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BISMUTH(III) FLUORIDE

Product Name
BISMUTH(III) FLUORIDE
CAS No.
7787-61-3
Chemical Name
BISMUTH(III) FLUORIDE
Synonyms
BISMUTH TRIFLUORIDE;BISMUTH FLUORIDE;Bismuthfluoride1;trifluoro-bismuthin;trifluorobismuthane;trifluoro-Bismuthine;Bismuth(Ⅲ) Fluoride;BISMUTH(III) FLUORIDE;Bismuthine, trifluoro-;BISMUTH(III) TRIFLUORIDE
CBNumber
CB3196539
Molecular Formula
BiF3
Formula Weight
265.98
MOL File
7787-61-3.mol
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BISMUTH(III) FLUORIDE Property

Melting point:
727 °C
Boiling point:
900°C
Density 
8.3 g/mL at 25 °C(lit.)
refractive index 
1.74
solubility 
H2O: insoluble(lit.)
form 
Powder
Specific Gravity
5.32
color 
white-gray cubic crystals, crystalline
Water Solubility 
Insoluble in water. Soluble in HF.
Crystal Structure
YF3 type
Sensitive 
Hygroscopic
Merck 
14,1265
crystal system
Nogata
Space group
Pnma
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.6560.7020.4849090900.2228
Exposure limits
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3
CAS DataBase Reference
7787-61-3(CAS DataBase Reference)
EPA Substance Registry System
Bismuthine, trifluoro- (7787-61-3)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
10-21
Hazard Note 
Corrosive
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
28261990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
401528
Product name
Bismuth(III) fluoride
Purity
≥99.99% trace metals basis
Packaging
5g
Price
$84.7
Updated
2024/03/01
Alfa Aesar
Product number
013075
Product name
Bismuth(III) fluoride, anhydrous, 99%
Packaging
100g
Price
$117.65
Updated
2024/03/01
Alfa Aesar
Product number
013075
Product name
Bismuth(III) fluoride, anhydrous, 99%
Packaging
25g
Price
$50.1
Updated
2023/06/20
Strem Chemicals
Product number
83-3000
Product name
Bismuth(III) fluoride (99.99+%-Bi) PURATREM
Packaging
10g
Price
$71
Updated
2024/03/01
Strem Chemicals
Product number
83-3000
Product name
Bismuth(III) fluoride (99.99+%-Bi) PURATREM
Packaging
50g
Price
$282
Updated
2024/03/01
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BISMUTH(III) FLUORIDE Chemical Properties,Usage,Production

Chemical Properties

White Crystal or crystalline powder

Physical properties

Bismuth fluoride is a heavy, white (gray if impure) crystalline powder, practically insoluble in water. M.p. 725-730°C; d. 8.3. Cubic (dimorphous).

Uses

Bismuth fluoride is used in the manufacturing of bismuth pentafluoride. It is an attractive reagent and catalyst in organic synthesis owing to its low cost, and ease of handling. It is also used in polarography.

Uses

In the preparation of bismuth pentafluoride, q.v.

Preparation

The preparation method of Bismuth fluoride: Freshly precipitated bismuth hydroxide is evaporated to dryness several times in a Pt dish, using an excess of hydrofluoric acid. It is then calcined in a covered Pt crucible until the HF has completely evaporated.

BISMUTH(III) FLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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BISMUTH(III) FLUORIDE Suppliers

SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
91

7787-61-3, BISMUTH(III) FLUORIDERelated Search:


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  • BISMUTH TRIFLUORIDE, ANH
  • Bismuth(III) fluoride, anhydrous 99.99%
  • Bismuth fluoride, ≥99.99%
  • trifluorobismuthane
  • 7787-61-3
  • Bi3F
  • Bi1F3
  • Catalysis and Inorganic Chemistry
  • metal halide
  • Bismuth Salts
  • BismuthMetal and Ceramic Science
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Crystal Grade Inorganics
  • Salts