Dichlorotriphenyl bismuth
- Product Name
- Dichlorotriphenyl bismuth
- CAS No.
- 594-30-9
- Chemical Name
- Dichlorotriphenyl bismuth
- Synonyms
- triphenylbismuth(2+);DICHLOROTRIPHENYLBISMUTH;Triphenyldichlorobismuth;Triphenyldichlorobismuthine;Triphenyldichlorobismuth(V);Dichlorotriphenylbismuthine;Dichlorotriphenylbismuth(V);TRIPHENYLBISMUTH DICHLORIDE;TTIPHENYLBISMUTH DICHLORIDE;Triphenylbismuthine dichloride
- CBNumber
- CB4214582
- Molecular Formula
- C18H15BiCl2
- Formula Weight
- 511.2
- MOL File
- 594-30-9.mol
Dichlorotriphenyl bismuth Property
- Melting point:
- 128-142°C
- storage temp.
- Refrigerator
- solubility
- soluble in Tetrahydrofuran
- form
- powder to crystal
- color
- White to Almost white
- EPA Substance Registry System
- Triphenylbismuthine dichloride (594-30-9)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 26-36/37/39
- HS Code
- 2931.90.6000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- T1837
- Product name
- Triphenylbismuth Dichloride
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $218
- Updated
- 2024/03/01
- Product number
- 291662
- Product name
- Triphenylbismuth Dichloride
- Packaging
- 1g
- Price
- $312
- Updated
- 2021/12/16
- Product number
- R192
- Product name
- Triphenylbismuth Dichloride
- Packaging
- 5g
- Price
- $356
- Updated
- 2021/12/16
- Product number
- 40587
- Product name
- Triphenylbismuthdichloride,98%(Assaybytitration)
- Purity
- 98%(Assaybytitration)
- Packaging
- 5G
- Price
- $252
- Updated
- 2021/12/16
- Product number
- ING0008362
- Product name
- TRIPHENYLBISMUTH DICHLORIDE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $281.72
- Updated
- 2021/12/16
Dichlorotriphenyl bismuth Chemical Properties,Usage,Production
Uses
Dichlorotriphenyl bismuth is used for phenylation of phenols, ketones and enols, and nitro compounds.
Preparation
Dichlorotriphenyl bismuth is easily prepared by oxidation of Triphenylbismuthine either by bubbling Chlorine gas into an ethereal solution of Ph3Bi at 0°C, or by addition of 1 equiv of Sulfuryl Chloride to a solution of Ph3Bi in CH2Cl2 at -78°C. The action of Phenyllithium on Ph3BiCl2 leads to pentaphenylbismuth (mp 77-78 °C). Addition of 1 equiv of a carboxylic or sulfonic acid to Ph5Bi affords compounds of the type Ph4BiX.(Ph4BiOCOCF3: mp 120-132 °C; Ph4BiOTs: mp 155-162 °C).
Definition
ChEBI: Dichloro(triphenyl)bismuthorane is an organobismuth compound. It derives from a hydride of a bismuthorane.
storage
Dichlorotriphenyl bismuth is a stable white solid; can be stored in the refrigerator in the absence of moisture.
Dichlorotriphenyl bismuth Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Dichlorotriphenyl bismuth manufacturers
- Product
- Dichlorotriphenyl bismuth 594-30-9
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2020-02-18