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Triphenylbismuth

Product Name
Triphenylbismuth
CAS No.
603-33-8
Chemical Name
Triphenylbismuth
Synonyms
TPB;Aerotex;(C6H5)3Bi;Trifenylbismutin;TRIPHENYLBISMUTH;BISMUTH TRIPHENYL;triphenyl-bismuthin;TRIPHENYLBISMUTHINE;Triphenylbismuth,99%;Triphenylbismuth,98%
CBNumber
CB7478628
Molecular Formula
C18H15Bi
Formula Weight
440.29
MOL File
603-33-8.mol
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Triphenylbismuth Property

Melting point:
78-80 °C
Boiling point:
310°C
Density 
1,585 g/cm3
refractive index 
1.7040
Flash point:
242°C/14mm
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
crystal
color 
white
Specific Gravity
1.585
Water Solubility 
insoluble
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
CAS DataBase Reference
603-33-8(CAS DataBase Reference)
NIST Chemistry Reference
Bismuthine, triphenyl-(603-33-8)
EPA Substance Registry System
Triphenylbismuth (603-33-8)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22
Safety Statements 
24/25-36/37
WGK Germany 
3
RTECS 
EB2980000
TSCA 
Yes
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P330Rinse mouth.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
93-8350
Product name
Triphenylbismuth, 99%
Packaging
10g
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
93-8350
Product name
Triphenylbismuth, 99%
Packaging
50g
Price
$432
Updated
2024/03/01
TRC
Product number
T895953
Product name
Triphenylbismuth
Packaging
2.5g
Price
$85
Updated
2021/12/16
Matrix Scientific
Product number
099616
Product name
Triphenylbismuthine
Purity
95+%
Packaging
5g
Price
$30
Updated
2021/12/16
Matrix Scientific
Product number
099616
Product name
Triphenylbismuthine
Purity
95+%
Packaging
10g
Price
$42
Updated
2021/12/16
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Triphenylbismuth Chemical Properties,Usage,Production

Chemical Properties

white to off-white crystalline powder

Uses

Triphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.

Preparation

Triphenylbismuth is conveniently prepared by reaction of Phenylmagnesium Bromide with BiCl3 in ether.

storage

It ?must be stored in dark bottles in the absence of moisture or acidic vapors. Use in a fume hood.

Purification Methods

Dissolve it in EtOH, precipitate it with H2O, extract with Et2O, dry and evaporate till the residue crystallises. It has been recrystallised from EtOH and Et2O/EtOH and is a stable compound. [Forward et al. J Chem Soc suppl p121 1949, Pfeiffer et al. Chem Ber 37 4620 1904, Gilman & Yablunky J Am Chem Soc 62 665 1940, UV: Jaffé J Chem Phys 22 1430 1954, Beilstein 4 III 1841.]

Triphenylbismuth Preparation Products And Raw materials

Raw materials

Preparation Products

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Triphenylbismuth Suppliers

Shanghai F.R. Chemical Technology Co.,Ltd
Tel
021-52230662 13795399395
Email
seaman79@126.com
Country
China
ProdList
259
Advantage
58
Yingkou Tianyuan Chemical Research Institute Co., Ltd.
Tel
086-17722431616-6 17722431616
Email
840117205@qq.com
Country
China
ProdList
47
Advantage
58
Changzhou Gabriel Chemical Co., Ltd.
Tel
13961111278
Email
731967165@qq.com
Country
China
ProdList
15
Advantage
58
Shanghai Licheng Chemical Co., Ltd.
Tel
021-67100011 15867680329
Fax
021-67105577
Email
1241713527@qq.com
Country
China
ProdList
76
Advantage
58
Panjin Greenchem Technology Co., Ltd.
Tel
13121959385
Email
chemrocking@bjgreenchem.com
Country
China
ProdList
220
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-021-61259138 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
INTATRADE GmbH
Tel
+49 3493/605464
Fax
+49 3493/605470
Email
sales@intatrade.de
Country
Germany
ProdList
3572
Advantage
66
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
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View Lastest Price from Triphenylbismuth manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Triphenylbismuth 603-33-8
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-08
Hebei Junhua Import and Export Co., LTD
Product
Triphenylbismuth 603-33-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000
Release date
2025-03-31
Henan Aochuang Chemical Co.,Ltd.
Product
Triphenylbismuth 603-33-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30

603-33-8, TriphenylbismuthRelated Search:


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