ChemicalBook > CAS DataBase List > BISMUTH(III) FLUORIDE
BISMUTH(III) FLUORIDE
- Product Name
- BISMUTH(III) FLUORIDE
- CAS No.
- 7787-61-3
- Chemical Name
- BISMUTH(III) FLUORIDE
- Synonyms
- BISMUTH TRIFLUORIDE;BISMUTH FLUORIDE;Bismuthfluoride1;trifluoro-bismuthin;trifluorobismuthane;trifluoro-Bismuthine;Bismuth(Ⅲ) Fluoride;BISMUTH(III) FLUORIDE;Bismuthine, trifluoro-;BISMUTH(III) TRIFLUORIDE
- CBNumber
- CB3196539
- Molecular Formula
- BiF3
- Formula Weight
- 265.98
- MOL File
- 7787-61-3.mol
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BISMUTH(III) FLUORIDE Property
- Melting point:
- 727 °C
- Boiling point:
- 900°C
- Density
- 8.3 g/mL at 25 °C(lit.)
- refractive index
- 1.74
- solubility
- H2O: insoluble(lit.)
- form
- Powder
- Specific Gravity
- 5.32
- color
- white-gray cubic crystals, crystalline
- Water Solubility
- Insoluble in water. Soluble in HF.
- Crystal Structure
- YF3 type
- Sensitive
- Hygroscopic
- Merck
- 14,1265
- crystal system
- Nogata
- Space group
- Pnma
- Lattice constant
a/nm b/nm c/nm α/o β/o γ/o V/nm3 0.656 0.702 0.484 90 90 90 0.2228 - Exposure limits
- ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3 - CAS DataBase Reference
- 7787-61-3(CAS DataBase Reference)
- EPA Substance Registry System
- Bismuthine, trifluoro- (7787-61-3)
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Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3260 8/PG 2
- WGK Germany
- 3
- F
- 10-21
- Hazard Note
- Corrosive
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 28261990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 401528
- Product name
- Bismuth(III) fluoride
- Purity
- ≥99.99% trace metals basis
- Packaging
- 5g
- Price
- $84.7
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 013075
- Product name
- Bismuth(III) fluoride, anhydrous, 99%
- Packaging
- 100g
- Price
- $117.65
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 013075
- Product name
- Bismuth(III) fluoride, anhydrous, 99%
- Packaging
- 25g
- Price
- $50.1
- Updated
- 2023/06/20
Strem Chemicals
- Product number
- 83-3000
- Product name
- Bismuth(III) fluoride (99.99+%-Bi) PURATREM
- Packaging
- 10g
- Price
- $71
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 83-3000
- Product name
- Bismuth(III) fluoride (99.99+%-Bi) PURATREM
- Packaging
- 50g
- Price
- $282
- Updated
- 2024/03/01
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BISMUTH(III) FLUORIDE Chemical Properties,Usage,Production
Chemical Properties
White Crystal or crystalline powder
Physical properties
Bismuth fluoride is a heavy, white (gray if impure) crystalline powder, practically insoluble in water. M.p. 725-730°C; d. 8.3. Cubic (dimorphous).
Uses
Bismuth fluoride is used in the manufacturing of bismuth pentafluoride. It is an attractive reagent and catalyst in organic synthesis owing to its low cost, and ease of handling. It is also used in polarography.
Uses
In the preparation of bismuth pentafluoride, q.v.
Preparation
The preparation method of Bismuth fluoride: Freshly precipitated bismuth hydroxide is evaporated to dryness several times in a Pt dish, using an excess of hydrofluoric acid. It is then calcined in a covered Pt crucible until the HF has completely evaporated.
BISMUTH(III) FLUORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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7787-61-3, BISMUTH(III) FLUORIDERelated Search:
BISMUTH TITANATE
Triphenylbismuth
Bismuth nitrate pentahydrate
Bismuth trioxide
BISMUTH SULFIDE
BISMUTH NEODECANOATE
Bismuth trichloride
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BISMUTH(III) IODIDE
BISMUTH TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE)
BISMUTH TELLURIDE
BISMUTH(III) BROMIDE
Bismuth
Bismuth pentafluoride
BISMUTH(III) FLUORIDE
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BISMUTH POTASSIUM FLUORIDE
BISMUTH(III) FLUORIDE 99.9