4-AMINO-3-BROMOBENZOIC ACID
Uses- Product Name
- 4-AMINO-3-BROMOBENZOIC ACID
- CAS No.
- 6311-37-1
- Chemical Name
- 4-AMINO-3-BROMOBENZOIC ACID
- Synonyms
- CL228;NSC43549;ZR BE DVQ;BUTTPARK 35\03-06;RARECHEM AL BO 1227;4-Amino-3-Bromobenzoic;4-AMINO-3-BROMOBENZOIC ACID;4-AMINO-3-BROMOBENZIOC ACID;4-azanyl-3-bromo-benzoic acid;Benzoic acid, 4-amino-3-bromo-
- CBNumber
- CB3186561
- Molecular Formula
- C7H6BrNO2
- Formula Weight
- 216.03
- MOL File
- 6311-37-1.mol
4-AMINO-3-BROMOBENZOIC ACID Property
- Melting point:
- 211-215 °C
- Boiling point:
- 368.5±32.0 °C(Predicted)
- Density
- 1.793±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- form
- powder to crystal
- pka
- 4.47±0.10(Predicted)
- color
- White to Light yellow to Light orange
- Major Application
- peptide synthesis
- InChI
- InChI=1S/C7H6BrNO2/c8-5-3-4(7(10)11)1-2-6(5)9/h1-3H,9H2,(H,10,11)
- InChIKey
- BFIVZIVVJNFTIQ-UHFFFAOYSA-N
- SMILES
- C(O)(=O)C1=CC=C(N)C(Br)=C1
- CAS DataBase Reference
- 6311-37-1(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36-37/38-36/37/38-22
- Safety Statements
- 26-37/39-36
- RIDADR
- UN 2811 6.1/PG 3
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- 6.1
- PackingGroup
- Ⅲ
- HS Code
- 29224999
- Storage Class
- 6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects - Hazard Classifications
- Acute Tox. 3 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 663484
- Product name
- 4-Amino-3-bromobenzoic acid
- Purity
- 97%
- Packaging
- 1g
- Price
- $25
- Updated
- 2023/06/20
- Product number
- 663484
- Product name
- 4-Amino-3-bromobenzoic acid
- Purity
- 97%
- Packaging
- 10g
- Price
- $238
- Updated
- 2023/01/07
- Product number
- A1969
- Product name
- 4-Amino-3-bromobenzoic Acid
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $54
- Updated
- 2026/03/19
- Product number
- A602493
- Product name
- 4-Amino-3-bromobenzoic acid
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 4657-9-05
- Product name
- 4-Amino-3-bromobenzoic acid
- Purity
- 98%
- Packaging
- 25g
- Price
- $103
- Updated
- 2021/12/16
4-AMINO-3-BROMOBENZOIC ACID Chemical Properties,Usage,Production
Uses
4-Amino-3-bromobenzoic acid is a useful research chemical.
Chemical Properties
White to light yellow crystal powder
Uses
peptide synthesis
reaction suitability
reaction type: solution phase peptide synthesis
Synthesis
150-13-0
6311-37-1
General procedure for the synthesis of 3-bromo-4-aminobenzoic acid from 4-aminobenzoic acid: 4-aminobenzoic acid (100 mmol) was dissolved in N,N-dimethylformamide (DMF, 50 mL), followed by the addition of N-bromosuccinimide (NBS, 100 mmol). The reaction mixture was stirred at room temperature for 18 hours. Upon completion of the reaction, the mixture was poured into water (100 mL) and a solid was precipitated. The product was collected by filtration, washed with water and dried under vacuum to afford the target compound 4-amino-3-bromobenzoic acid in 70% yield. The structure of the product was confirmed by 1H NMR (D6-DMSO): δ 6.10 (s, 2H), 6.78 (d, 1H), 7.63 (dd, 1H), 7.89 (d, 1H), 12.39 (br s, 1H).
References
[1] Russian Journal of Applied Chemistry, 2009, vol. 82, # 9, p. 1570 - 1576
[2] Journal of the American Chemical Society, 2010, vol. 132, # 6, p. 1734 - 1735
[3] Tetrahedron Letters, 2009, vol. 50, # 9, p. 1007 - 1009
[4] Journal of the Brazilian Chemical Society, 2010, vol. 21, # 3, p. 496 - 501
[5] Tetrahedron Letters, 2000, vol. 41, # 13, p. 2083 - 2085
4-AMINO-3-BROMOBENZOIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-AMINO-3-BROMOBENZOIC ACID manufacturers
- Product
- 4-AMINO-3-BROMOBENZOIC ACID 6311-37-1
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10000KGS
- Release date
- 2025-03-08
- Product
- 4-AMINO-3-BROMOBENZOIC ACID 6311-37-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-12