PENTYLTRIPHENYLPHOSPHONIUM BROMIDE
- Product Name
- PENTYLTRIPHENYLPHOSPHONIUM BROMIDE
- CAS No.
- 21406-61-1
- Chemical Name
- PENTYLTRIPHENYLPHOSPHONIUM BROMIDE
- Synonyms
- TPL;(1-PentyL;PENTYLTRIPHENYH;PhosphoniuM,pentyltriphenyl-;AMYLTRIPHENYLPHOSPHONIUM BROMIDE;pentyltriphenylphosphaniuM broMide;PENTYLTRIPHENYLPHOSPHONIUM BROMIDE;PENTYLTRIPHENYHLPHOSPHONIUM BROMIDE;N-AMYL TRIPHENYLPHOSPHONIUM BROMIDE;Triphenyl-n-amylphosphonium bromide
- CBNumber
- CB3186657
- Molecular Formula
- C23H26BrP
- Formula Weight
- 413.33
- MOL File
- 21406-61-1.mol
PENTYLTRIPHENYLPHOSPHONIUM BROMIDE Property
- Melting point:
- 165-168 °C
- storage temp.
- Inert atmosphere,Room Temperature
- form
- solid
- color
- White to Almost white
- Water Solubility
- Partly miscible in water. Soluble in methanol and chloroform.
- Sensitive
- Hygroscopic
- BRN
- 3580453
- InChI
- InChI=1S/C23H26P.BrH/c1-2-3-13-20-24(21-14-7-4-8-15-21,22-16-9-5-10-17-22)23-18-11-6-12-19-23;/h4-12,14-19H,2-3,13,20H2,1H3;1H/q+1;/p-1
- InChIKey
- VAUKWMSXUKODHR-UHFFFAOYSA-M
- SMILES
- [P+](CCCCC)(C1C=CC=CC=1)(C1C=CC=CC=1)C1=CC=CC=C1.[Br-]
- CAS DataBase Reference
- 21406-61-1(CAS DataBase Reference)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 37/39-26-37
- HS Code
- 29319090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- S616591
- Product name
- PENTYLTRIPHENYLPHOSPHONIUM BROMIDE
- Purity
- Aldrich<sup>CPR</sup>
- Packaging
- 1 unit
- Price
- $113
- Updated
- 2025/07/31
- Product number
- S616591
- Product name
- PENTYLTRIPHENYLPHOSPHONIUM BROMIDE
- Purity
- AldrichCPR
- Packaging
- 250mg
- Price
- $110
- Updated
- 2024/03/01
- Product number
- A0862
- Product name
- Amyltriphenylphosphonium Bromide
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $38
- Updated
- 2025/07/31
- Product number
- B699483
- Product name
- Bromo(pentyl)triphenylphosphorane
- Packaging
- 50g
- Price
- $160
- Updated
- 2021/12/16
- Product number
- 37254
- Product name
- Amyltriphenylphosphoniumbromide,98%(Assaybytitration,HPLC)
- Purity
- 98%(Assaybytitration,HPLC)
- Packaging
- 250G
- Price
- $173.6
- Updated
- 2021/12/16
PENTYLTRIPHENYLPHOSPHONIUM BROMIDE Chemical Properties,Usage,Production
Chemical Properties
LIGHT BROWN TO YELLOW-BROWN CRYSTALLINE POWDER
Uses
It is used as pharmaceutical intermediates.
Synthesis
110-53-2
603-35-0
21406-61-1
General procedure: 1-Bromopentane (1 eq.) was reacted with triphenylphosphine (1.3 eq.) in anhydrous toluene at reflux for 8 to 12 hours under vigorous stirring, referring to literature methods. After completion of the reaction, it was cooled to room temperature and the white solid product was collected by filtration. The solid was washed with excess diethyl ether and subsequently dried. The resulting (1-pentyl)triphenylphosphonium bromide can be used directly in subsequent reactions without further purification.
References
[1] Bulletin de la Societe Chimique de France, 1991, # 3, p. 397 - 406
[2] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985, p. 2307 - 2326
[3] Bioorganic and Medicinal Chemistry, 2014, vol. 22, # 19, p. 5168 - 5181
[4] Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1996, vol. 35, # 2, p. 99 - 101
[5] Pharmazie, 1999, vol. 54, # 1, p. 26 - 30
PENTYLTRIPHENYLPHOSPHONIUM BROMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
PENTYLTRIPHENYLPHOSPHONIUM BROMIDE Suppliers
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- Country
- United Kingdom
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- solutions@vwr.com
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- United Kingdom
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View Lastest Price from PENTYLTRIPHENYLPHOSPHONIUM BROMIDE manufacturers
- Product
- pentyltriphenylphosphonium bromide 21406-61-1
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-10
- Product
- Pentyltriphenylphosphonium bromide 21406-61-1
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-30
- Product
- PENTYLTRIPHENYLPHOSPHONIUM BROMIDE 21406-61-1
- Price
- US $20.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000KG
- Release date
- 2020-11-10