ChemicalBook > CAS DataBase List > Trimethyloxonium Tetrafluoroborate

Trimethyloxonium Tetrafluoroborate

Product Name
Trimethyloxonium Tetrafluoroborate
CAS No.
420-37-1
Chemical Name
Trimethyloxonium Tetrafluoroborate
Synonyms
TriMethyloxoniuM Fluoroborate;triMethyloxoiuM tetrafluoroborate;trimethyl-oxoniu tetrafluoroborate;SKL1456;SKL1563;NSC 528455;oxonium tetrafL;trimethyloxidanium;Oxonium, trimethyl-;Trimethoxonium fluoroborate
CBNumber
CB3184284
Molecular Formula
C3H9BF4O
Formula Weight
147.91
MOL File
420-37-1.mol
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Trimethyloxonium Tetrafluoroborate Property

Melting point:
200 °C
storage temp. 
Store at +2°C to +8°C.
solubility 
Soluble in nitrobenzene, nitromethane, chloroform, hot acetone, liquid sulfur dioxide. Slightly soluble in dichloromethane. Insoluble in common organic solvents.
form 
Crystals
color 
White to off-white
Sensitive 
Moisture Sensitive
BRN 
3597303
InChI
InChI=1S/C3H9O.BF4/c1-4(2)3;2-1(3,4)5/h1-3H3;/q+1;-1
InChIKey
JDFKFXJJAIJXPP-UHFFFAOYSA-M
SMILES
[B-](F)(F)(F)F.[O+](C)(C)C
CAS DataBase Reference
420-37-1(CAS DataBase Reference)
EPA Substance Registry System
Oxonium, trimethyl-, tetrafluoroborate(1-) (420-37-1)
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Safety

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-36/37/39-43-45
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
3-10-21
Hazard Note 
Corrosive/Freeze
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29420000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
281077
Product name
Trimethyloxonium tetrafluoroborate
Purity
95%
Packaging
1g
Price
$39.6
Updated
2024/03/01
Sigma-Aldrich
Product number
281077
Product name
Trimethyloxonium tetrafluoroborate
Purity
95%
Packaging
10g
Price
$82.7
Updated
2024/03/01
TCI Chemical
Product number
T1507
Product name
Trimethyloxonium Tetrafluoroborate
Purity
>95.0%(T)
Packaging
5g
Price
$37
Updated
2024/03/01
TCI Chemical
Product number
T1507
Product name
Trimethyloxonium Tetrafluoroborate
Purity
>95.0%(T)
Packaging
25g
Price
$98
Updated
2024/03/01
Alfa Aesar
Product number
A15175
Product name
Trimethyloxonium tetrafluoroborate
Purity
96%
Packaging
10g
Price
$75
Updated
2024/03/01
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Trimethyloxonium Tetrafluoroborate Chemical Properties,Usage,Production

Chemical Properties

This substance is a white to off-white crystals that is prone to water sensitivity and displays a level of hygroscopicity.

Uses

Trimethyloxonium Tetrafluoroborate is a trialkylated oxonium used as a methylation agent in organic synthesis.

Uses

Trimethyloxonium tetrafluoroborate act as a avmethylating agent and activates C-X multiple bonds. It is involved in the esterification of polyfunctional carboxylic acids. It acts as a catalyst in the polymerization of cyclic sulfides and ethers. Further, it is used in Beckmann rearrangement of oximes.

Uses

Reagent for the methylation of hydroxyl groups recently used in a complex, multistep synthesis directed towards spirastrellolide, a marine natural product.

Health Hazard

Trimethyloxonium Tetrafluoroborate is a potent alkylating agent, with its non-volatile nature reducing associated hazards. Nevertheless, it produces strong acids upon contact with water, so it is important to exercise caution and prevent water contact during its application.

Trimethyloxonium Tetrafluoroborate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Trimethyloxonium Tetrafluoroborate manufacturers

Zibo Hangyu Biotechnology Development Co., Ltd
Product
Trimethyloxonium Tetrafluoroborate 420-37-1
Price
US $0.00-0.00/KG
Min. Order
100KG
Purity
99.9%
Supply Ability
20TONS
Release date
2023-10-10
Anhui Ruihan Technology Co., Ltd
Product
Trimethyloxonium Tetrafluoroborate 420-37-1
Price
US $50.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000tons
Release date
2023-09-11
LY Global chemicals co.,ltd .
Product
TRIMETHYLOXONIUM TETRAFLUOROBORATE 420-37-1
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98% Min
Supply Ability
1000kg
Release date
2023-03-18

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  • 420-37-1
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  • CH33OBF4
  • C3H9BF4O
  • C3H9OBF4
  • Tetrafluoroborates
  • B (Classes of Boron Compounds)
  • Oxonium Compounds
  • Iodonium Sulfonium & Oxonium Compounds
  • Alkyl Transfer
  • Synthetic Reagents
  • C-X Bond Formation (Non-Halogen)
  • halometallate salts
  • B (Classes of Boron Compounds)
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  • Oxonium Compounds
  • Tetrafluoroborates
  • Alkyl Transfer
  • C-X Bond Formation (Non-Halogen)
  • Synthetic Reagents