGE-BROWN LIQUID AFTER MELTING

Uses

Julolidine used as amine building block and in chemoluminescent dye. Also used in photoconductive materials, chemiluminescence substances, chromogenic substrates in analytical redox reactions, dye intermediates, potential antidepressants and tranquilizers, nonlinear optical materials, high sensitivity photopolymerizable materials, and for improving color stability in photography.

Purification Methods

Purify julolidine by dissolving it in dilute HCl, steam is bubbled through the solution and the residual acidic solution is basified with 10N NaOH, extracted with Et2O, washed with H2O, dried (NaOH pellets), filtered, evaporated and distilled in vacuo. The distillate crystallises on cooling (m 39-40o). It develops a red colour on standing in contact with air for several days. The colour can be removed by distilling or dissolving in 2-3 parts of hexane, adding charcoal, filtering and cooling in an Me2CO/Dry-ice bath when julolidine crystallises out (85-90% yield m 39-40o). The hydrobromide [83646-41-7] has m 218o (239-242o), the picrate has m 174o(165o) and the methiodide crystallises from MeOH, with m 186o [Glass & Weisberger Org Synth Coll Vol III 504 1955, Smith & Yu J Org Chem 17 1285 1952, Beilstein 20 H 332, 20 I 133, 20 II 214, 20 III/IV 3281.] Highly TOXIC.

Julolidine Preparation Products And Raw materials

Raw materials

Tetrahydroquinoline 1-Bromo-3-chloropropane

Preparation Products

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View Lastest Price from Julolidine manufacturers

Career Henan Chemical Co

Product: Julolidine 479-59-4
Price: US $1.00/KG
Min. Order: 1g
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-10

Nanjing jinheyou Trading Co., Ltd.

Product: Julolidine 479-59-4
Price: US $0.00/g
Min. Order: 1g
Purity: 99.5%min
Supply Ability: 20kg/week
Release date: 2019-10-31

479-59-4, JulolidineRelated Search:

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JULOLIDINE

2,3,6,7-TETRAHYDRO-1H,5H-BENZO[IJ]QUINOLIZINE

2,3,6,7-TETRAHYDRO-1H,5H-PYRIDO[3.2.1-IJ]QUINOLINE

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5h-benzo[ij]quinolizine,2,3,6,7-tetrahydro-1

Julolidine,98%

2,3,6,7-Tetrahydro-1H,5H-benzop[ij]quinolizine

Julolidine, 98% 25GR

1,2,3,5,6,7-Hexahydropyrido[3,2,1-ij]quinoline

Julolidine&gt

Julolidine>97.0%(GC&T)

Julolidine USP/EP/BP

479-59-4

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