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Potassium trimethylsilanolate

Product Name
Potassium trimethylsilanolate
CAS No.
10519-96-7
Chemical Name
Potassium trimethylsilanolate
Synonyms
Potassium methyl silicate;DK457;Potassium trimethyL;Carazolol Impurity 3;Trimethylsiloxypotassium;Potassiooxytrimethylsilane;Potassium Trimethylsiloxide;Trimethyl(potassiooxy)silane;(Potassiooxy)trimethylsilane;Potassium trimethylsilanoate
CBNumber
CB6769011
Molecular Formula
C3H9KOSi
Formula Weight
128.29
MOL File
10519-96-7.mol
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Potassium trimethylsilanolate Property

Melting point:
135-138 °C (lit.)
Density 
0.91
Flash point:
-14°C (7°F)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
DMSO (Springly), Methanol (Slightly)
form 
powder
Specific Gravity
0.91
color 
White
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
3560282
InChI
InChI=1S/C3H9OSi.K/c1-5(2,3)4;/h1-3H3;/q-1;+1
InChIKey
LBKJNHPKYFYCLL-UHFFFAOYSA-N
SMILES
[Si]([O-])(C)(C)C.[K+]
EPA Substance Registry System
Silanol, trimethyl-, potassium salt (10519-96-7)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3263 8/PG 2
WGK Germany 
3
3-10-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
324868
Product name
Potassium trimethylsilanolate
Purity
90%, technical grade
Packaging
25g
Price
$198
Updated
2024/03/01
Sigma-Aldrich
Product number
324868
Product name
Potassium trimethylsilanolate
Purity
90%, technical grade
Packaging
1kg
Price
$3270
Updated
2024/03/01
Sigma-Aldrich
Product number
324868
Product name
Potassium trimethylsilanolate
Purity
90%, technical grade
Packaging
100g
Price
$645
Updated
2024/03/01
TRC
Product number
P698580
Product name
Potassium trimethylsilanolate
Packaging
5g
Price
$120
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
61344
Product name
Potassium trimethylsilanolate
Packaging
25g
Price
$650
Updated
2021/12/16
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Potassium trimethylsilanolate Chemical Properties,Usage,Production

Uses

Potassium trimethylsilanolate can be used as a reagent in the:

  • Hydrolysis of nitriles to primary amides.
  • Conversion of esters to carboxylic acids, and dialkyl phosphonates to their monoalkyl phosphonates.
  • Synthesis of E-alkenes, and nitrocefin.


It can also be used as a coupling promoter in cross-coupling reaction of aliphatic alkynylsilanols with aryl iodides.

Solubility in organics

Potassium trimethylsilanolate is solubility in tetrahydrofuran, diethyl ether, toluene, dichloromethane, alcohols, and most other organic solvents.

Purification Methods

Recrystallise it from H2O and dry it at 100o/1-2mm. [Hyde et al. J Am Chem Soc 75 5615 1953, IR: Tatlock & Rochow J Org Chem 17 1555 1952, Beilstein 4 IV 3992.]

Potassium trimethylsilanolate Preparation Products And Raw materials

Raw materials

Preparation Products

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Potassium trimethylsilanolate Suppliers

Shanghai Rochi Pharmaceutical Co., Ltd.
Tel
021-38751876 15000076078
Fax
021-50275764
Email
Info@rochipharma.com
Country
China
ProdList
568
Advantage
55
Shanghai chuqing Organosilane technology ltd
Tel
021-61530618
Fax
86-21-51714575
Email
sales@chuqingtech.com
Country
China
ProdList
274
Advantage
55
New Energy Chemicals
Tel
0515-82159088 13770142076
Fax
86-0515-8215909
Email
twl@njuchem.com
Country
China
ProdList
213
Advantage
65
Hubei Dongcao Chemical Technology Co., Ltd
Tel
027-83261126 18971318572
Email
2969475037@qq.com
Country
China
ProdList
5000
Advantage
58
SHENZHEN REISCH BIOTECH CO., LTD
Tel
0755-0755-28609002 15112530219
Email
1179151648@qq.com
Country
China
ProdList
318
Advantage
58
Jikang Chemical Industry Co. , Ltd.
Tel
0573-85609002 18157336032
Email
zhejia01@163.com
Country
China
ProdList
7858
Advantage
58
Shanghai Qiming New Material Co. LTD
Tel
021-36010885 13661599081
Fax
021-66167180
Email
sale@qmsilicon.com
Country
China
ProdList
1434
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
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View Lastest Price from Potassium trimethylsilanolate manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Potassium trimethylsilanolate 10519-96-7
Price
US $20.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
30 tons
Release date
2023-10-23
Hebei Weibang Biotechnology Co., Ltd
Product
Potassium trimethylsilanolate 10519-96-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24
Hebei Kangcang new material Technology Co., LTD
Product
POTASSIUM TRIMETHYLSILANOLATE 10519-96-7
Price
US $20.00-10.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
20
Release date
2024-04-25

10519-96-7, Potassium trimethylsilanolateRelated Search:


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